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arXiv:1011.3311 · Physical Review A

Collisionally induced atomic clock shifts and correlations

Y. B. Band, I. Osherov

Published Jul 20, 2011• 6 citations
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Abstract

We develop a formalism to incorporate exchange symmetry considerations into the calculation of collisional frequency shifts for atomic clocks using a density-matrix formalism. The formalism is developed for both fermionic and bosonic atomic clocks. Numerical results for a finite-temperature ${}^{87}$Sr ${}^{1}{S}_{0}$ ($F=9/2$) atomic clock in a magic wavelength optical lattice are presented.

DOI
10.1103/physreva.84.013822

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We report an s-wave collisional frequency shift of an atomic clock based on fermions. In contrast to bosons, the fermion clock shift is insensitive to the population difference of the clock states, set by the first pulse area in Ramsey spectroscopy, θ(1). The fermion shift instead depends strongly on the second pulse area θ(2). It allows the shift to be canceled, nominally at θ(2)=π/2, but correlations perturb the null to slightly larger θ(2). The frequency shift is relevant for optical lattice clocks and increases with the spatial inhomogeneity of the clock excitation field, naturally larger at optical frequencies.
We study the influence of ultracold collisions induced by the inhomogeneous excitation on the clock-transition frequency in one- and two-dimensional shallow blue-detuned (BD) 87{}^{87}87Sr optical lattice clocks with a magic wavelength of ${\ensuremath{\lambda}}_{b}=389.889$ nm. The minimal lattice potential required to tightly confine atoms in each single lattice site is much larger than that required for a red-detuned (RD) lattice operating at ${\ensuremath{\lambda}}_{r}=813.4$ nm because of the relatively smaller magic wavelength. For a deep optical lattice, the two-body interactions of atoms in a single lattice site mainly contribute to the clock-transition frequency shift, while the intersite collisions primarily affect the collisional shift in a shallow optical lattice. For an effective misalignment angle $\ensuremath{\Delta}\ensuremath{\theta}\ensuremath{\sim}10$ mrad of the probe beam with respect to the lattice axis, the fractional collisional shifts in both one- and two-dimensional BD lattices are at the ${10}^{\ensuremath{-}16}$ level.
We demonstrate a one-dimensional optical lattice clock with a spin-polarized fermionic isotope designed to realize a collision-shift-free atomic clock with neutral atom ensembles. To reduce systematic uncertainties, we developed both Zeeman shift and vector light-shift cancellation techniques. By introducing both an H-maser and a Global Positioning System (GPS) carrier phase link, the absolute frequency of the 1S0(F=9/2)−3P0(F=9/2)^1S_0(F=9/2) - {}^3P_0(F=9/2)1S0​(F=9/2)−3P0​(F=9/2) clock transition of the 87^{87}87Sr optical lattice clock is determined as 429,228,004,229,875(4) Hz, where the uncertainty is mainly limited by that of the frequency link. The result indicates that the Sr lattice clock will play an important role in the scope of the redefinition of the ``second'' by optical frequency standards.
We excite spin waves with spatially inhomogeneous Ramsey pulses and study the resulting frequency shifts of a chip-scale atomic clock of trapped 87Rb. The density-dependent frequency shifts of the hyperfine transition simulate the s-wave collisional frequency shifts of fermions, including those of optical lattice clocks. As the spin polarizations oscillate in the trap, the frequency shift reverses and it depends on the area of the second Ramsey pulse, exhibiting a predicted beyond mean-field frequency shift. Numerical and analytic models illustrate these observed behaviors.