Both conservation laws and practical restrictions impose symmetry constraints on the dynamics of open quantum systems. In the case of time-translation symmetry, which arises naturally in many physically relevant scenarios, the quantum coherence between energy eigenstates becomes a valuable resource for quantum information processing. In this work, we identify the minimum amount of decoherence compatible with this symmetry for a given population dynamics. This yields a generalization to higher-dimensional systems of the relation ${T}_{2}\ensuremath{\le}2{T}_{1}$ for qubit decoherence and relaxation times. It also enables us to witness and assess the role of non-Markovianity as a resource for coherence preservation and transfer. Moreover, we discuss the relationship between ergodicity and the ability of Markovian dynamics to indefinitely sustain a superposition of different energy states. Finally, we establish a formal connection between the resource-theoretic and the master equation approaches to thermodynamics, with the former being a non-Markovian generalization of the latter. Our work thus brings the abstract study of quantum coherence as a resource towards the realm of actual physical applications.
Both conservation laws and practical restrictions impose symmetry constraints on the dynamics of open quantum systems. In the case of time-translation symmetry, which arises naturally in many physically relevant scenarios, the quantum coherence between energy eigenstates becomes a valuable resource for quantum information processing. In this work, we identify the minimum amount of decoherence compatible with this symmetry for a given population dynamics. This yields a generalization to higher-dimensional systems of the relation T2\ensuremath≤2T1 for qubit decoherence and relaxation times. It also enables us to witness and assess the role of non-Markovianity as a resource for coherence preservation and transfer. Moreover, we discuss the relationship between ergodicity and the ability of Markovian dynamics to indefinitely sustain a superposition of different energy states. Finally, we establish a formal connection between the resource-theoretic and the master equation approaches to thermodynamics, with the former being a non-Markovian generalization of the latter. Our work thus brings the abstract study of quantum coherence as a resource towards the realm of actual physical applications.
The first law of thermodynamics imposes not just a constraint on the energy content of systems in extreme quantum regimes but also symmetry constraints related to the thermodynamic processing of quantum coherence. We show that this thermodynamic symmetry decomposes any quantum state into mode operators that quantify the coherence present in the state. We then establish general upper and lower bounds for the evolution of quantum coherence under arbitrary thermal operations, valid for any temperature. We identify primitive coherence manipulations and show that the transfer of coherence between energy levels manifests irreversibility not captured by free energy. Moreover, the recently developed thermomajorization relations on block-diagonal quantum states are observed to be special cases of this symmetry analysis. Published by the American Physical Society 2015
A dynamical symmetry is employed to determine the structure of the quantum non-Markovian time-local master equation. Such a structure is composed from two components: scalar kinetic coefficients and the standard quantum Markovian operator form. The kinetic coefficients are generally time-dependent and incorporate information on the kinematics and memory effects, while the operators manifest the dynamical symmetry. Specifically, we focus on time-translation symmetric dynamics, where the Lindblad jump operators constitute the eigenoperators of the free dynamics. This symmetry is motivated by thermodynamic microscopic considerations, where strict energy conservation between system and environment imposes the time-translation symmetry. The construction is generalized to other symmetries, and to driven quantum systems. The formalism is illustrated by three exactly solvable non-Markovian models, where the exact reduced description exhibits a dynamical symmetric structure. The formal structure of the master equation leads to a first principle calculation of the exact kinetic coefficients. This opens the possibility to simulate in a modular fashion non-Markovian dynamics.
