The principle of superposition is one of the main building blocks of quantum physics and has tremendous consequences both for our fundamental understanding of nature and for technological applications. In particular, the existence of coherent superposition leads to the concept of unavoidable quantum uncertainty. The role played by this "coherent" uncertainty within thermodynamics, as well as its relationship to classical lack of knowledge, is the main subject of this thesis. In Part I we study thermodynamic limitations of processing quantum coherence within a resource-theoretic framework. Using the time-translation symmetry that arises from the first law of thermodynamics, we find constraints on possible manipulations of coherence and prove their irreversibility due to the second law. We also generalise to the quantum domain Szilard's concept of converting information into work. Namely, we show how, in the presence of a heat bath, coherence of a system can be exploited to perform mechanical work. Finally, we analyse the effect that coherence has on the structure of the thermodynamic arrow of time, i.e., on the set of states into which a given state can freely evolve under thermodynamic constraints. In Part II we focus on the interplay between quantum and classical uncertainty manifested in uncertainty relations. We show that separating the total uncertainty into these two distinct components leads to a new type of "fixed-entropy" uncertainty relation. We also analyse how classical ignorance affects the structure of states that minimise the unavoidable uncertainty arising from the noncommutativity of two observables. Finally, we study error-disturbance trade-off relations and, by proving that quantum uncertainty can be simultaneously maximised for any two observables, we clarify the unphysical nature of state-dependent relations.
The principle of superposition is one of the main building blocks of quantum physics and has tremendous consequences both for our fundamental understanding of nature and for technological applications. In particular, the existence of coherent superposition leads to the concept of unavoidable quantum uncertainty. The role played by this "coherent" uncertainty within thermodynamics, as well as its relationship to classical lack of knowledge, is the main subject of this thesis. In Part I we study thermodynamic limitations of processing quantum coherence within a resource-theoretic framework. Using the time-translation symmetry that arises from the first law of thermodynamics, we find constraints on possible manipulations of coherence and prove their irreversibility due to the second law. We also generalise to the quantum domain Szilard's concept of converting information into work. Namely, we show how, in the presence of a heat bath, coherence of a system can be exploited to perform mechanical work. Finally, we analyse the effect that coherence has on the structure of the thermodynamic arrow of time, i.e., on the set of states into which a given state can freely evolve under thermodynamic constraints. In Part II we focus on the interplay between quantum and classical uncertainty manifested in uncertainty relations. We show that separating the total uncertainty into these two distinct components leads to a new type of "fixed-entropy" uncertainty relation. We also analyse how classical ignorance affects the structure of states that minimise the unavoidable uncertainty arising from the noncommutativity of two observables. Finally, we study error-disturbance trade-off relations and, by proving that quantum uncertainty can be simultaneously maximised for any two observables, we clarify the unphysical nature of state-dependent relations.
Planck found, when attempting to describe the way in which hot bodies glow, that energy at microscopic scales often comes in discrete chunks. Thus began the long and intimate relationship between the field of thermodynamics, which explores our ability to manipulate heat and other energy transfers between macroscopic systems, and quantum mechanics, which explains the dynamics of individual microscopic systems. Even as both our technology and our theoretical investigations have extended to ever-smaller devices, our understanding of quantum effects on thermodynamics has remained almost exclusively limited to the quantized nature of energy. There is much more, however, to quantum theory than energy quantization. In this thesis we focus on the property of quantum coherence, the ability of quantum systems to emulate Schrodinger’s cat and somehow be neither dead nor alive, but something completely different altogether. We provide a simple and elegant formulation for the processing of coherence in thermodynamics, relying on the fact that thermodynamical processes possess an underlying time-translation symmetry. This fact allows us to quantify the ways in which coherence can play an active role, facilitating otherwise impossible thermodynamic transformations. We argue that coherence should be thought of as a distinctly quantum-mechanical thermodynamic resource. By considering an isolated quantum system connected, for some period of time, to a thermal bath, we give fundamental limitations on how coherence can be irreversibly manipulated. These limitations are related to those dictated on energy transfer by the second law of thermodynamics. Others topics that are investigated here is what is the role of correlations at the smallest scales and the conversion of quantum coherence into work. It has long been appreciated that thermodynamics is subtly interlinked with the notion of information. This work provides evidence that, to apply the laws of thermodynamics to the smallest systems around us, we must develop deeper insights into the nature of quantum information.
Quantum information science is at the interface of physics and information theory, with applications including quantum computing and communication. Within this science, a resource theory is a detailed study of a particular class of physical processes, under which the possible state transitions are restricted. Given any initial physical state, the possible final states are also restricted. Initial states with a wealth of possible final states can then be considered more valuable than less versatile initial states, leading to a notion of "resourcefulness" of states. The broad goals of a resource theory include (1) to identify, characterize, and quantify resources; (2) to find an efficient way to determine whether an arbitrary instance of resource conversion is possible; and (3) to relate practical applications to resource conversion. In this thesis, we will take the resource-theoretic approach to understanding thermodynamics. The mathematical methods used in this work will enable us to also develop resource theories for measurement uncertainty and reference frames; in fact, the resource-theoretic treatment of thermodynamics is a combination of these two. Our approach is based on a model called thermal operations, applicable on individual quantum-mechanical systems out of thermal equilibrium. We study this model in detail, resulting in a better understanding of the resource of thermal inequilibrium. In a simplified version of the model where quantum coherence is neglected, we find that the conditions for state transitions are already more complex than the classical second law of thermodynamics. We extend the model to quantum systems controlled by classical circuitry. We also extend it to incorporate quantum coherence in the low-temperature limit. Measurement uncertainty is an important element in quantum mechanics. But its current understanding is through particular measures of uncertainty, such as the variance. We apply the resource theory approach to develop a measure-independent formalism for uncertainty, even in the case where the measurement is on part of a composite system with quantum correlations. Under physical processes restricted by some symmetry (e.g. rotational symmetry), asymmetric states act as resourceful reference frames. In this resource theory, we find the rate at which large quantities of resources can be interconverted through measurements.
