Technological and scientific advances have given rise to an era in which coherent quantum-mechanical phenomena can be probed and experimentally-realised over unprecedented timescales in condensed matter physics. In turn, scientific interest in non-equilibrium dynamics and irreversibility signatures of thermodynamics has taken place in recent decades, particularly in relation to cold-atom platforms and thermoelectric devices. In this PhD thesis I summarise some of the most important results obtained over the duration of my PhD, on the topic of thermodynamics involving interacting many-body quantum systems. The topics of discussion encompass three main themes: spin/particle transport in non-integrable systems, explorations in eigenstate thermalisation and finite-temperature transport in autonomous thermal machines. By questioning the effect of local integrability-breaking perturbations, I describe the subtle effects that may rise from conservation laws and their connection to linear response transport using microscopic models. Then, I describe thermalisation in the context of the eigenstate thermalisation hypothesis and its consequence to multipartite entanglement and high-order correlation functions. Finally, motivated by the necessity of describing quantum thermal machines in the finite-temperature regime, I introduce a novel tensor-network based method to investigate thermodynamic properties of autonomous machines that employ interacting many-body systems as working media.
Technological and scientific advances have given rise to an era in which coherent quantum-mechanical phenomena can be probed and experimentally-realised over unprecedented timescales in condensed matter physics. In turn, scientific interest in non-equilibrium dynamics and irreversibility signatures of thermodynamics has taken place in recent decades, particularly in relation to cold-atom platforms and thermoelectric devices. In this PhD thesis I summarise some of the most important results obtained over the duration of my PhD, on the topic of thermodynamics involving interacting many-body quantum systems. The topics of discussion encompass three main themes: spin/particle transport in non-integrable systems, explorations in eigenstate thermalisation and finite-temperature transport in autonomous thermal machines. By questioning the effect of local integrability-breaking perturbations, I describe the subtle effects that may rise from conservation laws and their connection to linear response transport using microscopic models. Then, I describe thermalisation in the context of the eigenstate thermalisation hypothesis and its consequence to multipartite entanglement and high-order correlation functions. Finally, motivated by the necessity of describing quantum thermal machines in the finite-temperature regime, I introduce a novel tensor-network based method to investigate thermodynamic properties of autonomous machines that employ interacting many-body systems as working media.
The ability of classical thermodynamics to predict phenomena using only handful of parameters is miraculous. Moreover, this framework contrasts with other theories with its ability to describe our day to day experience, i. e. we know intuitively that an ice cube melts in a cold beverage on a hot summer day. A similarly powerful yet significantly less intuitive theory is quantum mechanics which describes the world at its tiniest length scales. Given this foundational position, we would expect to be able to derive all physical theories from quantum mechanics only. Unfortunately this would require knowing the quantum state of all particles which is costly as quantum mechanics requires resources growing exponentially in the system size to describe even relatively innocent many-body systems. Given this uncontrollable growth of parameters, it is highly desirable to apply the principles of thermodynamics to quantum many-body systems as a means to describe them ef- ficiently. Yet, the two theories are not obviously compatible. Subtle differences such as the definition of thermalisation already puzzled founding fathers like John von Neumann. While these have been understood by now, the focus shifted to gaining a thorough understanding of the process of thermalisation in the quantum regime, meaning that the state of the system can be described by a thermal ensemble locally after an initial out-of-equilibrium situation. In the recent past the field of quantum thermodynamics and specifically out-of-equilibrium dynamics has witnessed many successes notably the advent of highly controllable analogue quantum simulators which allow to probe out-of-equilibrium physics to an unprecedented precision. It has been established that thermalisation takes place in quantum many-body systems, but the underlying reasons and a comprehensive theory are still elusive. Only very recently, a class of systems exhibiting many-body localisation has been identi ed that defy this paradigm of thermalisation by localising their constituent particles despite many-body interactions. This can be captured using an effective description in terms of local constants of motion. Understanding the emergence of these physically relevant operators that hinder thermalisation hopefully sheds light also on the mechanism of thermalisation itself. In this thesis, we investigate the relation between thermodynamics and quantum mechanics in the context of out-of-equilibrium physics for many-body localisation. We give numerical evidence for the stability of localisation in large, closed onedimensional chains. Furthermore, we connect the established phenomenology of many-body localisation to experiments with ultra-cold atoms in optical lattices and give a blue print of measurements that can be performed with existing technology to show that the simulator indeed exhibits many-body localisation. We then set out to obtain a deeper understanding of the underlying theory of many-body localisation by devising an algorithm that explicitly constructs exact constants of motion allowing us to put the existing theoretical framework of many-body localisation to the test. It is our firm belief that understanding local constants of motion is indispensable to not only understand thermalisation in quantum many-body systems but is also of great use in other fields. A connection of this type is displayed by an extension of our algorithm to finding edge modes in spin chains with symmetry protected order.
