In thermodynamics, quantum coherences-superpositions between energy eigenstates-behave in distinctly nonclassical ways. Here we describe how thermodynamic coherence splits into two kinds-"internal" coherence that admits an energetic value in terms of thermodynamic work, and "external" coherence that does not have energetic value, but instead corresponds to the functioning of the system as a quantum clock. For the latter form of coherence, we provide dynamical constraints that relate to quantum metrology and macroscopicity, while for the former, we show that quantum states exist that have finite internal coherence yet with zero deterministic work value. Finally, under minimal thermodynamic assumptions, we establish a clock-work trade-off relation between these two types of coherences. This can be viewed as a form of time-energy conjugate relation within quantum thermodynamics that bounds the total maximum of clock and work resources for a given system.
In thermodynamics, quantum coherences-superpositions between energy eigenstates-behave in distinctly nonclassical ways. Here we describe how thermodynamic coherence splits into two kinds-"internal" coherence that admits an energetic value in terms of thermodynamic work, and "external" coherence that does not have energetic value, but instead corresponds to the functioning of the system as a quantum clock. For the latter form of coherence, we provide dynamical constraints that relate to quantum metrology and macroscopicity, while for the former, we show that quantum states exist that have finite internal coherence yet with zero deterministic work value. Finally, under minimal thermodynamic assumptions, we establish a clock-work trade-off relation between these two types of coherences. This can be viewed as a form of time-energy conjugate relation within quantum thermodynamics that bounds the total maximum of clock and work resources for a given system.
The principle of superposition is one of the main building blocks of quantum physics and has tremendous consequences both for our fundamental understanding of nature and for technological applications. In particular, the existence of coherent superposition leads to the concept of unavoidable quantum uncertainty. The role played by this "coherent" uncertainty within thermodynamics, as well as its relationship to classical lack of knowledge, is the main subject of this thesis. In Part I we study thermodynamic limitations of processing quantum coherence within a resource-theoretic framework. Using the time-translation symmetry that arises from the first law of thermodynamics, we find constraints on possible manipulations of coherence and prove their irreversibility due to the second law. We also generalise to the quantum domain Szilard's concept of converting information into work. Namely, we show how, in the presence of a heat bath, coherence of a system can be exploited to perform mechanical work. Finally, we analyse the effect that coherence has on the structure of the thermodynamic arrow of time, i.e., on the set of states into which a given state can freely evolve under thermodynamic constraints. In Part II we focus on the interplay between quantum and classical uncertainty manifested in uncertainty relations. We show that separating the total uncertainty into these two distinct components leads to a new type of "fixed-entropy" uncertainty relation. We also analyse how classical ignorance affects the structure of states that minimise the unavoidable uncertainty arising from the noncommutativity of two observables. Finally, we study error-disturbance trade-off relations and, by proving that quantum uncertainty can be simultaneously maximised for any two observables, we clarify the unphysical nature of state-dependent relations.
Even though our microscopic physical theories, such as classical or quantum mechanics, are time-reversal invariant, time appears to march forward irreversibly. It is widely believed that effective entropy increase due to the second law of thermodynamics is at the origin of this emergent arrow of time. Any system that is out of thermal equilibrium and produces entropy can thus be used as a clock, be it a melting ice cube or a sophisticated atomic clock. The understanding of entropy in physics has significantly advanced with the advent of information theory in the last century. It has also led to the insight that the amount of entropy a clock produces is linked to how precisely the clock works, and thereby, how much information the clock reveals about the passage of time. In this thesis, we ask: what fundamental limits does the underlying physical theory impose on the precision of clocks within that theory? To rigorously answer this question, we devise a minimal clock model within quantum theory. By consistently modeling all clock constituents as quantum systems, we can ensure we account for all the resources used by the clock. This includes, in particular, the readout. Classically, one can obtain this for free, but quantum mechanically, this has a resource cost associated with it. To this end, we consolidate existing frameworks that describe clocks in both classical and quantum theory. Revising fluctuation theorems from quantum thermodynamics, we demonstrate how such theorems impose limits on the attainable precision of clocks. These precision bounds turn out to be more stringent for classical systems than for quantum ones. Quantum clocks can harness coherence and correlations to suppress fluctuations, allowing them to exponentially surpass precision bounds that hold for classical clocks. We show this separation between classical and quantum clocks by constructing an explicit example that uses quantum dynamics to saturate the quantum precision bounds. Finally, we close the thesis by exploring implications of these timekeeping bounds beyond fundamental science in quantum technologies. We show how quantum clocks can be used to quantify the energetic cost of quantum computation by linking computational fidelity to thermodynamic entropy production.
