Time remains one of the least well-understood concepts in physics, most notably in quantum mechanics.A central goal is to find the fundamental limits of measuring time.One of the main obstacles is the fact that time is not an observable and thus has to be measured indirectly.Here, we explore these questions by introducing a model of time measurements that is complete and autonomous.Specifically, our autonomous quantum clock consists of a system out of thermal equilibrium-a prerequisite for any system to function as a clock-powered by minimal resources, namely, two thermal baths at different temperatures.Through a detailed analysis of this specific clock model, we find that the laws of thermodynamics dictate a trade-off between the amount of dissipated heat and the clock's performance in terms of its accuracy and resolution.Our results furthermore imply that a fundamental entropy production is associated with the operation of any autonomous quantum clock, assuming that quantum machines cannot achieve perfect efficiency at finite power.More generally, autonomous clocks provide a natural framework for the exploration of fundamental questions about time in quantum theory and beyond.
Time remains one of the least well-understood concepts in physics, most notably in quantum mechanics.A central goal is to find the fundamental limits of measuring time.One of the main obstacles is the fact that time is not an observable and thus has to be measured indirectly.Here, we explore these questions by introducing a model of time measurements that is complete and autonomous.Specifically, our autonomous quantum clock consists of a system out of thermal equilibrium-a prerequisite for any system to function as a clock-powered by minimal resources, namely, two thermal baths at different temperatures.Through a detailed analysis of this specific clock model, we find that the laws of thermodynamics dictate a trade-off between the amount of dissipated heat and the clock's performance in terms of its accuracy and resolution.Our results furthermore imply that a fundamental entropy production is associated with the operation of any autonomous quantum clock, assuming that quantum machines cannot achieve perfect efficiency at finite power.More generally, autonomous clocks provide a natural framework for the exploration of fundamental questions about time in quantum theory and beyond.
Time remains one of the least well-understood concepts in physics, most notably in quantum mechanics.A central goal is to find the fundamental limits of measuring time.One of the main obstacles is the fact that time is not an observable and thus has to be measured indirectly.Here, we explore these questions by introducing a model of time measurements that is complete and autonomous.Specifically, our autonomous quantum clock consists of a system out of thermal equilibrium-a prerequisite for any system to function as a clock-powered by minimal resources, namely, two thermal baths at different temperatures.Through a detailed analysis of this specific clock model, we find that the laws of thermodynamics dictate a trade-off between the amount of dissipated heat and the clock's performance in terms of its accuracy and resolution.Our results furthermore imply that a fundamental entropy production is associated with the operation of any autonomous quantum clock, assuming that quantum machines cannot achieve perfect efficiency at finite power.More generally, autonomous clocks provide a natural framework for the exploration of fundamental questions about time in quantum theory and beyond.
Thermodynamics is one of the core disciplines of physics, and despite its long history it is still a very active area of research. Particularly in the regime of non-equilibrium processes and at small scales many open questions remain. In this thesis we critically study the role that autonomous machines play in the emerging field of quantum thermodynamics. We show that autonomous machines generally comprise several interacting subsystems that can take on various roles. In Part I we look at the issue of external control. Any non-autonomous machine by definition requires some external agent to interact with the machine. This agent is generally assumed to be classical and to not suffer any back-actions from the machine. If all the involved systems are of microscopic size this approximation is no longer valid and we have to include all the control mechanisms within a unified quantum framework. We show that in order to avoid external control and operate autonomously, a machine that is to extract work from another system requires an inbuilt quantum clock. Being itself a finite-size quantum system, such a clock will inevitably experience back-actions and develop correlations with the other systems, which lead to its degradation as a time keeping device. We show that this degradation can be counteracted by a judicious choice of quantum measurements. These measurements not only allow us to stabilise the clock, but also magnify thermodynamic properties such as work from the quantum scale, where their definition can be ambiguous, to the well understood classical scale. In Part II we consider the scenario of an autonomous quantum machine interacting with a thermal environment, for which we are experimentally restricted to only observe a subset of all the possible environment interactions, while the remaining ones are hidden from direct observation. Using a modification of the notion of quantum jump trajectories we show that the visible interactions in many cases still allow us to make some inferences about the hidden interactions. We introduce a new quantity, the coarse-grained hidden entropy, which quantifies the entropy production in the hidden subsystem conditioned on our observations of the visible part. The total entropy production consisting of the sum of visible and coarse-grained hidden entropy is shown to satisfy an integral fluctuations theorem. Depending on the information flow between the subsystems, the hidden entropy can assume negative values in which case the hidden systems acts as a Maxwell's demon. This behaviour is also captured by a modified second law like inequality which gives a refinement of the conventional second law for autonomous quantum machines with continuous information flows between the machine's subsystems.