This thesis investigates quantum-many body systems out of equilibrium in a variety of physically relevant and intriguing settings. It provides an overview of the recent developments in this field and based on the author’s recent review illuminates many interesting connections and summarises open questions. In this general framework, the various results of the author are embedded. While they often rely on advanced mathematics, great care is taken to present them in an intuitive way and most technical material is discussed separately in appendices. In the context of equilibration, work created as part of this thesis is able to capture the Gaussification of correlated initial states for a large class of free models. This allows to significantly extend equilibration results of free models, which are of crucial importance, as they provide reasonable relaxation time scales and immediately connect to our physical intuition in terms of ballistic spreading. Building on two surprising connections between static and dynamic features of Hamiltonians, which in general are hard to obtain, the results of this thesis further greatly contribute to the recent debate on the true nature of quantum many- body localisation. For those interacting models, we derive the localised structure of eigenstates from a dynamical suppression of information propagation on the low-energy sector. Further, we show how a non-degenerate spectrum, indicating the presence of interactions, and the existence of an approximately local constant of motion are sufficient to show information propagation, if arbitrary energies are allowed. In the context of quantum phase transitions, we continue such connections between static and dynamic features. We specifically investigate the Mott-superfluid transition of the Bose-Hubbard model and ask to what extent it has a universal dynamical signature. In a joint experimental, numerical and analytical effort, complex behaviour of these dynamics is uncovered, thus challenging the common believe that the Kibble-Zurek mechanism is sufficient to fully capture such transitions. We embed such experimental investigation in the recent debate on quantum simulators, which give the exciting perspective of solving notoriously and even provably hard problems efficiently in the laboratory. For such devices, we argue that the final read-out of the results is an important out- standing problem to be solved. We approach this issue in the case of a continuous quantum field, in which the notion of reconstructing the quantum state is even conceptually unclear. Based on tensor network methods, we demonstrate that in an experiment of ultra-cold atoms in a continuous setup, states can nevertheless efficiently be obtained. Thus, this thesis constitutes not only an important review of the field of quantum many-body systems out of equilibrium, but, using advanced mathematical and numerical tools, has significantly contributed to our understanding of various important out- standing questions in interacting many-body systems.
To understand in detail the relation between unitary quantum theory that describes our world at the microscopic scale and thermodynamics, which was long believed only to apply to macroscopic objects, is one of the most interesting and long-standing problems in physics. Recently, this problem has received renewed attention, in particular from the community of quantum information theory, but also from the field of statistical mechanics, inspired from stochastic thermodynamics. These results suggest that thermodynamics is also relevant for individual quantum systems, provided that they can be brought into contact with thermal baths. In this thesis, I use recently developed tools to provide new results both on fundamental questions, but also on questions which are of practical relevance for potential miniaturized thermal machines. In terms of fundamental questions, the results in this thesis contribute to understanding how the basic laws of thermodynamics and statistical mechanics can be understood directly from unitary quantum mechanics. In particular, I discuss and answer the following questions: i) How can we quantify the third law of thermodynamics using information theoretic methods? ii) How can we quantify the "thermodynamic value" of a state-transition in quantum systems? iii) How can we axiomatically characterize the non-equilibrium free energy and relative entropy? iv) How can we justify statistical ensembles from an operational perspective, without having to introduce either some probability measures or an information theoretic entropy measure? v) How can we understand the equilibration of closed quantum systems, how long does it take and how difficult is it to avoid? In the second part of the thesis I discuss in detail how experimental restrictions, which become important at the quantum scale, influence the ultimate thermodynamic bounds for thermal machines. In particular, the results in this thesis provide thermodynamic bounds on work-extraction and efficiencies of thermal machines in situations where 1.) an experimenter only has limited field strengths available, 2.) an experimenter cannot control the interactions between particles, but external fields arbitrarily well, and 3.) situations in which a small quantum system can only be strongly coupled to heat baths. These bounds are tight and I provide explicit examples illustrating the different behaviours. Finally, I come back to a classic problem in statistical physics: The emergence of spontaneous symmetry breaking. Here, I provide general and rigorous new results that show how symmetry-breaking stationary states emerge from fluctuations in order parameters in dissipative lattice models.
