Quantum information science is at the interface of physics and information theory, with applications including quantum computing and communication. Within this science, a resource theory is a detailed study of a particular class of physical processes, under which the possible state transitions are restricted. Given any initial physical state, the possible final states are also restricted. Initial states with a wealth of possible final states can then be considered more valuable than less versatile initial states, leading to a notion of "resourcefulness" of states. The broad goals of a resource theory include (1) to identify, characterize, and quantify resources; (2) to find an efficient way to determine whether an arbitrary instance of resource conversion is possible; and (3) to relate practical applications to resource conversion. In this thesis, we will take the resource-theoretic approach to understanding thermodynamics. The mathematical methods used in this work will enable us to also develop resource theories for measurement uncertainty and reference frames; in fact, the resource-theoretic treatment of thermodynamics is a combination of these two. Our approach is based on a model called thermal operations, applicable on individual quantum-mechanical systems out of thermal equilibrium. We study this model in detail, resulting in a better understanding of the resource of thermal inequilibrium. In a simplified version of the model where quantum coherence is neglected, we find that the conditions for state transitions are already more complex than the classical second law of thermodynamics. We extend the model to quantum systems controlled by classical circuitry. We also extend it to incorporate quantum coherence in the low-temperature limit. Measurement uncertainty is an important element in quantum mechanics. But its current understanding is through particular measures of uncertainty, such as the variance. We apply the resource theory approach to develop a measure-independent formalism for uncertainty, even in the case where the measurement is on part of a composite system with quantum correlations. Under physical processes restricted by some symmetry (e.g. rotational symmetry), asymmetric states act as resourceful reference frames. In this resource theory, we find the rate at which large quantities of resources can be interconverted through measurements.
Quantum information science is at the interface of physics and information theory, with applications including quantum computing and communication. Within this science, a resource theory is a detailed study of a particular class of physical processes, under which the possible state transitions are restricted. Given any initial physical state, the possible final states are also restricted. Initial states with a wealth of possible final states can then be considered more valuable than less versatile initial states, leading to a notion of "resourcefulness" of states. The broad goals of a resource theory include (1) to identify, characterize, and quantify resources; (2) to find an efficient way to determine whether an arbitrary instance of resource conversion is possible; and (3) to relate practical applications to resource conversion. In this thesis, we will take the resource-theoretic approach to understanding thermodynamics. The mathematical methods used in this work will enable us to also develop resource theories for measurement uncertainty and reference frames; in fact, the resource-theoretic treatment of thermodynamics is a combination of these two. Our approach is based on a model called thermal operations, applicable on individual quantum-mechanical systems out of thermal equilibrium. We study this model in detail, resulting in a better understanding of the resource of thermal inequilibrium. In a simplified version of the model where quantum coherence is neglected, we find that the conditions for state transitions are already more complex than the classical second law of thermodynamics. We extend the model to quantum systems controlled by classical circuitry. We also extend it to incorporate quantum coherence in the low-temperature limit. Measurement uncertainty is an important element in quantum mechanics. But its current understanding is through particular measures of uncertainty, such as the variance. We apply the resource theory approach to develop a measure-independent formalism for uncertainty, even in the case where the measurement is on part of a composite system with quantum correlations. Under physical processes restricted by some symmetry (e.g. rotational symmetry), asymmetric states act as resourceful reference frames. In this resource theory, we find the rate at which large quantities of resources can be interconverted through measurements.
Resource theories are a set of tools, coming from the field of quantum information theory, that find applications in the study of several physical scenarios. These theories describe the physical world from the perspective of an agent, who acts over a system to modify its quantum state, while having at disposal a limited set of operations. A noticeable example of a physical theory which has recently been described with these tools is quantum thermodynamics, consisting in the study of thermodynamic phenomena at the nano-scale. In the standard approach to resource theories, it is usually the case that the constraints over the set of available operations single out a unique resource. In this thesis, we extend the resource theoretic framework to include situations where multiple resources can be identified, and we apply our findings to the study of quantum thermodynamics, to gain a better understanding of quantities like work and heat in the microscopic regime. We introduce a mathematical framework to study resource theories with multiple resources, and we explore under which conditions these multi-resource theories are reversible. Furthermore, we investigate the interconversion of resources, i.e., in which situations it is possible to exchange between two different kinds of resources. We then apply this formalism to quantum thermodynamics, where the two resources under consideration are energy and entropy. This multi-resource theory allows us to explore thermodynamics when the system under examination is closed or coupled with a thermal environment with a finite size. In addition to our work on multi-resource theories, we study the states of equilibrium of closed systems, known as passive states, and analyse under which circumstances it is possible to extract energy from these states. We show that passivity is energetically unstable, and that, even for closed systems, the only stable states are those with a well-defined temperature.
