We study the Caldeira-Leggett model where a quantum Brownian particle interacts with an environment or a bath consisting of a collection of harmonic oscillators in the path-integral formalism. Compared to the contours that the paths take in the conventional Schwinger-Keldysh formalism, the paths in our study are deformed in the complex time plane as suggested by the recent study by C. Aron, G. Biroli, and L. F. Cugliandolo [SciPost Phys. 4, 008 (2018)10.21468/SciPostPhys.4.1.008]. This is done to investigate the connection between the symmetry properties in the Schwinger-Keldysh action and the equilibrium or nonequilibrium nature of the dynamics in an open quantum system. We derive the influence functional explicitly in this setting, which captures the effect of the coupling to the bath. We show that in equilibrium the action and the influence functional are invariant under a set of transformations of path-integral variables. The fluctuation-dissipation relation is obtained as a consequence of this symmetry. When the system is driven by an external time-dependent protocol, the symmetry is broken. From the terms that break the symmetry, we derive a quantum Jarzynski-like equality for a quantum mechanical worklike quantity given as a function of fluctuating quantum trajectory. In the classical limit, the transformations becomes those used in the functional integral formalism of the classical stochastic thermodynamics to derive the classical fluctuation theorem.
We unveil the universal (model-independent) symmetry satisfied by Schwinger-Keldysh quantum field theories whenever they describe equilibrium dynamics. This is made possible by a generalization of the Schwinger-Keldysh path-integral formalism in which the physical time can be re-parametrized to arbitrary contours in the complex plane. Strong relations between correlation functions, such as the fluctuation-dissipation theorems, are derived as immediate consequences of this symmetry of equilibrium. In this view, quantum non-equilibrium dynamics – e.g. when driving with a time-dependent potential – are seen as symmetry-breaking processes. The symmetry-breaking terms of the action are identified as a measure of irreversibility, or entropy creation, defined at the level of a single quantum trajectory. Moreover, they are shown to obey quantum fluctuation theorems. These results extend stochastic thermodynamics to the quantum realm.
Extended quantum systems can be theoretically described in terms of the Schwinger-Keldysh functional integral formalism, whose action conveniently describes both dynamical and static properties. We show here that in thermal equilibrium, defined by the validity of fluctuation-dissipation relations, the action of a quantum system is invariant under a certain symmetry transformation, and thus it is distinguished from generic systems. In turn, the fluctuation-dissipation relations can be derived as the Ward-Takahashi identities associated with this symmetry. Accordingly, the latter provides an efficient test for the onset of thermodynamic equilibrium and it makes checking the validity of fluctuation-dissipation relations unnecessary. In the classical limit, this symmetry reduces to the well-known one that characterizes equilibrium in the stochastic dynamics of classical systems coupled to thermal baths, described by Langevin equations.
This thesis explores the concept of quantum work within the framework of the Keldysh contour approach, a technique rooted in the non-equilibrium dynamics of quantum systems. The work begins with a review of classical fluctuation relations and their quantum counterparts, emphasizing the challenges in defining work in quantum systems due to the lack of a unique trajectory in phase space. Utilizing the two-point measurement protocol, we derive the characteristic function of quantum work and discuss its implications for the symmetry properties in quantum thermodynamics. A key contribution of this thesis is the formulation of a path-integral representation for quantum work, leading to the identification of a work-like functional. This functional is shown to be directly related to the breaking of symmetry in out-of-equilibrium dynamics. The results presented extend the applicability of fluctuation theorems and offer new insights into the role of symmetry in quantum thermodynamic processes.
Building upon the work of Hu, Paz, and Zhang [1,2] on open quantum systems we consider the quantum Brownian motion (QBM) model with one oscillator (position variable
x) as the system, {\it nonlinearly} coupled to an environment of
N harmonic oscillators (with mass
mn, natural frequency
ωn, position
qn and momentum
pn variables) in the form
∑n(vn1(x)qnk+vn2(x)pnl) where
k,l are integers (the present work only considers the
k=l=2 cases). The vertex functions $v_{n1}, v_{n2} $ are of the form
vn1=λCn1f(x),vn2(x)=−λCn2mn−2ωn−2f(x) where
Cn1,2 are the coupling constants with the
nth oscillator,
f(x) is any arbitrary function of
x, and
λ is a dimensionless constant. Employing the closed-time-path formalism the influence action
SIF is calculated using a perturbative expansion in
λ. It is possible to identify the terms in
SIF quadratic or higher in
Δ(s)≡f(x+(s))−f(x−(s)) to constitute the noise kernel, while terms linear in
Δ to that of the dissipation kernel. The non-Gaussian noise kernel gives rise to non-zero three-point correlation function of the corresponding stochastic force. The pathway presented here should be useful for the exploration of \textit{non-Gaussian properties of systems nonlinearly coupled with their environments}; examples in early universe cosmology and in quantum optomechanics (QOM) are mentioned. A modified fluctuation-dissipation relation (FDR) is also established, which ensures the consistency of the model and the accuracy of results even at higher perturbative orders. Another result of significance is the derivation of a nonlinear Langevin equation which is expected to be useful for many open quantum system applications.
This chapter demonstrates the equivalence between Feynman–Vernon influence functional approach and Keldysh diagram technique developed to describe non-equilibrium phenomena in quantum many-body systems with interactions. Path integrals appearing in both quantum mechanics and quantum field theory may be viewed as a formal representation of the exact infinite series of Feynman diagrams. In other words, path integral and diagram techniques are formally equivalent to each other. The chapter discusses a single degree of freedom, introducing interactions with a bath of harmonic oscillators. In a way, to employ the Caldeira–Leggett model of a bath of harmonic oscillators can be considered just as a physical trick helping to derive the influence functional in the case of linear Ohmic damping. Gaussian influence functionals are exact provided the environment consists of an arbitrary number of harmonic oscillators coupled linearly to the system of interest q .
The Caldeira-Leggett model of quantum Brownian motion is generalized using a generic velocity-dependent coupling. That leads to the description of a set of models able to capture Markovian and non-Markovian versions of Brownian and L\'evy statistics, depending on the functional form of the coupling and on the spectral function of the reservoir. One specific coupling force is found that establishes a connection with L\'evy statistics of cold atoms in Sisyphus laser cooling. In the low-velocity limit, this also gives rise to additional inertia of the Brownian particle, reproducing the Abraham-Lorentz equation from first principles for a superohmic bath. Through path-integral quantization in Euclidean time, the environment is integrated out, leaving a set of nonlocal effective actions. These results further serve as starting points for several numerical calculations, particularly decoherence properties of nonohmic baths.