The question of how statistical physics can be seen to emerge from unitary quantum dynamics goes back to Schrödinger and von Neumann, however has been reaffirmed as a topic of importance due to recent advances in experimental capabilities, allowing the observation of the unitary evolution of many-particle systems over long periods of time. Understanding why such a system evolves to the specific thermal equilibrium state, effectively described by a relevant thermodynamic ensemble, has thus seen significantly more interest in recent years. Furthermore, observations of the dynamics of such systems open questions on the route to equilibrium, and subsequent fluctuations. In this thesis I will develop an approach to this problem, taking as a starting point the non-integrability of the system under study, which leads to a generic model in terms of random matrix theory (RMT), and more generally, chaotic wavefunctions. In the formulation of these methods, special attention is paid to the form of local observables of quantum systems, and an approach to their description is developed in terms of correlation functions of chaotic wavefunctions. From this approach a key conjecture in the understanding of thermalization, the eigenstate thermalization hypothesis (ETH), is derived in full, and the dynamical behaviour of such observables is obtained analytically. Further, I will show that emergent classical behaviour can be observed in the form of a fluctuation-dissipation theorem (FDT) of Brownian processes. This is exploited to develop an experimental proposal to measure the ‘complexity’ of a quantum device, by experimentally obtaining its effective Hilbert space dimension in terms of a fully connected system. Finally, quantum jump trajectories, describing stroboscopic projective measurements of local observables are studied, and shown to display classical Brownian dynamics in the form of a Markov process. Throughout this thesis, exact diagonalization calculations of realistic quantum spin systems are used to confirm analytical results.
During recent years the interest to dynamics of quantum systems has grown considerably. Quantum many body systems out of equilibrium often manifest behavior, different from the one predicted by standard statistical mechanics and thermodynamics in equilibrium. Since the dynamics of a many body quantum system typically involve many excited eigenstates, with a non-thermal distribution, the time evolution of such a system provides an unique way for investigation of non-equilibrium quantum statistical mechanics. Last decade such new subjects like quantum quenches, thermalization, pre-thermalization, equilibration, generalized Gibbs ensemble, etc. are among the most attractive topics of investigation in modern quantum physics. One of the most interesting themes in the study of dynamics of quantum many-body systems out of equilibrium is connected with the recently proposed important concept of dynamical quantum phase transitions. During the last few years a great progress has been achieved in studying of those singularities in the time dependence of characteristics of quantum mechanical systems, in particular, in understanding how the quantum critical points of equilibrium thermodynamics affect their dynamical properties. Dynamical quantum phase transitions reveal universality, scaling, connection to the topology, and many other interesting features. Here we review the recent achievements of this quickly developing part of low temperature quantum physics. The study of dynamical quantum phase transitions is especially important in context of their connection to the problem of the modern theory of quantum information, where namely non-equilibrium dynamics of many-body quantum system plays the major role.
Relatively small many-body quantum systems are often used as hardware for quantum devices. Most of these devices will operate below the thermal limit where thermodynamics must be treated differently to account for quantum behaviours. It is therefore imperative that the thermodynamic properties of these systems are well understood, especially as they can limit the technologies but also help the fabrication and running of efficient quantum devices. \n \nIn this thesis we study quantum work and entropy production in closed many-body quantum systems out-of-equilibrium. We find that, for the systems studied, the largest average quantum work can be extracted in adiabatic weakly correlated regimes. These regimes are also seen to minimise the entropy produced, making them efficient regimes in which to operate devices based on these systems. \n \nAdiabatic evolutions are important for many quantum devices, and so it is important that they can be accurately characterised. The validity of current methods has been questioned recently, so in this thesis we propose the use of metrics as a good quantitative measure to characterise adiabaticity. We found that the density distance (a more accessible quantity than the wavefunction and its distance measures) alone can determine adiabaticity in a range of quantum systems, even at finite temperature. \n \nHowever, when calculating properties of many-body systems, there are many challenges often resulting in the need to approximate. In this thesis we propose a new style of approximation for quantum thermodynamic properties, taking inspiration from density functional theory (DFT). This new style uses the exact initial state of the system but approximates the dynamics and is seen to be computationally cheap but largely accurate. We test this with non-interacting and DFT approximated dynamics, finding that, surprisingly, the non-interacting dynamics give the most accurate results in most regimes, with the cheapest cost.