A useful and unifying concept in quantum information theory is the idea of a consumable "resource". The basic idea behind quantum resource theories is that whenever we face restrictions on the set of operations we can perform, some states (resource states) enable us to perform particular tasks that otherwise would have been impossible. In this thesis we first review a resource theory that recently has gained a lot of attention, namely the resource theory of asymmetry in which one is restricted to symmetric operations and therefore asymmetric states are the resource states. The asymmetry properties of a state relative to some symmetry group specify how and to what extent the given symmetry is broken by the state. In the remainder of the thesis we explain how the ideas developed in this resource theory are related to three different areas in quantum theory: theory of quantum reference frames, the Wigner-Araki-Yanase(WAY) theorem and the conditional probability interpretation of time in quantum mechanics. Theory of quantum reference frames treats reference frames like any other physical system within the formalism of quantum theory, which causes the measurements to be an approximation of the measurements against their classical counterparts. We consider the dynamics of a quantum directional reference frame undergoing repeated interactions. These interactions induce a back-action on the reference which is the central focus of our study. The effect of a precise sequence of measurement outcomes on the reference frame is studied by looking at both the case that the measurement record is averaged over and the case wherein it is retained. We find, in particular, that there is interesting dynamics in the latter situation, which cannot be revealed by considering the average case. We then consider in detail how a sequence of rotationally invariant unitary interactions affects the reference frame, a situation, which leads to quite different dynamics than the case of repeated measurements. Different strategies for correcting reference frame drift is considered given that we have access to a set of particles with polarization opposite to the direction of drift. In particular, we find that, by implementing a suitably chosen unitary interaction after every two measurements, we can eliminate the rotational drift of the reference frame. The WAY theorem establishes an important constraint that conservation laws impose on quantum mechanical measurements. We formulate the WAY theorem in the broader context of resource theories, where one is constrained to a subset of quantum mechanical operations described by a symmetry group. Establishing connections with the theory of quantum state discrimination we obtain optimal unitaries describing the measurement of arbitrary observables, explain how prior information can permit perfect measurements that circumvent the WAY constraint, and provide a framework that establishes a natural ordering on measurement apparatuses through a decomposition into asymmetry and charge subsystems. Finally we review two di erent schemes in the conditional probability interpretation (CPI) of time in quantum mechanics. In these schemes parameter time "t" as it appears in Schrodinder equation is considered to be unobservable, yet one can use an extension of conditional probabilities in order to study dynamics of a system relative to another system, namely the quantum clock. We phrase CPI as a quantum communication protocol which enables us to use the machinery developed in the resource theory of asymmetry. This provides us with a deeper understanding of the decoherence effect caused due to the inaccessibility of the parameter time "t" and that how this effect can be suppressed by choosing an optimal initial state for the quantum clock.
