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arXiv:quant-ph/0702052 · Open Physics

On solutions of the Schrödinger equation for some molecular potentials: wave function ansatz

Sameer M. Ikhdair, R. Sever

Published Apr 2, 2008• 38 citations
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Abstract

Abstract Making an ansatz to the wave function, the exact solutions of the D-dimensional radial Schrödinger equation with some molecular potentials, such as pseudoharmonic and modified Kratzer, are obtained. Restrictions on the parameters of the given potential, δ and ν are also given, where η depends on a linear combination of the angular momentum quantum number ℓ and the spatial dimensions D and δ is a parameter in the ansatz to the wave function. On inserting D = 3, we find that the bound state eigensolutions recover their standard analytical forms in literature.

DOI
10.2478/s11534-008-0060-y

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Abstract Making an ansatz to the wave function, the exact solutions of the D-dimensional radial Schrödinger equation with some molecular potentials, such as pseudoharmonic and modified Kratzer, are obtained. Restrictions on the parameters of the given potential, δ and ν are also given, where η depends on a linear combination of the angular momentum quantum number ℓ and the spatial dimensions D and δ is a parameter in the ansatz to the wave function. On inserting D = 3, we find that the bound state eigensolutions recover their standard analytical forms in literature.
The point canonical transformation (PCT) approach is used to solve the Schrödinger equation for an arbitrary dimension D with a power-law position-dependent effective mass (PDEM) distribution function for the pseudoharmonic and modified Kratzer (Mie-type) diatomic molecular potentials. In mapping the transformed exactly solvable D-dimensional (D ≥ 2) Schrödinger equation with constant mass into the effective mass equation by using a proper transformation, the exact bound state solutions including the energy eigenvalues and corresponding wave functions are derived. The well-known pseudoharmonic and modified Kratzer exact eigenstates of various dimensionality is manifested.
Exactly solvable models play an extremely important role in many fields of quantum physics. In this study, the Schrödinger equation is applied for a solution of a two--dimensional (2D) problem for two particles interacting via Kratzer, and modified Kratzer potentials. We found the exact bound state solutions of the two--dimensional Schrödinger equation with Kratzer--type potentials and present analytical expressions for the eigenvalues and eigenfunctions. The eigenfunctions are given in terms of the associated Laguerre polynomials.