The emergence of irreversibility in physical processes, despite the fundamentally reversible nature of quantum mechanics, remains an open question in physics. This thesis explores the intricate relationship between quantum mechanics and thermodynamics, with a particular focus on minimizing entropy production in finite-time processes. By employing tools from quantum information theory and geometric thermodynamics, we tackle the challenge of deriving irreversible thermodynamic behavior from the reversible microscopic framework of quantum mechanics. We begin with a comprehensive review of the laws of thermodynamics, setting the stage for the subsequent analyses. We introduce novel developments in quantum thermodynamics through a generalized framework for geometric thermodynamics, which enables the derivation of finite-time corrections beyond the Markovian regime. Building on this foundation, we extend Landauer's principle by incorporating a finite-time correction that highlights the necessity of strong coupling for optimal information erasure processes. This result underscores the emergence of Planckian time as a fundamental speed limit to thermalization. Additionally, we explore how collective effects can be harnessed to reduce energy dissipation in thermodynamic operations, revealing that classical correlations between systems can significantly mitigate dissipation, though this may pose new questions regarding the third law of thermodynamics. Finally, we optimize thermodynamic processes in mesoscopic systems, including quantum dot engines and information engines. These findings not only enhance our understanding of the fundamental limits of irreversibility but also open new avenues for research. Future works will focus on fully exploiting collective effects, aligning these with the third law of thermodynamics, and understanding the thermodynamic consistency of master equations.
The first law of thermodynamics imposes not just a constraint on the energy content of systems in extreme quantum regimes but also symmetry constraints related to the thermodynamic processing of quantum coherence. We show that this thermodynamic symmetry decomposes any quantum state into mode operators that quantify the coherence present in the state. We then establish general upper and lower bounds for the evolution of quantum coherence under arbitrary thermal operations, valid for any temperature. We identify primitive coherence manipulations and show that the transfer of coherence between energy levels manifests irreversibility not captured by free energy. Moreover, the recently developed thermomajorization relations on block-diagonal quantum states are observed to be special cases of this symmetry analysis. Published by the American Physical Society 2015
Recent studies have developed fundamental limitations on nanoscale thermodynamics, in terms of a set of independent free energy relations. Here we show that free energy relations cannot properly describe quantum coherence in thermodynamic processes. By casting time-asymmetry as a quantifiable, fundamental resource of a quantum state we arrive at an additional, independent set of thermodynamic laws, that naturally extend the existing ones. These asymmetry relations reveal that the traditional Szilard engine argument does not extend automatically to quantum coherences, but instead only relational coherences in a multipartite scenario can contribute to thermodynamic work. We find that coherence transformations are always irreversible. Our results also reveal additional structural parallels between thermodynamics and entanglement theory.
To understand in detail the relation between unitary quantum theory that describes our world at the microscopic scale and thermodynamics, which was long believed only to apply to macroscopic objects, is one of the most interesting and long-standing problems in physics. Recently, this problem has received renewed attention, in particular from the community of quantum information theory, but also from the field of statistical mechanics, inspired from stochastic thermodynamics. These results suggest that thermodynamics is also relevant for individual quantum systems, provided that they can be brought into contact with thermal baths. In this thesis, I use recently developed tools to provide new results both on fundamental questions, but also on questions which are of practical relevance for potential miniaturized thermal machines. In terms of fundamental questions, the results in this thesis contribute to understanding how the basic laws of thermodynamics and statistical mechanics can be understood directly from unitary quantum mechanics. In particular, I discuss and answer the following questions: i) How can we quantify the third law of thermodynamics using information theoretic methods? ii) How can we quantify the "thermodynamic value" of a state-transition in quantum systems? iii) How can we axiomatically characterize the non-equilibrium free energy and relative entropy? iv) How can we justify statistical ensembles from an operational perspective, without having to introduce either some probability measures or an information theoretic entropy measure? v) How can we understand the equilibration of closed quantum systems, how long does it take and how difficult is it to avoid? In the second part of the thesis I discuss in detail how experimental restrictions, which become important at the quantum scale, influence the ultimate thermodynamic bounds for thermal machines. In particular, the results in this thesis provide thermodynamic bounds on work-extraction and efficiencies of thermal machines in situations where 1.) an experimenter only has limited field strengths available, 2.) an experimenter cannot control the interactions between particles, but external fields arbitrarily well, and 3.) situations in which a small quantum system can only be strongly coupled to heat baths. These bounds are tight and I provide explicit examples illustrating the different behaviours. Finally, I come back to a classic problem in statistical physics: The emergence of spontaneous symmetry breaking. Here, I provide general and rigorous new results that show how symmetry-breaking stationary states emerge from fluctuations in order parameters in dissipative lattice models.