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arXiv:quant-ph/9504001

Quantum mechanics of time-dependent systems. Construction of pure states

Víctor Tapia

Published Apr 3, 1995• 0 citations
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Abstract

For time-dependent systems the wavefunction depends explicitly on time and it is not a pure state of the Hamiltonian. We construct operators for which the above wavefunction is a pure state. The method is based on the introduction of conserved quantities $Q$ and the pure states are defined by ${\hat Q}ψ=qψ$. The conserved quantities are constructed using parametrised mechanics and the Noether theorem.

DOI
10.48550/arxiv.quant-ph/9504001

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For time-dependent systems the wavefunction depends explicitly on time and it is not a pure state of the Hamiltonian. We construct operators for which the above wavefunction is a pure state. The method is based on the introduction of conserved quantities QQQ and the pure states are defined by Q^ψ=qψ{\hat Q}ψ=qψQ^​ψ=qψ. The conserved quantities are constructed using parametrised mechanics and the Noether theorem.
In the classical mechanics of conservative systems, the position and momentum evolve deterministically such that the sum of the kinetic energy and potential energy remains constant in time. This canonical trademark of energy conservation is absent in the standard presentations of quantum mechanics based on the Schrödinger picture. We present a purely canonical proof of energy conservation that focuses exclusively on the time-dependent position x(t) and momentum p(t) operators. This treatment of energy conservation serves as an introduction to the Heisenberg picture and illuminates the classical-quantum connection. We derive a quantum-mechanical work-energy theorem and show explicitly how the time dependence of x and p and the noncommutivity of x and p conspire to bring about a perfect temporal balance between the evolving kinetic and potential parts of the total energy operator.
This chapter demonstrates how one can find the time evolution of the operators from the knowledge of the time evolution of the state vector, and vice versa. It introduces a unitary operator and discusses the concept of a unitary transformation to show how one could transfer the time dependence from the state vectors to the operators. The possibility that either the state vectors or the operators can depend explicitly on time will lead to introduce the Schrodinger, Heisenberg, and interaction pictures. The chapter discusses the fundamental differences between these pictures. It also discusses the Ehrenfest theorem, which shows under which conditions quantum mechanics predicts the same results for measured physical quantities as classical physics. It illustrates unitary transformations of an arbitrary operator Â(t) which can depend explicitly on time. Quantum mechanics produces the same result as classical mechanics for a system in which particles are represented by well-localized wave functions.
The time-dependent integrals of motion, linear in position and momentum operators, of a quantum system are extracted from Noether's theorem prescription by means of special time-dependent variations of coordinates. For the stationary case of the generalized two-dimensional harmonic oscillator, the time-independent integrals of motion are shown to correspond to special Bragg-type symmetry properties. A detailed study for the nonstationary case of this quantum system is presented. The linear integrals of motion are constructed explicitly for the case of varying mass and coupling strength. They are also obtained from Noether's theorem. The general treatment for a multi-dimensional quadratic system is indicated and it is shown that the time-dependent variations that give rise to the linear invariants, as conserved quantities, satisfy the corresponding classical homogeneous equations of motion for the coordinates.