Planck found, when attempting to describe the way in which hot bodies glow, that energy at microscopic scales often comes in discrete chunks. Thus began the long and intimate relationship between the field of thermodynamics, which explores our ability to manipulate heat and other energy transfers between macroscopic systems, and quantum mechanics, which explains the dynamics of individual microscopic systems. Even as both our technology and our theoretical investigations have extended to ever-smaller devices, our understanding of quantum effects on thermodynamics has remained almost exclusively limited to the quantized nature of energy. There is much more, however, to quantum theory than energy quantization. In this thesis we focus on the property of quantum coherence, the ability of quantum systems to emulate Schrodinger’s cat and somehow be neither dead nor alive, but something completely different altogether. We provide a simple and elegant formulation for the processing of coherence in thermodynamics, relying on the fact that thermodynamical processes possess an underlying time-translation symmetry. This fact allows us to quantify the ways in which coherence can play an active role, facilitating otherwise impossible thermodynamic transformations. We argue that coherence should be thought of as a distinctly quantum-mechanical thermodynamic resource. By considering an isolated quantum system connected, for some period of time, to a thermal bath, we give fundamental limitations on how coherence can be irreversibly manipulated. These limitations are related to those dictated on energy transfer by the second law of thermodynamics. Others topics that are investigated here is what is the role of correlations at the smallest scales and the conversion of quantum coherence into work. It has long been appreciated that thermodynamics is subtly interlinked with the notion of information. This work provides evidence that, to apply the laws of thermodynamics to the smallest systems around us, we must develop deeper insights into the nature of quantum information.
Abstract We demonstrate, both analytically and experimentally, the usefulness of non-Markovianity for preserving correlations and coherence in quantum systems. For this, we consider a broad class of qubit evolutions, having a decoherence matrix separated from zero for large times. While any such Markovian evolution leads to an exponential loss of correlations, non-Markovianity can help to preserve correlations even in the limit t → ∞. In fact, under general assumptions, eternally non-Markovian evolution naturally emerges as the one that allows for optimal preservation of quantum correlations. For covariant qubit evolutions, we also show that non-Markovianity can be used to preserve quantum coherence at all times, which is an important resource for quantum metrology. We explicitly demonstrate this effect experimentally with linear optics, by implementing the optimal non-Markovian quantum evolution.
On its own, the invariance properties of Markovian master equations have mostly played a mathematical or computational role in the evaluation of quantum open system dynamics. Because all forms of the equation lead to the same time evolution for the state of the system, the fixation of a particular form has only gained physical meaning when correlated with additional information such as in the evolution of quantum trajectories or the study of decoherence-free subspaces. Here, we show that these symmetry transformations can be exploited, on their own, to optimize practical physical tasks. In particular, we present a general formulation showing how they can be used to change the measurable values of physical quantities regarding the exchange of energy and/or information with the environment. We also analyze examples of optimization in quantum thermodynamics and, finally, discuss practical implementations in terms of quantum trajectories. Published by the American Physical Society 2024
Quantum thermodynamics has emerged as a central field for understanding how energy conversion processes occur in microscopic systems. In these systems, effects such as coherence, entanglement, and non-Markovianity play key roles. In this thesis, we explore different ways to describe quantum thermodynamics, using two main approaches: one based on entropy and the other on ergotropy. First, we introduce a generalized approach to quantify non-Markovianity through the breakdown of monotonicity in thermodynamic functions. In this context, the entropy-based heat flow serves as a practical tool to witness and measure quantum memory in unital maps that do not reverse the sign of the internal energy. Next, we analyze the dynamics of ergotropy in open qubits under both Markovian and non-Markovian evolutions. We identify phenomena such as freezing and sudden death of ergotropy, and we establish an analytical relation between the change in ergotropy and the environment-induced work . This provides a clear physical interpretation for the additional term in the first law in the entropy-based formulation. Finally, we propose an ergotropy-based thermodynamic formulation, in which heat is reinterpreted in terms of the change of the passive state associated with the density operator governing the quantum dynamics. This approach allows one to measure non-Markovianity of unital maps more generally and accurately than the entropy-based heat flow. This advantage comes from the direct link between heat and von Neumann entropy, a property ensured by invariance under passive transformations. Moreover, the out-of-equilibrium temperature naturally remains non-negative, similarly to equilibrium thermodynamics.