Even though our microscopic physical theories, such as classical or quantum mechanics, are time-reversal invariant, time appears to march forward irreversibly. It is widely believed that effective entropy increase due to the second law of thermodynamics is at the origin of this emergent arrow of time. Any system that is out of thermal equilibrium and produces entropy can thus be used as a clock, be it a melting ice cube or a sophisticated atomic clock. The understanding of entropy in physics has significantly advanced with the advent of information theory in the last century. It has also led to the insight that the amount of entropy a clock produces is linked to how precisely the clock works, and thereby, how much information the clock reveals about the passage of time. In this thesis, we ask: what fundamental limits does the underlying physical theory impose on the precision of clocks within that theory? To rigorously answer this question, we devise a minimal clock model within quantum theory. By consistently modeling all clock constituents as quantum systems, we can ensure we account for all the resources used by the clock. This includes, in particular, the readout. Classically, one can obtain this for free, but quantum mechanically, this has a resource cost associated with it. To this end, we consolidate existing frameworks that describe clocks in both classical and quantum theory. Revising fluctuation theorems from quantum thermodynamics, we demonstrate how such theorems impose limits on the attainable precision of clocks. These precision bounds turn out to be more stringent for classical systems than for quantum ones. Quantum clocks can harness coherence and correlations to suppress fluctuations, allowing them to exponentially surpass precision bounds that hold for classical clocks. We show this separation between classical and quantum clocks by constructing an explicit example that uses quantum dynamics to saturate the quantum precision bounds. Finally, we close the thesis by exploring implications of these timekeeping bounds beyond fundamental science in quantum technologies. We show how quantum clocks can be used to quantify the energetic cost of quantum computation by linking computational fidelity to thermodynamic entropy production.
Even though our microscopic physical theories, such as classical or quantum mechanics, are time-reversal invariant, time appears to march forward irreversibly. It is widely believed that effective entropy increase due to the second law of thermodynamics is at the origin of this emergent arrow of time. Any system that is out of thermal equilibrium and produces entropy can thus be used as a clock, be it a melting ice cube or a sophisticated atomic clock. The understanding of entropy in physics has significantly advanced with the advent of information theory in the last century. It has also led to the insight that the amount of entropy a clock produces is linked to how precisely the clock works, and thereby, how much information the clock reveals about the passage of time. In this thesis, we ask: what fundamental limits does the underlying physical theory impose on the precision of clocks within that theory? To rigorously answer this question, we devise a minimal clock model within quantum theory. By consistently modeling all clock constituents as quantum systems, we can ensure we account for all the resources used by the clock. This includes, in particular, the readout. Classically, one can obtain this for free, but quantum mechanically, this has a resource cost associated with it. To this end, we consolidate existing frameworks that describe clocks in both classical and quantum theory. Revising fluctuation theorems from quantum thermodynamics, we demonstrate how such theorems impose limits on the attainable precision of clocks. These precision bounds turn out to be more stringent for classical systems than for quantum ones. Quantum clocks can harness coherence and correlations to suppress fluctuations, allowing them to exponentially surpass precision bounds that hold for classical clocks. We show this separation between classical and quantum clocks by constructing an explicit example that uses quantum dynamics to saturate the quantum precision bounds. Finally, we close the thesis by exploring implications of these timekeeping bounds beyond fundamental science in quantum technologies. We show how quantum clocks can be used to quantify the energetic cost of quantum computation by linking computational fidelity to thermodynamic entropy production.
Time remains one of the least well-understood concepts in physics, most notably in quantum mechanics.A central goal is to find the fundamental limits of measuring time.One of the main obstacles is the fact that time is not an observable and thus has to be measured indirectly.Here, we explore these questions by introducing a model of time measurements that is complete and autonomous.Specifically, our autonomous quantum clock consists of a system out of thermal equilibrium-a prerequisite for any system to function as a clock-powered by minimal resources, namely, two thermal baths at different temperatures.Through a detailed analysis of this specific clock model, we find that the laws of thermodynamics dictate a trade-off between the amount of dissipated heat and the clock's performance in terms of its accuracy and resolution.Our results furthermore imply that a fundamental entropy production is associated with the operation of any autonomous quantum clock, assuming that quantum machines cannot achieve perfect efficiency at finite power.More generally, autonomous clocks provide a natural framework for the exploration of fundamental questions about time in quantum theory and beyond.
The emergence of irreversibility in physical processes, despite the fundamentally reversible nature of quantum mechanics, remains an open question in physics. This thesis explores the intricate relationship between quantum mechanics and thermodynamics, with a particular focus on minimizing entropy production in finite-time processes. By employing tools from quantum information theory and geometric thermodynamics, we tackle the challenge of deriving irreversible thermodynamic behavior from the reversible microscopic framework of quantum mechanics. We begin with a comprehensive review of the laws of thermodynamics, setting the stage for the subsequent analyses. We introduce novel developments in quantum thermodynamics through a generalized framework for geometric thermodynamics, which enables the derivation of finite-time corrections beyond the Markovian regime. Building on this foundation, we extend Landauer's principle by incorporating a finite-time correction that highlights the necessity of strong coupling for optimal information erasure processes. This result underscores the emergence of Planckian time as a fundamental speed limit to thermalization. Additionally, we explore how collective effects can be harnessed to reduce energy dissipation in thermodynamic operations, revealing that classical correlations between systems can significantly mitigate dissipation, though this may pose new questions regarding the third law of thermodynamics. Finally, we optimize thermodynamic processes in mesoscopic systems, including quantum dot engines and information engines. These findings not only enhance our understanding of the fundamental limits of irreversibility but also open new avenues for research. Future works will focus on fully exploiting collective effects, aligning these with the third law of thermodynamics, and understanding the thermodynamic consistency of master equations.
