Passive states are defined as those states that do not allow for work extraction in a cyclic (unitary) process. Within the set of passive states, thermal states are the most stable ones: they maximize the entropy for a given energy, and similarly they minimize the energy for a given entropy. Here we find the passive states lying in the other extreme, i.e., those that maximize the energy for a given entropy, which we show also minimize the entropy when the energy is fixed. These extremal properties make these states useful to obtain fundamental bounds for the thermodynamics of finite-dimensional quantum systems, which we show in several scenarios.
Passive states are defined as those states that do not allow for work extraction in a cyclic (unitary) process. Within the set of passive states, thermal states are the most stable ones: they maximize the entropy for a given energy, and similarly they minimize the energy for a given entropy. Here we find the passive states lying in the other extreme, i.e., those that maximize the energy for a given entropy, which we show also minimize the entropy when the energy is fixed. These extremal properties make these states useful to obtain fundamental bounds for the thermodynamics of finite-dimensional quantum systems, which we show in several scenarios.
Passivity is a fundamental concept in thermodynamics that demands a quantum system's energy cannot be lowered by any reversible, unitary process acting on the system. In the limit of many such systems, passivity leads in turn to the concept of complete passivity, thermal states and the emergence of a thermodynamic temperature. Here we only consider a single system and show that every passive state except the thermal state is unstable under a weaker form of reversibility. Indeed, we show that given a single copy of any athermal quantum state, an optimal amount of energy can be extracted from it when we utilise a machine that operates in a reversible cycle. This means that for individual systems, the only form of passivity that is stable under general reversible processes is complete passivity, and thus provides a physically motivated identification of thermal states when we are not operating in the thermodynamic limit.
Abstract Passivity is a fundamental concept in thermodynamics that demands a quantum system’s energy cannot be lowered by any reversible, unitary process acting on the system. In the limit of many such systems, passivity leads in turn to the concept of complete passivity, thermal states and the emergence of a thermodynamic temperature. Here we only consider a single system and show that every passive state except the thermal state is unstable under a weaker form of reversibility. Indeed, we show that given a single copy of any athermal quantum state, an optimal amount of energy can be extracted from it when we utilise a machine that operates in a reversible cycle. This means that for individual systems, the only form of passivity that is stable under general reversible processes is complete passivity, and thus provides a physically motivated identification of thermal states when we are not operating in the thermodynamic limit.
Quantum states that can yield work in a cyclical Hamiltonian process form one of the primary resources in the context of quantum thermodynamics. Conversely, states whose average energy cannot be lowered by unitary transformations are called passive. However, while work may be extracted from non-passive states using arbitrary unitaries, the latter may be hard to realize in practice. It is therefore pertinent to consider the passivity of states under restricted classes of operations that can be feasibly implemented. Here, we ask how restrictive the class of Gaussian unitaries is for the task of work extraction. We investigate the notion of Gaussian passivity, that is, we present necessary and sufficient criteria identifying all states whose energy cannot be lowered by Gaussian unitaries. For all other states we give a prescription for the Gaussian operations that extract the maximal amount of energy. Finally, we show that the gap between passivity and Gaussian passivity is maximal, i.e., Gaussian-passive states may still have a maximal amount of energy that is extractable by arbitrary unitaries, even under entropy constraints.
Passive states are special configurations of a quantum system which exhibit no energy decrement at the end of an arbitrary cyclic driving of the model Hamiltonian. When applied to an increasing number of copies of the initial density matrix, the requirement of passivity induces a hierarchical ordering which, in the asymptotic limit of infinitely many elements, pinpoints ground states and thermal Gibbs states. In particular, for large values of N the energy content of a N -passive state which is also structurally stable (i.e. capable to maintain its passivity status under small perturbations of the model Hamiltonian), is expected to be close to the corresponding value of the thermal Gibbs state which has the same entropy. In the present paper we provide a quantitative assessment of this fact, by producing an upper bound for the energy of an arbitrary N -passive, structurally stable state which only depends on the spectral properties of the Hamiltonian of the system. We also show the condition under which our inequality can be saturated. A generalization of the bound is finally presented that, for sufficiently large N , applies to states which are N -passive, but not necessarily structurally stable.
Passive states, i.e., those states from which no work can be extracted via unitary operations, play an important role in the foundations and applications of quantum thermodynamics. They generalize the familiar Gibbs thermal states, which are the sole passive states being stable under tensor product. Here, we introduce a partial order on the set of passive states that captures the idea of a passive state being virtually cooler than another one. This partial order, which we build by defining the notion of relative passivity, offers a fine-grained comparison between passive states based on virtual temperatures (just like thermal states are compared based on their temperatures). We then characterize the quantum operations that are closed on the set of virtually cooler states with respect to some fixed input and output passive states. Viewing the activity, i.e., nonpassivity, of a state as a resource, our main result is then a necessary and sufficient condition on the transformation of a class of pure active states under these relative passivity-preserving operations. This condition gives a quantum thermodynamical meaning to the majorization relation on the set of nonincreasing vectors due to Hoffman. The maximum extractable work under relative passivity-preserving operations is then shown to be equal to the ergotropy of these pure active states. Finally, we are able to fully characterize passivity-preserving operations in the simpler case of qubit systems, and hence to derive a state interconversion condition under passivity-preserving qubit operations. The prospect of this work is a general resource-theoretical framework for the extractable work via quantum operations going beyond thermal operations.
Although entropy is a necessary and sufficient quantity to characterize the order of work content for equal energetic (EE) states in the asymptotic limit, for the finite quantum systems, the relation is not so linear and requires detailed investigation. Toward this, we have considered a resource theoretic framework taking the energy preserving operations (EPOs) as free, to compare the amount of extractable work from two different quantum states. Under the EPO, majorization becomes a necessary criterion for state transformation. It is also shown that the passive-state energy is a concave function, and, for EE states, it becomes proportional to the ergotropy in absolute sense. Invariance of the passive-state energy under unitary action on the given state makes it an entanglement measure for the pure bipartite states. Furthermore, due to the nonadditivity of passive-state energy for the different system Hamiltonians, one can generate Vidal^{'}s monotones which would give the optimal probability for pure entangled state transformation. This measure also quantifies the ergotropic gap which is employed to distinguish some specific classes of three-qubit pure entangled states.