Even though our microscopic physical theories, such as classical or quantum mechanics, are time-reversal invariant, time appears to march forward irreversibly. It is widely believed that effective entropy increase due to the second law of thermodynamics is at the origin of this emergent arrow of time. Any system that is out of thermal equilibrium and produces entropy can thus be used as a clock, be it a melting ice cube or a sophisticated atomic clock. The understanding of entropy in physics has significantly advanced with the advent of information theory in the last century. It has also led to the insight that the amount of entropy a clock produces is linked to how precisely the clock works, and thereby, how much information the clock reveals about the passage of time. In this thesis, we ask: what fundamental limits does the underlying physical theory impose on the precision of clocks within that theory? To rigorously answer this question, we devise a minimal clock model within quantum theory. By consistently modeling all clock constituents as quantum systems, we can ensure we account for all the resources used by the clock. This includes, in particular, the readout. Classically, one can obtain this for free, but quantum mechanically, this has a resource cost associated with it. To this end, we consolidate existing frameworks that describe clocks in both classical and quantum theory. Revising fluctuation theorems from quantum thermodynamics, we demonstrate how such theorems impose limits on the attainable precision of clocks. These precision bounds turn out to be more stringent for classical systems than for quantum ones. Quantum clocks can harness coherence and correlations to suppress fluctuations, allowing them to exponentially surpass precision bounds that hold for classical clocks. We show this separation between classical and quantum clocks by constructing an explicit example that uses quantum dynamics to saturate the quantum precision bounds. Finally, we close the thesis by exploring implications of these timekeeping bounds beyond fundamental science in quantum technologies. We show how quantum clocks can be used to quantify the energetic cost of quantum computation by linking computational fidelity to thermodynamic entropy production.
We formulate a minimal model of a quantum particle detector as an autonomous quantum thermal machine. Our goal is to establish how entropy production, which is needed to maintain the detector out of equilibrium, is linked to the quality of the measurement process. Using our model, we perform a detailed investigation of the detector’s key performance characteristics: namely, detection efficiency, gain, jitter, dead time, and dark counts. We find that entropy production constrains both the efficiency and temporal precision of the detection process, in the sense that improved performance generally requires more dissipation. We also find that reducing either the detection jitter or dead time unavoidably increases the rate of dark counts. Our work establishes a quantitative connection between entropy production and the quality of the irreversible detection process, highlights fundamental tradeoffs in the performance of particle detectors, and provides a framework for further investigations of the non-equilibrium thermodynamics of quantum measurement and amplification.
The problem of time is a deep paradox in our physical description of the world. According to Aristotle's relational theory, time is a measure of change and does not exist on its own. In contrast, quantum mechanics, just like Newtonian mechanics, is equipped with a master clock that dictates the evolution of a system. This clock is infinitely precise and tacitly supplied free of charge from outside physics. Not only does this absolute time make it notoriously difficult to make a consistent theory of quantum gravity, it is also the underlying problem in establishing the second law. Indeed, contrary to our experience, the Wheeler-deWitt equation --a canonical quantization of general relativity-- predicts a static universe. Similarly, when simply concerned with the dynamics of a closed quantum system, there is no second law because the Von Neumann entropy is invariant under unitary transformations. Here we are mainly concerned with the latter problem and we show that it can be resolved by attributing a minimal amount of resources to the measurement of time. Although there is an absolute time in quantum mechanics, an observer can only establish a time by measuring a clock. For a local measurement, the minimal entropy production is equal to the number of ticks. This lower bound is attained by a black hole.
To understand in detail the relation between unitary quantum theory that describes our world at the microscopic scale and thermodynamics, which was long believed only to apply to macroscopic objects, is one of the most interesting and long-standing problems in physics. Recently, this problem has received renewed attention, in particular from the community of quantum information theory, but also from the field of statistical mechanics, inspired from stochastic thermodynamics. These results suggest that thermodynamics is also relevant for individual quantum systems, provided that they can be brought into contact with thermal baths. In this thesis, I use recently developed tools to provide new results both on fundamental questions, but also on questions which are of practical relevance for potential miniaturized thermal machines. In terms of fundamental questions, the results in this thesis contribute to understanding how the basic laws of thermodynamics and statistical mechanics can be understood directly from unitary quantum mechanics. In particular, I discuss and answer the following questions: i) How can we quantify the third law of thermodynamics using information theoretic methods? ii) How can we quantify the "thermodynamic value" of a state-transition in quantum systems? iii) How can we axiomatically characterize the non-equilibrium free energy and relative entropy? iv) How can we justify statistical ensembles from an operational perspective, without having to introduce either some probability measures or an information theoretic entropy measure? v) How can we understand the equilibration of closed quantum systems, how long does it take and how difficult is it to avoid? In the second part of the thesis I discuss in detail how experimental restrictions, which become important at the quantum scale, influence the ultimate thermodynamic bounds for thermal machines. In particular, the results in this thesis provide thermodynamic bounds on work-extraction and efficiencies of thermal machines in situations where 1.) an experimenter only has limited field strengths available, 2.) an experimenter cannot control the interactions between particles, but external fields arbitrarily well, and 3.) situations in which a small quantum system can only be strongly coupled to heat baths. These bounds are tight and I provide explicit examples illustrating the different behaviours. Finally, I come back to a classic problem in statistical physics: The emergence of spontaneous symmetry breaking. Here, I provide general and rigorous new results that show how symmetry-breaking stationary states emerge from fluctuations in order parameters in dissipative lattice models.