Fluctuation theorem is derived for a quantum current system around a nonequilibrium steady state. It is demonstrated that the fluctuation theorem can be a part of the generalized Green-Kubo formula or a nonlinear response theory of an external field or a change of the chemical potential difference.
Quantum response theory is a cornerstone of statistical physics.However, the standard Kubo formalism is restricted to isolated equilibrium systems.We here generalize Kubo's results to open quantum systems in nonequilibrium steady states.We derive three different, but equivalent, forms of the quantum response function.We discuss for each of them the role of the noncommutativity of quantum operators and introduce a steady-state extension of the Kubo transformation.We show in particular that the equilibrium response vanishes for perturbations that commute with the unperturbed Hamiltonian, while the steady-state response does not, highlighting the profound difference between the two linear response theories.
Current quantum noise can be pictured as a sum over transitions through which the electronic system exchanges energy with its environment. We formulate this picture and use it to show which type of current correlators are measurable, and in what measurement the zero point fluctuations will play a role (the answer to the latter is as expected: only if the detector excites the system.) Using the above picture, we calculate and give physical interpretation of the finite-frequency finite-temperature current noise in a noninteracting Landauer-type system, where the chemical potentials of terminals 1 and 2 are μ+eV/2 and μ−eV/2 respectively, and derive a detailed-balance condition for this nonequilibrium system. Finally, we derive a generalized form of the Kubo formula for a wide class of interacting nonequilibrium systems, relating the differential conductivity to the current noise.
The Kubo fluctuation-dissipation theorem relates the current fluctuations of a system in an equilibrium state with the linear AC-conductance. This theorem holds also out of equilibrium provided that the system is in a stationary state and that the linear conductance is replaced by the (dynamic) conductance with respect to the nonequilibrium state. We provide a simple proof for that statement and then apply it in two cases. We first show that in an excess noise measurement at zero temperature, in which the impedance matching is maintained while driving a mesoscopic sample out of equilibrium, it is the nonsymmetrized noise power spectrum which is measured, even if the bare measurement, i.e. without extracting the excess part of the noise, obtains the symmetrized noise. As a second application we derive a commutation relation for the two components of fermionic or bosonic currents which holds in every stationary state and which is a generalization of the one valid only for bosonic currents. As is usually the case, such a commutation relation can be used e.g. to derive Heisenberg uncertainty relationships among these current components.
We address the question of whether transport coefficients obtained from a unitary closed system setting, i.e., the standard equilibrium Green-Kubo formula, are the same as the ones obtained from a weakly driven nonequilibrium steady-state calculation. We first derive a nonequilibrium Kubo-like expression for the steady-state diffusion constant expressed as a time integral of either a current or a conserved density nonequilibrium correlation function. This expression has certain advantages over the equilibrium Green-Kubo formula, but it is not clear if it gives the same value of the diffusion constant. We then rigorously show that if the unitary dynamics is diffusive, the nonequilibrium formula indeed gives exactly the same transport coefficient. The form of finite-size correction is also predicted. Theoretical results are verified by an explicit calculation of the diffusion constant in several interacting many-body models.
There is no simple fluctuation-dissipation theorem (FDT) for nonequilibrium systems. We show that for a fluid in a nonequilibrium steady state (NESS) characterized by a constant temperature gradient there is a generalized FDT that relates commutator correlation functions to the bilinear response of products of observables. This allows for experimental probes of the long-range correlations in such a system, quantum or classical, via response experiments. We also show that the correlations are not tied to thermal fluctuations but are intrinsic to the NESS and reflect a generalized rigidity.
We derive a general set of fluctuation relations for a nonequilibrium open quantum system described by a Lindblad master equation. In the special case of conservative Hamiltonian dynamics, these identities allow us to retrieve quantum versions of Jarzynski and Crooks relations. In the linear response regime, these fluctuation relations yield a fluctuation-dissipation theorem (FDT) valid for a stationary state arbitrarily far from equilibrium. For a closed system, this FDT reduces to the celebrated Callen-Welton-Kubo formula.