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arXiv:quant-ph/0304203 · Journal of Physics A Mathematical and General

Spin-dependent Bohm trajectories associated with an electronic transition in hydrogen

C Colijn, E R Vrscay

Published Apr 8, 2003• 13 citations
arXivHTMLPDF

Abstract

The de Broglie–Bohm causal theory of quantum mechanics with spin-dependence is used to determine electron trajectories when a hydrogen atom is subjected to (semiclassical) radiation. The transition between the 1s ground state and the 2p 0 state is examined. It is found that transitions can be identified along Bohm trajectories. The trajectories lie on invariant hyperboloid surfaces of revolution in R 3 . The energy along the trajectories is also discussed in relation to the hydrogen energy eigenvalues.

DOI
10.1088/0305-4470/36/16/317

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The de Broglie–Bohm causal theory of quantum mechanics with spin-dependence is used to determine electron trajectories when a hydrogen atom is subjected to (semiclassical) radiation. The transition between the 1s ground state and the 2p 0 state is examined. It is found that transitions can be identified along Bohm trajectories. The trajectories lie on invariant hyperboloid surfaces of revolution in R 3 . The energy along the trajectories is also discussed in relation to the hydrogen energy eigenvalues.
The Bohm causal theory of quantum mechanics with spin-dependence is used to determine electron trajectories when a hydrogen atom is subjected to (semi-classical) radiation. The transition between the 1s ground state and the 2p0 state is examined. It is found that transitions can be identified along Bohm trajectories. The trajectories lie on invariant hyperboloid surfaces of revolution in R 3. The energy along the trajectories is also discussed in relation to the hydrogen energy eigenvalues. PACS Nos: 3.65.Bz Keywords: de Broglie-Bohm quantum mechanics, causal interpretation
The de Broglie-Bohm causal interpretation of quantum mechanics is discussed, and applied to the hydrogen atom in several contexts. Prominent critiques of the causal program are noted and responses are given; it is argued that the de Broglie-Bohm theory is of notable interest to physics. Using the causal theory, electron trajectories are found for the conventional Schrödinger, Pauli and Dirac hydrogen eigenstates. In the Schrödinger case, an additional term is used to account for the spin; this term was not present in the original formulation of the theory but is necessary for the theory to be embedded in a relativistic formulation. In the Schrödinger, Pauli and Dirac cases, the eigenstate trajectories are shown to be circular, with electron motion revolving around the z-axis. Electron trajectories are also found for the 1s-2p0 transition problem under the Schrödinger equation; it is shown that the transition can be characterized by a comparison of the trajectory to the relevant eigenstate trajectories. The structures of the computed trajectories are relevant to the question of the possible evolution of a quantum distribution towards the standard quantum distribution (quantum equilibrium); this process is known as quantum relaxation. The transition problem is generalized to include all possible transitions in hydrogen stimulated by semi-classical radiation, and all of the trajectories found are examined in light of their implications for the evolution of the distribution to the standard distribution. Several promising avenues for future research are discussed.
We introduce the de Broglie-Bohm causal interpreation of quantum mechanics and compare it to the standard interpretation of quantum mechanics, the Copenhagen interpretation. We examine the possibility of experimentally distinguishing between the two theories, as well as the potential for the causal interpretation to more easily bridge the gap between the physics of the quantum and classical worlds. We then use the causal interpretation to construct a deterministic model of the helium atom in which the two electrons move along trajectories through space and time about a stationary nucleus. The dynamics are governed by the non-relativistic Schrödinger equation and the spin vectors of both electrons are assumed to be constant along their respective trajectories. We examine the Bohmian trajectories associated with (approximations to) eigenstates of the helium Hamiltonian as well as the trajectories associated with some non-eigenstates. We also compute an approximation to the ground state energy of the helium atom using a representation of the helium wavefunction in terms of hydrogenic eigenfunctions which is motivated by a perturbation approach.
The evolution of probability distributions for quantum systems defined by the de Broglie–Bohm causal interpretation of quantum mechanics is examined in the context of whether, in general, a non-|ψ|2 distribution will evolve to approximate a |ψ|2 distribution, as has been suggested by Bohm and others. This study focusses on hydrogen eigenstates and two-state hydrogen transitions stimulated by semi-classical radiation. It is shown that this process of ‘relaxation’ will not in general occur in such hydrogen systems, and thus that the de Broglie–Bohm theory must retain the |ψ|2 postulate if it is to be consistent with the standard quantum theory of individual systems.
State transition in the multiple-levels system has the great potential applications in the quantum technology. In this article we employ a deterministic approach in complex space to analyze the dynamics of the 1s-2p electron transition in the hydrogen atom. The electron’s spin motion is embodied in the framework of quantum Hamilton mechanics that allows us to examine the transition dynamics more precisely. The transition is driven by an oscillating electric field in the z-direction. The electron’s transition process can be visualized by monitoring its motion in the complex space. The quantum potential and the total energy proposed in this paper provide new indices to observe the dynamic changes of electrons in the transition process.
de Broglie-Bohm theory (dBBT), treating quantum particles as point objects moving along well defined (Bohmian) trajectories, offers an appealing solution of the measurement problem in quantum mechanics; it has, however, problems relating to spin, relativity and lack of proper integration with the Hilbert space based framework. In this work, we present a consistent formalism which has the traditional state-observable framework integrated with the desirable features of dBBT. We adopt ensemble interpretation for the Schrodinger wave function ψψψ. Given a Schrodinger wave function ψψψ, we use its value ψ0ψ_0ψ0​ at some fixed time (say, t=0t = 0t=0) to define the probability measure ∣ψ0∣2dx|ψ_0|^2 {\rm d}x∣ψ0​∣2dx on the system configuration space MMM (=Rn=\mathbb{R}^n=Rn). On the resulting probability space M0\mathcal{M}_0M0​, we introduce a stochastic process ξ(t)ξ(t)ξ(t) corresponding to the Heisenberg position operator XH(t)X_H(t)XH​(t) such that, in the Heisenberg state ∣ψh⟩|ψ_h\rangle∣ψh​⟩ corresponding to ψ0ψ_0ψ0​, the expectation value of XH(t)X_H(t)XH​(t) equals that of ξ(t)ξ(t)ξ(t) in M0\mathcal{M}_0M0​. This condition leads to the de Broglie-Bohm guidance equation for the sample paths of the process ξ(t)ξ(t)ξ(t) which are, therefore, Bohmian trajectories supposedly representing time-evolutions of individual members of the ψ0ψ_0ψ0​-ensemble. Stochastic processes and Bohmian trajectories corresponding to observables with discrete eigenvalues (in particular spin) are treated by extending the configuration space to the spectral space of the commutative algebra obtained by adding appropriate discrete observables to the position observables. Pauli's equation is treated as an example. A straightforward derivation of von Neumann's projection rule employing the Schrodinger-Bohm evolution of individual systems along their Bohmian trajectories is given. Some comments on the potential application of the formalism developed here to quantum mechanics of the universe are included.