Abstract The deterministic and time-reversal symmetric dynamics of isolated quantum systems is at odds with irreversible equilibration observed in generic thermodynamic systems. Standard approaches at a reconciliation employ subjective restrictions on the space of observables or states and do not explain how a single macroscopic quantum system achieves equilibrium dynamically. We instead argue that quantum theory is an effective theory and requires corrections to accurately describe systems approaching the thermodynamic limit. We construct a stochastic extension of quantum theory which is practically identical to quantum mechanics for microscopic systems, yet allows individual macroscopic and isolated systems to objectively thermalize, generically. A fluctuation–dissipation relation guarantees physical consistency including norm preservation, energy conservation, no superluminal signalling and the emergence of microcanonical equilibrium. We further discuss the inclusion of objective collapse, thereby realizing a falsifiable theory of spontaneous universal irreversibility which describes the quantum-to-classical crossover dynamics of macroscopic quantum systems. The dynamics of the model describe spontaneous symmetry breaking, quantum state reduction and objective quantum thermalization for individual systems, while realizing emergent hybrid statistics for ensembles that integrate Born’s rule and microcanonical equilibrium.
Abstract The deterministic and time-reversal symmetric dynamics of isolated quantum systems is at odds with irreversible equilibration observed in generic thermodynamic systems. Standard approaches at a reconciliation employ subjective restrictions on the space of observables or states and do not explain how a single macroscopic quantum system achieves equilibrium dynamically. We instead argue that quantum theory is an effective theory and requires corrections to accurately describe systems approaching the thermodynamic limit. We construct a stochastic extension of quantum theory which is practically identical to quantum mechanics for microscopic systems, yet allows individual macroscopic and isolated systems to objectively thermalize, generically. A fluctuation–dissipation relation guarantees physical consistency including norm preservation, energy conservation, no superluminal signalling and the emergence of microcanonical equilibrium. We further discuss the inclusion of objective collapse, thereby realizing a falsifiable theory of spontaneous universal irreversibility which describes the quantum-to-classical crossover dynamics of macroscopic quantum systems. The dynamics of the model describe spontaneous symmetry breaking, quantum state reduction and objective quantum thermalization for individual systems, while realizing emergent hybrid statistics for ensembles that integrate Born’s rule and microcanonical equilibrium.
Quantum mechanics is widely recognised as being incomplete. It is not consistent with the second law of thermodynamics and does not provide a scientifically credible physical account of the measurement process, the means by which coherence is broken and classically observable states are recorded. This has led to many ad hoc assumptions being used to account for various properties of quantum systems, among which is the coherence time of quantum devices that determines their ability to perform computations. Here, we show that all these properties can be accommodated naturally and consistently in the context of mixing quantum systems which exhibit continuous spectra, as arises in the thermodynamic limit in quantum statistical mechanics and quantum gravity. In particular, for isolated systems we show that the time-reversal symmetry associated with unitary time evolution of the quantum state gives rise to time-symmetry breaking and a semi-group evolution which attains thermodynamic equilibrium at long times. Moreover, the emergence of this non-unitary time-asymmetry leads to microcanonical equilibrium states in which all quantum coherence is lost and is accompanied by the transformation of pure states into mixtures, leading in turn to an increase in entropy. Inclusion of a macroscopic measurement apparatus shows how the outcome of a measurement corresponds to the von Neumann projection postulate, arising with probabilities in conformance with the Born rule. The mathematical structure of the theory which applies to quantum systems with continuous spectra is closely analogous to the classical ergodic theory of dynamical systems and the conditions under which they attain equilibrium states.
The collapse of the wave function remains one of the deepest puzzles in quantum mechanics. The Schrödinger equation is unitary and time-reversal symmetric, yet measurement requires an additional postulate that is neither—and we have no physical explanation for why. Existing interpretations either deny that collapse is real (Many-Worlds), treat it as purely subjective (QBism), or add stochastic noise by hand without deriving it from fundamental principles (GRW, CSL). We demonstrate that collapse is a real physical process requiring fundamentally irreversible dynamics. No purely unitary, time-symmetric theory can account for the objective suppression of macroscopic superpositions—irreversibility must be built into the dynamics from the start. We introduce a minimal extension of quantum mechanics through coupling to a universal scalar field (the I-field) governed by an explicit time-asymmetric field equation. Collapse emerges objectively through deterministic dissipative dynamics, with no reference to observers, measurement devices, or stochastic noise. By integrating out the I-field degrees of freedom, we derive effective Lindblad dynamics for quantum systems. The collapse rate scales quadratically with system mass, ensuring microscopic quantum coherence remains intact while macroscopic superpositions are dynamically suppressed. Unlike stochastic collapse models (GRW/CSL), the mechanism is deterministic and produces no spontaneous heating. Unlike gravitational collapse proposals (Diósi-Penrose), it provides explicit field equations rather than heuristic arguments. Unlike environmental decoherence, the irreversibility is fundamental rather than effective. The theory respects relativistic causality and makes testable predictions for current and near-future experiments in matter-wave interferometry, optomechanical systems, and molecular interferometry. Observation of mass-dependent decoherence without accompanying stochastic heating would provide strong evidence for the I-field mechanism. The framework establishes irreversibility as a fundamental interaction rather than an emergent phenomenon, providing a unified physical origin for both wave function collapse and the quantum arrow of time.
