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arXiv:quant-ph/0606009

Untouched aspects of the wave mechanics of a particle in one dimensional box

Yatendra Singh Jain

Published Jun 1, 2006• 2 citations
arXivHTMLPDF

Abstract

Wave mechanics of a particle in 1-D box (size $= d$) is critically analyzed to reveal its untouched aspects. When the particle rests in its ground state, its zero-point force ($F_o$) produces non-zero strain by modifying the box size from $d$ to $d' = d + Δd$ in all practical situations where the force ($F_a$) restoring $d$ is not infinitely strong. Assuming that $F_a$ originates from a potential $\propto x^2$ ($x$ being a small change in $d$), we find that: (i) the particle and strained box assume a mutually bound state (under the equilibrium between $F_o$ and $F_a$) with binding energy $Δ{E} = -ε_o'Δ{d}/d'$ (with $ε_o' = h^2/8md'^2$ being the ground state energy of the particle in the strained box), (ii) the box size oscillates around $d'$ when the said equilibrium is disturbed, (iii) an exchange of energy between the particle and the strained box occurs during such oscillations, and (iv) the particle, having collisional motion in its excited states, assumes collisionless motion in its ground state. These aspects have desired experimental support and proven relevance for understanding the physics of widely different systems such as quantum dots, quantum wires, trapped single particle/ion, clusters of particles, superconductors, superfluids, {\it etc.} It is emphasized that the physics of such a system in its low energy states can be truly revealed if the theory incorporates $F_o$ and related aspects.

DOI
10.48550/arxiv.quant-ph/0606009

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Wave mechanics of a particle in 1-D box (size =d= d=d) is critically analyzed to reveal its untouched aspects. When the particle rests in its ground state, its zero-point force (FoF_oFo​) produces non-zero strain by modifying the box size from ddd to d′=d+Δdd' = d + Δdd′=d+Δd in all practical situations where the force (FaF_aFa​) restoring ddd is not infinitely strong. Assuming that FaF_aFa​ originates from a potential ∝x2\propto x^2∝x2 (xxx being a small change in ddd), we find that: (i) the particle and strained box assume a mutually bound state (under the equilibrium between FoF_oFo​ and FaF_aFa​) with binding energy ΔE=−εo′Δd/d′Δ{E} = -ε_o'Δ{d}/d'ΔE=−εo′​Δd/d′ (with εo′=h2/8md′2ε_o' = h^2/8md'^2εo′​=h2/8md′2 being the ground state energy of the particle in the strained box), (ii) the box size oscillates around d′d'd′ when the said equilibrium is disturbed, (iii) an exchange of energy between the particle and the strained box occurs during such oscillations, and (iv) the particle, having collisional motion in its excited states, assumes collisionless motion in its ground state. These aspects have desired experimental support and proven relevance for understanding the physics of widely different systems such as quantum dots, quantum wires, trapped single particle/ion, clusters of particles, superconductors, superfluids, {\it etc.} It is emphasized that the physics of such a system in its low energy states can be truly revealed if the theory incorporates FoF_oFo​ and related aspects.
A critical study of the wave mechanics of a particle trapped in a 1-D box having infinite potential walls and small flexibility in its size reveals its several important and hither to unknown aspects which could be relevant for better understanding of systems like quantum -dot/wire/well. Since most of these aspects arise from the zero-point force coming into operation when the particle occupies its ground state in the box, they are expected to have great significance at low temperatures. To demonstrate this we briefly analyze some important aspects of an electron bubble in liquid helium and its nano-droplets.
One of the classic first problems in quantum theory textbooks is that of the particle trapped in a box. Despite the apparent artificiality of the situation, it has quite a few interesting features that we can quickly apply to some more physically plausible situations. The particle in a box is literally an object, such as an electron, trapped inside a ‘box.’ In a realistic physical example, this ‘box’ would be a volume of space bound by some constraining force acting on the particle. For example, an atom is a ‘box’ as far as the orbiting electrons are concerned, with the electrostatic force between the positive protons in the nucleus and the negative electrons providing the constraint. The first move is to assume that the wave function for any particle in the box will have separate spatial and temporal dependencies. One of the key steps in obtaining our wave function was the quantization of the momentum.
A particle moves in one spatial dimension in an attractive symmetric negative potential vf(x), and obeys non-relativistic quantum mechanics. If the system is enclosed in a finite box then, unlike the situation in , the ground-state energy is negative only when the coupling v is sufficiently large. General upper- and lower-bound formulae are derived for the critical coupling which corresponds to . Some generalizations are derived for potentials which change sign and for unsymmetric unimodal potentials.
Abstract The wave mechanics of two impenetrable hard core particles in a 1-D box is analyzed. Each particle in the box behaves like an independent entity represented by a macro-orbital (a kind of pair waveform). While the expectation value of their interaction, 〈 V HC(x) 〉, vanishes for every state of two particles, the expectation value of their relative separation, 〈 x 〉, satisfies 〈 x 〉≥λ/2 (or q ≥ π/d, with 2d=L being the size of the box). The particles in their ground state define a close-packed arrangement of their wave packets (with 〈 x 〉= λ/2, phase position separation Δϕ = 2π and momentum |q o| = π/d) and experience a mutual repulsive force (zero point repulsion) f o=h 2/2md 3 which also tries to expand the box. While the relative dynamics of two particles in their excited states represents usual collisional motion, the same in their ground state becomes collisionless. These results have great significance in determining a correct microscopic understanding of widely different many-body systems.
Quantum mechanics has brought revolutionary changes in the conceptual foundations of physics and continues to shape the modern world. In this book, the author's emphasis is on helping students comprehend the significance of the underlying principles and understand the ways the new concepts were introduced. Including many worked examples and problems, this book will be an invaluable resource for students in physics, chemistry and electrical engineering needing a clear and rigorous introduction to quantum mechanics.
Macro-orbital representation of a particle (detailed account given in cond-mat/0603784) has been used to develop the microscopic theory of a system of interacting bosons. It concludes that: (i) below certain temperature (say, TλT_λTλ​), particles assume a state of (q, -q) bound pairs, (ii) the λ−λ-λ−transition is a consequence of inter-particle quantum correlations clubbed with zero-point repulsion and inter-particle attraction and represents an onset of the order-disorder of particles in their ϕ−ϕ-ϕ−space followed simultaneously by their BEC as (q, -q) bound pairs in a state of q = qo=π/dq_o = π/dqo​=π/d and K = 0, (iii) particles at T≤TλT \le T_λT≤Tλ​ acquire collective binding which locks them at = 0, = λ/2λ/2λ/2 and Δϕ=2nπΔϕ= 2nπΔϕ=2nπ (with n = 1, 2, 3, ...), (iv) the entire system assumes mechanical strain in inter-particle bonds and behaves like a single macroscopic molecule, (v) there exists an energy gap between the superfluid and normal fluid phases of the system, (vi) the λ−λ-λ−transition represents the twin phenomena of broken gauge symmetry and phase coherence, (vii) the system does not have p = 0 condensate, (viii) a new kind of quantum quasi-particle "omon" (a phononlike wave of the oscillations of the momentum coordinates of particles) exists in superfluid phase, etc. It explains the properties of He-II, including the origin of quantized vortices, critical velocities, logarithmic singularity of specific heat, etc. at quantitative level and provides microscopic foundation to two fluid theory, Ψ−Ψ-Ψ−theory, idea of macroscopic wave function, etc. The framework of the theory can unify the physics of interacting bosons and fermions.