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arXiv:1505.00912 · Physical Review B

Thermodynamic equilibrium as a symmetry of the Schwinger-Keldysh action

Lukas M. Sieberer, Alessio Chiocchetta, Andrea Gambassi, Uwe Claus Täuber, Sebastian Diehl

Published Oct 28, 2015• 112 citations
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Abstract

Extended quantum systems can be theoretically described in terms of the Schwinger-Keldysh functional integral formalism, whose action conveniently describes both dynamical and static properties. We show here that in thermal equilibrium, defined by the validity of fluctuation-dissipation relations, the action of a quantum system is invariant under a certain symmetry transformation, and thus it is distinguished from generic systems. In turn, the fluctuation-dissipation relations can be derived as the Ward-Takahashi identities associated with this symmetry. Accordingly, the latter provides an efficient test for the onset of thermodynamic equilibrium and it makes checking the validity of fluctuation-dissipation relations unnecessary. In the classical limit, this symmetry reduces to the well-known one that characterizes equilibrium in the stochastic dynamics of classical systems coupled to thermal baths, described by Langevin equations.

DOI
10.1103/physrevb.92.134307

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Extended quantum systems can be theoretically described in terms of the Schwinger-Keldysh functional integral formalism, whose action conveniently describes both dynamical and static properties. We show here that in thermal equilibrium, defined by the validity of fluctuation-dissipation relations, the action of a quantum system is invariant under a certain symmetry transformation, and thus it is distinguished from generic systems. In turn, the fluctuation-dissipation relations can be derived as the Ward-Takahashi identities associated with this symmetry. Accordingly, the latter provides an efficient test for the onset of thermodynamic equilibrium and it makes checking the validity of fluctuation-dissipation relations unnecessary. In the classical limit, this symmetry reduces to the well-known one that characterizes equilibrium in the stochastic dynamics of classical systems coupled to thermal baths, described by Langevin equations.
We unveil the universal (model-independent) symmetry satisfied by Schwinger-Keldysh quantum field theories whenever they describe equilibrium dynamics. This is made possible by a generalization of the Schwinger-Keldysh path-integral formalism in which the physical time can be re-parametrized to arbitrary contours in the complex plane. Strong relations between correlation functions, such as the fluctuation-dissipation theorems, are derived as immediate consequences of this symmetry of equilibrium. In this view, quantum non-equilibrium dynamics – e.g. when driving with a time-dependent potential – are seen as symmetry-breaking processes. The symmetry-breaking terms of the action are identified as a measure of irreversibility, or entropy creation, defined at the level of a single quantum trajectory. Moreover, they are shown to obey quantum fluctuation theorems. These results extend stochastic thermodynamics to the quantum realm.
We study the Caldeira-Leggett model where a quantum Brownian particle interacts with an environment or a bath consisting of a collection of harmonic oscillators in the path-integral formalism. Compared to the contours that the paths take in the conventional Schwinger-Keldysh formalism, the paths in our study are deformed in the complex time plane as suggested by the recent study by C. Aron, G. Biroli, and L. F. Cugliandolo [SciPost Phys. 4, 008 (2018)10.21468/SciPostPhys.4.1.008]. This is done to investigate the connection between the symmetry properties in the Schwinger-Keldysh action and the equilibrium or nonequilibrium nature of the dynamics in an open quantum system. We derive the influence functional explicitly in this setting, which captures the effect of the coupling to the bath. We show that in equilibrium the action and the influence functional are invariant under a set of transformations of path-integral variables. The fluctuation-dissipation relation is obtained as a consequence of this symmetry. When the system is driven by an external time-dependent protocol, the symmetry is broken. From the terms that break the symmetry, we derive a quantum Jarzynski-like equality for a quantum mechanical worklike quantity given as a function of fluctuating quantum trajectory. In the classical limit, the transformations becomes those used in the functional integral formalism of the classical stochastic thermodynamics to derive the classical fluctuation theorem.
This chapter is devoted to the classical limit of the quantum dissipative action obtained in Chapter 3. We show how it yields Langevin, Fokker–Planck and optimal path descriptions of classical stochastic systems. These approaches are used to discuss activation escape, fluctuation relation, reaction models and other examples. Classical dissipative action In Section 3.2 we derived the Keldysh action for a quantum particle coupled to an Ohmic environment, Eq. (3.20). If only linear terms in the quantum coordinate X q (t) are kept in this action, it leads to a classical Newtonian equation with a viscous friction force, Eq. (3.21). Such an approximation completely disregards any fluctuations: both quantum and classical . Our goal now is to do better than that and to keep classical thermal fluctuations, while still neglecting quantum effects. To this end it is convenient to restore the Planck constant ħ in the action and then take the limit ħ → 0. For dimensional reasons, the factor ħ -1 should stay in front of the entire action. To keep the part of the action responsible for the classical equation of motion (3.21) free from the Planck constant it is convenient to rescale the quantum component as X q → ħ X q . Indeed, when this is done all terms linear in X q do not contain ħ. Finally, to have the temperature in energy units, one needs to substitute T with T /ħ.
Abstract The deterministic and time-reversal symmetric dynamics of isolated quantum systems is at odds with irreversible equilibration observed in generic thermodynamic systems. Standard approaches at a reconciliation employ subjective restrictions on the space of observables or states and do not explain how a single macroscopic quantum system achieves equilibrium dynamically. We instead argue that quantum theory is an effective theory and requires corrections to accurately describe systems approaching the thermodynamic limit. We construct a stochastic extension of quantum theory which is practically identical to quantum mechanics for microscopic systems, yet allows individual macroscopic and isolated systems to objectively thermalize, generically. A fluctuation–dissipation relation guarantees physical consistency including norm preservation, energy conservation, no superluminal signalling and the emergence of microcanonical equilibrium. We further discuss the inclusion of objective collapse, thereby realizing a falsifiable theory of spontaneous universal irreversibility which describes the quantum-to-classical crossover dynamics of macroscopic quantum systems. The dynamics of the model describe spontaneous symmetry breaking, quantum state reduction and objective quantum thermalization for individual systems, while realizing emergent hybrid statistics for ensembles that integrate Born’s rule and microcanonical equilibrium.
This thesis explores the concept of quantum work within the framework of the Keldysh contour approach, a technique rooted in the non-equilibrium dynamics of quantum systems. The work begins with a review of classical fluctuation relations and their quantum counterparts, emphasizing the challenges in defining work in quantum systems due to the lack of a unique trajectory in phase space. Utilizing the two-point measurement protocol, we derive the characteristic function of quantum work and discuss its implications for the symmetry properties in quantum thermodynamics. A key contribution of this thesis is the formulation of a path-integral representation for quantum work, leading to the identification of a work-like functional. This functional is shown to be directly related to the breaking of symmetry in out-of-equilibrium dynamics. The results presented extend the applicability of fluctuation theorems and offer new insights into the role of symmetry in quantum thermodynamic processes.