Time remains one of the least well-understood concepts in physics, most notably in quantum mechanics.A central goal is to find the fundamental limits of measuring time.One of the main obstacles is the fact that time is not an observable and thus has to be measured indirectly.Here, we explore these questions by introducing a model of time measurements that is complete and autonomous.Specifically, our autonomous quantum clock consists of a system out of thermal equilibrium-a prerequisite for any system to function as a clock-powered by minimal resources, namely, two thermal baths at different temperatures.Through a detailed analysis of this specific clock model, we find that the laws of thermodynamics dictate a trade-off between the amount of dissipated heat and the clock's performance in terms of its accuracy and resolution.Our results furthermore imply that a fundamental entropy production is associated with the operation of any autonomous quantum clock, assuming that quantum machines cannot achieve perfect efficiency at finite power.More generally, autonomous clocks provide a natural framework for the exploration of fundamental questions about time in quantum theory and beyond.
The problem of time is a deep paradox in our physical description of the world. According to Aristotle's relational theory, time is a measure of change and does not exist on its own. In contrast, quantum mechanics, just like Newtonian mechanics, is equipped with a master clock that dictates the evolution of a system. This clock is infinitely precise and tacitly supplied free of charge from outside physics. Not only does this absolute time make it notoriously difficult to make a consistent theory of quantum gravity, it is also the underlying problem in establishing the second law. Indeed, contrary to our experience, the Wheeler-deWitt equation --a canonical quantization of general relativity-- predicts a static universe. Similarly, when simply concerned with the dynamics of a closed quantum system, there is no second law because the Von Neumann entropy is invariant under unitary transformations. Here we are mainly concerned with the latter problem and we show that it can be resolved by attributing a minimal amount of resources to the measurement of time. Although there is an absolute time in quantum mechanics, an observer can only establish a time by measuring a clock. For a local measurement, the minimal entropy production is equal to the number of ticks. This lower bound is attained by a black hole.
To understand in detail the relation between unitary quantum theory that describes our world at the microscopic scale and thermodynamics, which was long believed only to apply to macroscopic objects, is one of the most interesting and long-standing problems in physics. Recently, this problem has received renewed attention, in particular from the community of quantum information theory, but also from the field of statistical mechanics, inspired from stochastic thermodynamics. These results suggest that thermodynamics is also relevant for individual quantum systems, provided that they can be brought into contact with thermal baths. In this thesis, I use recently developed tools to provide new results both on fundamental questions, but also on questions which are of practical relevance for potential miniaturized thermal machines. In terms of fundamental questions, the results in this thesis contribute to understanding how the basic laws of thermodynamics and statistical mechanics can be understood directly from unitary quantum mechanics. In particular, I discuss and answer the following questions: i) How can we quantify the third law of thermodynamics using information theoretic methods? ii) How can we quantify the "thermodynamic value" of a state-transition in quantum systems? iii) How can we axiomatically characterize the non-equilibrium free energy and relative entropy? iv) How can we justify statistical ensembles from an operational perspective, without having to introduce either some probability measures or an information theoretic entropy measure? v) How can we understand the equilibration of closed quantum systems, how long does it take and how difficult is it to avoid? In the second part of the thesis I discuss in detail how experimental restrictions, which become important at the quantum scale, influence the ultimate thermodynamic bounds for thermal machines. In particular, the results in this thesis provide thermodynamic bounds on work-extraction and efficiencies of thermal machines in situations where 1.) an experimenter only has limited field strengths available, 2.) an experimenter cannot control the interactions between particles, but external fields arbitrarily well, and 3.) situations in which a small quantum system can only be strongly coupled to heat baths. These bounds are tight and I provide explicit examples illustrating the different behaviours. Finally, I come back to a classic problem in statistical physics: The emergence of spontaneous symmetry breaking. Here, I provide general and rigorous new results that show how symmetry-breaking stationary states emerge from fluctuations in order parameters in dissipative lattice models.
Physical devices operating out of equilibrium are affected by thermal fluctuations, limiting their operational precision. This issue is particularly pronounced at microscopic and quantum scales, where its mitigation requires additional entropy dissipation. Understanding this constraint is important for both fundamental physics and technological design. Clocks, for example, need a thermodynamic flux towards equilibrium to measure time, resulting in a minimum entropy dissipation per clock tick. Although classical and quantum models often show a linear relationship between precision and dissipation, the ultimate bounds on this relationship remain unclear. Here we present an autonomous quantum many-body clock model that achieves clock precision that scales exponentially with entropy dissipation. This is enabled by coherent transport in a spin chain with tailored couplings, where dissipation is confined to a single link. The result demonstrates that coherent quantum dynamics can surpass the traditional thermodynamic precision limits, potentially guiding the development of future high-precision, low-dissipation quantum devices.