The challenge of understanding quantum measurement persists as a fundamental issue in modern physics. Particularly, the abrupt and energy-nonconserving collapse of the wave function appears to contradict classical thermodynamic laws. The contradiction can be resolved by considering measurement itself to be an entropy-increasing process, driven by the second law of thermodynamics. One such resolution explains the apparently irreversible emergence of objective outcomes in an isolated, unitarily evolving quantum system via the theory of closed-system equilibration. Working within this framework, we construct the set of “” that best encode the measurement statistics of a system in an objective manner and establish a measurement error bound to quantify the probability an observer will obtain an incorrect measurement outcome. Using this error bound, we show that the objectifying observables readily equilibrate on average under the set of Hamiltonians which preserve the outcome statistics on the measured system. Using a random matrix model for this set, we numerically determine the measurement error bound, finding that the error only approaches zero with increasing environment size when the environment is coarse grained into so-called observer systems. This indicates the necessity of coarse graining an environment for the emergence of objective, classical measurement outcomes.
To understand in detail the relation between unitary quantum theory that describes our world at the microscopic scale and thermodynamics, which was long believed only to apply to macroscopic objects, is one of the most interesting and long-standing problems in physics. Recently, this problem has received renewed attention, in particular from the community of quantum information theory, but also from the field of statistical mechanics, inspired from stochastic thermodynamics. These results suggest that thermodynamics is also relevant for individual quantum systems, provided that they can be brought into contact with thermal baths. In this thesis, I use recently developed tools to provide new results both on fundamental questions, but also on questions which are of practical relevance for potential miniaturized thermal machines. In terms of fundamental questions, the results in this thesis contribute to understanding how the basic laws of thermodynamics and statistical mechanics can be understood directly from unitary quantum mechanics. In particular, I discuss and answer the following questions: i) How can we quantify the third law of thermodynamics using information theoretic methods? ii) How can we quantify the "thermodynamic value" of a state-transition in quantum systems? iii) How can we axiomatically characterize the non-equilibrium free energy and relative entropy? iv) How can we justify statistical ensembles from an operational perspective, without having to introduce either some probability measures or an information theoretic entropy measure? v) How can we understand the equilibration of closed quantum systems, how long does it take and how difficult is it to avoid? In the second part of the thesis I discuss in detail how experimental restrictions, which become important at the quantum scale, influence the ultimate thermodynamic bounds for thermal machines. In particular, the results in this thesis provide thermodynamic bounds on work-extraction and efficiencies of thermal machines in situations where 1.) an experimenter only has limited field strengths available, 2.) an experimenter cannot control the interactions between particles, but external fields arbitrarily well, and 3.) situations in which a small quantum system can only be strongly coupled to heat baths. These bounds are tight and I provide explicit examples illustrating the different behaviours. Finally, I come back to a classic problem in statistical physics: The emergence of spontaneous symmetry breaking. Here, I provide general and rigorous new results that show how symmetry-breaking stationary states emerge from fluctuations in order parameters in dissipative lattice models.
The question of how irreversibility can emerge as a generic phenomenon when the underlying mechanical theory is reversible has been a long-standing fundamental problem for both classical and quantum mechanics. We describe a mechanism for the appearance of irreversibility that applies to coherent, isolated systems in a pure quantum state. This equilibration mechanism requires only an assumption of sufficiently complex internal dynamics and natural information-theoretic constraints arising from the infeasibility of collecting an astronomical amount of measurement data. Remarkably, we are able to prove that irreversibility can be understood as typical without assuming decoherence or restricting to coarse-grained observables, and hence occurs under distinct conditions and time scales from those implied by the usual decoherence point of view. We illustrate the effect numerically in several model systems and prove that the effect is typical under the standard random-matrix conjecture for complex quantum systems.
Focusing on isolated macroscopic systems, described in terms of either a quantum mechanical or a classical model, our two key questions are how far does an initial ensemble (usually far from equilibrium and largely unknown in detail) evolve towards a stationary long-time behavior (equilibration) and how far is this steady state in agreement with the microcanonical ensemble as predicted by statistical mechanics (thermalization). A recently developed quantum mechanical treatment of the problem is briefly summarized, putting particular emphasis on the realistic modeling of experimental measurements and nonequilibrium initial conditions. Within this framework, equilibration can be proven under very weak assumptions about those measurements and initial conditions, while thermalization still requires quite strong additional hypotheses. An analogous approach within the framework of classical mechanics is developed and compared with the quantum case. In particular, the assumptions to guarantee classical equilibration are now rather strong, while thermalization then follows under relatively weak additional conditions.