The role of coherence in quantum thermodynamics has been extensively studied in the recent years and it is now well-understood that coherence between different energy eigenstates is a resource independent of other thermodynamics resources, such as work. A fundamental remaining open question is whether the laws of quantum mechanics and thermodynamics allow the existence of a coherence distillation machine, i.e., a machine that, by possibly consuming work, obtains pure coherent states from mixed states, at a nonzero rate. This is related to another fundamental question: Starting from many copies of noisy quantum clocks which are (approximately) synchronized with a reference clock, can one distill synchronized clocks in pure states, at a non-zero rate? Surprisingly, we find that the answer to both questions is negative for generic (full-rank) mixed states. However, at the same time, it is possible to distill a sub-linear number of pure coherent states with a vanishing error.
In the framework of quantum thermodynamics preparing a quantum system in a general state requires the consumption of two distinct resources, namely, work and energetic coherence. It has been shown that the work cost of preparing a quantum state is determined by its free energy. Considering a similar setting, here we determine the coherence cost of preparing a general state when there are no restrictions on work consumption. More precisely, the coherence cost is defined as the minimum rate of consumption of systems in a pure coherent state, that is needed to prepare copies of the desired system. We show that the coherence cost of any system is determined by its quantum Fisher information about the time parameter, hence introducing a new operational interpretation of this central quantity of quantum metrology. Our resource-theoretic approach also reveals a previously unnoticed connection between two fundamental properties of quantum Fisher information.
In the framework of quantum thermodynamics preparing a quantum system in a general state requires the consumption of two distinct resources, namely, work and energetic coherence. It has been shown that the work cost of preparing a quantum state is determined by its free energy. Considering a similar setting, here we determine the coherence cost of preparing a general state when there are no restrictions on work consumption. More precisely, the coherence cost is defined as the minimum rate of consumption of systems in a pure coherent state, that is needed to prepare copies of the desired system. We show that the coherence cost of any system is determined by its quantum Fisher information about the time parameter, hence introducing a new operational interpretation of this central quantity of quantum metrology. Our resource-theoretic approach also reveals a previously unnoticed connection between two fundamental properties of quantum Fisher information.
Both conservation laws and practical restrictions impose symmetry constraints on the dynamics of open quantum systems. In the case of time-translation symmetry, which arises naturally in many physically relevant scenarios, the quantum coherence between energy eigenstates becomes a valuable resource for quantum information processing. In this work, we identify the minimum amount of decoherence compatible with this symmetry for a given population dynamics. This yields a generalization to higher-dimensional systems of the relation ${T}_{2}\ensuremath{\le}2{T}_{1}$ for qubit decoherence and relaxation times. It also enables us to witness and assess the role of non-Markovianity as a resource for coherence preservation and transfer. Moreover, we discuss the relationship between ergodicity and the ability of Markovian dynamics to indefinitely sustain a superposition of different energy states. Finally, we establish a formal connection between the resource-theoretic and the master equation approaches to thermodynamics, with the former being a non-Markovian generalization of the latter. Our work thus brings the abstract study of quantum coherence as a resource towards the realm of actual physical applications.