Planck found, when attempting to describe the way in which hot bodies glow, that energy at microscopic scales often comes in discrete chunks. Thus began the long and intimate relationship between the field of thermodynamics, which explores our ability to manipulate heat and other energy transfers between macroscopic systems, and quantum mechanics, which explains the dynamics of individual microscopic systems. Even as both our technology and our theoretical investigations have extended to ever-smaller devices, our understanding of quantum effects on thermodynamics has remained almost exclusively limited to the quantized nature of energy. There is much more, however, to quantum theory than energy quantization. In this thesis we focus on the property of quantum coherence, the ability of quantum systems to emulate Schrodinger’s cat and somehow be neither dead nor alive, but something completely different altogether. We provide a simple and elegant formulation for the processing of coherence in thermodynamics, relying on the fact that thermodynamical processes possess an underlying time-translation symmetry. This fact allows us to quantify the ways in which coherence can play an active role, facilitating otherwise impossible thermodynamic transformations. We argue that coherence should be thought of as a distinctly quantum-mechanical thermodynamic resource. By considering an isolated quantum system connected, for some period of time, to a thermal bath, we give fundamental limitations on how coherence can be irreversibly manipulated. These limitations are related to those dictated on energy transfer by the second law of thermodynamics. Others topics that are investigated here is what is the role of correlations at the smallest scales and the conversion of quantum coherence into work. It has long been appreciated that thermodynamics is subtly interlinked with the notion of information. This work provides evidence that, to apply the laws of thermodynamics to the smallest systems around us, we must develop deeper insights into the nature of quantum information.
How far can we take the resource theoretic approach to explore physics? Resource theories like LOCC, reference frames and quantum thermodynamics have proven a powerful tool to study how agents who are subject to certain constraints can act on physical systems. This approach has advanced our understanding of fundamental physical principles, such as the second law of thermodynamics, and provided operational measures to quantify resources such as entanglement or information content. In this work, we significantly extend the approach and range of applicability of resource theories. Firstly we generalize the notion of resource theories to include any description or knowledge that agents may have of a physical state, beyond the density operator formalism. We show how to relate theories that differ in the language used to describe resources, like micro and macroscopic thermodynamics. Finally, we take a top-down approach to locality, in which a subsystem structure is derived from a global theory rather than assumed. The extended framework introduced here enables us to formalize new tasks in the language of resource theories, ranging from tomography, cryptography, thermodynamics and foundational questions, both within and beyond quantum theory.
The ideas of thermodynamics have proved fruitful in the setting of quantum information theory, in particular the notion that when the allowed transformations of a system are restricted, certain states of the system become useful resources with which one can prepare previously inaccessible states. The theory of entanglement is perhaps the best-known and most well-understood resource theory in this sense. Here, we return to the basic questions of thermodynamics using the formalism of resource theories developed in quantum information theory and show that the free energy of thermodynamics emerges naturally from the resource theory of energy-preserving transformations. Specifically, the free energy quantifies the amount of useful work which can be extracted from asymptotically many copies of a quantum system when using only reversible energy-preserving transformations and a thermal bath at fixed temperature. The free energy also quantifies the rate at which resource states can be reversibly interconverted asymptotically, provided that a sublinear amount of coherent superposition over energy levels is available, a situation analogous to the sublinear amount of classical communication required for entanglement dilution.
Quantum physics currently provides our deepest description of nature. To understand precisely how it differs from classical physics is not only of foundational interest, but also important to advance technology: the advent of quantum information has led to the insight that certain quantum phenomena, e.g., entanglement and coherence, are resources which enable us to solve practical tasks that are unsolvable within the realm of classical physics. But how can we quantify quantum resources and how do we decide which resource is relevant for a specific operational advantage in quantum cryptography, quantum computation, or quantum metrology? How can we employ these resources optimally? Addressing these questions is the motivation for the development of quantum resource theories, a mathematically rigorous framework that allows us to investigate a specific quantum phenomenon as a resource. Formally, such theories emerge from restrictions which are imposed in addition to the laws of quantum mechanics. A prominent example is the restriction to local operations and classical communication, which singles out entanglement as a resource. Typically, such theories describe the value of quantum states, i.e., static resources. An important question in such theories concerns their structure as determined by the restriction under consideration, which is analyzed for coherence theory on qubits in this thesis. Only recently, so-called dynamical resource theories that quantify the value of operations were proposed, which are advantageous for several reasons: they include resource theories of states as special cases, allow us to quantify additional quantum properties such as the detection or usage of static resources, which will be a main topic of this thesis, and are more natural from an operational perspective. But are different types of dynamical resources present in quantum operations related? For the case of dynamical coherence and entanglement, it will be shown that there is not only a quantitative, but also a qualitative connection.