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arXiv:1608.04977 · New Journal of Physics

Passivity and practical work extraction using Gaussian operations

Eric G Brown, Nicolai Friis, Marcus Huber

Published Nov 16, 2016• 69 citations
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Abstract

Quantum states that can yield work in a cyclical Hamiltonian process form one of the primary resources in the context of quantum thermodynamics. Conversely, states whose average energy cannot be lowered by unitary transformations are called passive. However, while work may be extracted from non-passive states using arbitrary unitaries, the latter may be hard to realize in practice. It is therefore pertinent to consider the passivity of states under restricted classes of operations that can be feasibly implemented. Here, we ask how restrictive the class of Gaussian unitaries is for the task of work extraction. We investigate the notion of Gaussian passivity, that is, we present necessary and sufficient criteria identifying all states whose energy cannot be lowered by Gaussian unitaries. For all other states we give a prescription for the Gaussian operations that extract the maximal amount of energy. Finally, we show that the gap between passivity and Gaussian passivity is maximal, i.e., Gaussian-passive states may still have a maximal amount of energy that is extractable by arbitrary unitaries, even under entropy constraints.

DOI
10.1088/1367-2630/18/11/113028

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Quantum states that can yield work in a cyclical Hamiltonian process form one of the primary resources in the context of quantum thermodynamics. Conversely, states whose average energy cannot be lowered by unitary transformations are called passive. However, while work may be extracted from non-passive states using arbitrary unitaries, the latter may be hard to realize in practice. It is therefore pertinent to consider the passivity of states under restricted classes of operations that can be feasibly implemented. Here, we ask how restrictive the class of Gaussian unitaries is for the task of work extraction. We investigate the notion of Gaussian passivity, that is, we present necessary and sufficient criteria identifying all states whose energy cannot be lowered by Gaussian unitaries. For all other states we give a prescription for the Gaussian operations that extract the maximal amount of energy. Finally, we show that the gap between passivity and Gaussian passivity is maximal, i.e., Gaussian-passive states may still have a maximal amount of energy that is extractable by arbitrary unitaries, even under entropy constraints.
One of the most fundamental tasks in quantum thermodynamics is extracting energy from one system and subsequently storing this energy in an appropriate battery. Both of these steps, work extraction and charging, can be viewed as cyclic Hamiltonian processes acting on individual quantum systems. Interestingly, so-called passive states exist, whose energy cannot be lowered by unitary operations, but it is safe to assume that the energy of any not fully charged battery may be increased unitarily. However, unitaries raising the average energy by the same amount may differ in qualities such as their precision, fluctuations, and charging power. Moreover, some unitaries may be extremely difficult to realize in practice. It is hence of crucial importance to understand the qualities that can be expected from practically implementable transformations. Here, we consider the limitations on charging batteries when restricting to the feasibly realizable family of Gaussian unitaries. We derive optimal protocols for general unitary operations as well as for the restriction to easier implementable Gaussian unitaries. We find that practical Gaussian battery charging, while performing significantly less well than is possible in principle, still offers asymptotically vanishing relative charge variances and fluctuations.
We investigate work extraction from noninteracting fermions under arbitrary unitary operations and the more restricted class of Gaussian unitary operations that can be feasibly implemented. We characterize general quantum states in fermionic systems according to their ability to yield work (or not) under such transformations and study the limit for which multiple copies of passive states in fermionic systems can be activated for work extraction. We find that a sufficient number of copies of nonthermal passive states can achieve this, yielding an upper bound on the number of copies needed.
Passive states are defined as those states that do not allow for work extraction in a cyclic (unitary) process. Within the set of passive states, thermal states are the most stable ones: they maximize the entropy for a given energy, and similarly they minimize the energy for a given entropy. Here we find the passive states lying in the other extreme, i.e., those that maximize the energy for a given entropy, which we show also minimize the entropy when the energy is fixed. These extremal properties make these states useful to obtain fundamental bounds for the thermodynamics of finite-dimensional quantum systems, which we show in several scenarios.
We consider the task of extracting work from quantum systems in the resource theory perspective of thermodynamics, where free states are arbitrary thermal states, and allowed operations are energy conserving unitary transformations. Taking as our work storage system a 'weight' we prove the second law and then present simple protocols which extract average work equal to the free energy change of the system - the same amount as in classical thermodynamics. Crucially, for systems in 'classical' states (mixtures of energy eigenstates) our protocol works on a single copy of the system. This is in sharp contrast to previous results, which showed that in case of almost-deterministic work extraction, collective actions on multiple copies are necessary to extract the free energy. This establishes the fact that free energy is a meaningful notion even for individual systems in classical states. However, for non-classical states, where coherences between energy levels exist, we prove that collective actions are necessary, so long as no external sources of coherence are used.
Free energy fixes the maximum work of a thermodynamic process once the state and Hamiltonian are specified. A work-extraction task asks a different question: how much average work can a single device realize across several preparations and Hamiltonian settings? A classical work device is one whose Hamiltonian settings are mutually commuting. We place every branch at its best free-energy-limited work envelope and derive the corresponding classical limit on the task average. For pure preparations, the source is specified only by pairwise maximal-energy constraints: for each pair, the intrinsic maximal average energy under one common normalized Hamiltonian is bounded as part of the task data, while the work device is otherwise microscopically unrestricted. The benchmark is optimized over arbitrary-dimensional classical implementations. Incompatible Hamiltonian settings exceed this limit, even though every branch remains bounded by its own free-energy maximum. The advantage therefore does not arise in any single process, but in the average work of the task: incompatible Hamiltonians realize a value that no classical work device can attain. Hamiltonian incompatibility is thus a thermodynamic resource for work extraction.
The second law of thermodynamics states that work cannot be extracted from thermal equilibrium, whose quantum formulation is known as complete passivity; a state is called completely passive if work cannot be extracted from any number of copies of the state by any unitary operations.It has been established that a quantum state is completely passive if and only if it is a Gibbs ensemble.In physically plausible setups, however, the class of possible operations is often restricted by fundamental constraints such as symmetries imposed on the system.In the present work, we investigate the concept of complete passivity under symmetry constraints.Specifically, we prove that a quantum state is completely passive under a symmetry constraint described by a connected compact Lie group, if and only if it is a generalized Gibbs ensemble including conserved charges associated with the symmetry.Remarkably, our result applies to noncommutative symmetry such as SU(2) symmetry, suggesting an unconventional extension of the notion of generalized Gibbs ensemble.Furthermore, we consider the setup where a quantum work storage is explicitly included, and prove that the characterization of complete passivity remains unchanged.Our result extends the notion of thermal equilibrium to systems protected by symmetries, and would lead to flexible design principles of quantum heat engines and batteries.Moreover, our approach serves as a foundation of the resource theory of thermodynamics in the presence of symmetries.