de Broglie-Bohm theory (dBBT), treating quantum particles as point objects moving along well defined (Bohmian) trajectories, offers an appealing solution of the measurement problem in quantum mechanics; it has, however, problems relating to spin, relativity and lack of proper integration with the Hilbert space based framework. In this work, we present a consistent formalism which has the traditional state-observable framework integrated with the desirable features of dBBT. We adopt ensemble interpretation for the Schrodinger wave function $ψ$. Given a Schrodinger wave function $ψ$, we use its value $ψ_0$ at some fixed time (say, $t = 0$) to define the probability measure $|ψ_0|^2 {\rm d}x$ on the system configuration space $M$ ($=\mathbb{R}^n$). On the resulting probability space $\mathcal{M}_0$, we introduce a stochastic process $ξ(t)$ corresponding to the Heisenberg position operator $X_H(t)$ such that, in the Heisenberg state $|ψ_h\rangle$ corresponding to $ψ_0$, the expectation value of $X_H(t)$ equals that of $ξ(t)$ in $\mathcal{M}_0$. This condition leads to the de Broglie-Bohm guidance equation for the sample paths of the process $ξ(t)$ which are, therefore, Bohmian trajectories supposedly representing time-evolutions of individual members of the $ψ_0$-ensemble. Stochastic processes and Bohmian trajectories corresponding to observables with discrete eigenvalues (in particular spin) are treated by extending the configuration space to the spectral space of the commutative algebra obtained by adding appropriate discrete observables to the position observables. Pauli's equation is treated as an example. A straightforward derivation of von Neumann's projection rule employing the Schrodinger-Bohm evolution of individual systems along their Bohmian trajectories is given. Some comments on the potential application of the formalism developed here to quantum mechanics of the universe are included.
de Broglie-Bohm theory (dBBT), treating quantum particles as point objects moving along well defined (Bohmian) trajectories, offers an appealing solution of the measurement problem in quantum mechanics; it has, however, problems relating to spin, relativity and lack of proper integration with the Hilbert space based framework. In this work, we present a consistent formalism which has the traditional state-observable framework integrated with the desirable features of dBBT. We adopt ensemble interpretation for the Schrodinger wave function ψ. Given a Schrodinger wave function ψ, we use its value ψ0 at some fixed time (say, t=0) to define the probability measure ∣ψ0∣2dx on the system configuration space M (=Rn). On the resulting probability space M0, we introduce a stochastic process ξ(t) corresponding to the Heisenberg position operator XH(t) such that, in the Heisenberg state ∣ψh⟩ corresponding to ψ0, the expectation value of XH(t) equals that of ξ(t) in M0. This condition leads to the de Broglie-Bohm guidance equation for the sample paths of the process ξ(t) which are, therefore, Bohmian trajectories supposedly representing time-evolutions of individual members of the ψ0-ensemble. Stochastic processes and Bohmian trajectories corresponding to observables with discrete eigenvalues (in particular spin) are treated by extending the configuration space to the spectral space of the commutative algebra obtained by adding appropriate discrete observables to the position observables. Pauli's equation is treated as an example. A straightforward derivation of von Neumann's projection rule employing the Schrodinger-Bohm evolution of individual systems along their Bohmian trajectories is given. Some comments on the potential application of the formalism developed here to quantum mechanics of the universe are included.
Bohm theory is a formulation of Quantum Mechanics that characterises the state of a quantum system according to both the wave function, as in the conventional formulation, and the coordinates (positions) of all the particles that evolve in time drawing quantum continuous trajectories. Furthermore, a statistical ensemble of all the possible trajectories, raising from the impossibility to know the initial position of all the particles, establishes the exact correspondence with the traditional Quantum Mechanics. From a computational point of view, Bohm theory has found many applications in Chemical Physics especially to develop new methodologies for solving the Schrödinger equation and to address semi-classical approximations of Quantum Mechanics. From a theoretical point of view, the most appealing feature of Bohm theory is its capability to supply a conceptual map between the quantum formalism and our representation of what a chemical system is. Chemical systems are composed of molecules, but the same idea of molecule requires a specific arrangement in the space of particles, i.e., the nuclei of the atoms. The statistical description of conventional Quantum Mechanics on the basis of wave function alone is insufficient to establish a clear correspondence with such a picture of molecules. Indeed, chemists employ usually Classical Mechanics in order to overcome this drawback of the standard quantum theory. On the other hand, if the particles position is included in the quantum formalism, as Bohm theory does, the map can be defined in a self-consistent way. In other words, Bohm theory appears to be the suitable quantum framework to represent molecules and their motion. The chemical representation of molecular systems finds a natural correspondence with a single Bohm trajectory, since it is always implicitly assumed that molecular components have specific spatial position independently of our knowledge about it. Consequently, we develop a quantum method whose fundamental assumption is that a single Bohm trajectory, i.e., a quantum molecular trajectory, describes the molecular systems and the molecular motion correctly. First of all, we examine the correspondence between a single Bohm trajectory and the conventional Quantum Mechanics, without using the ensemble of trajectories. We verify that such a correspondence exists through numerical simulations and we prove formally that the statistical properties of a single Bohm trajectory explain the probabilistic description of Quantum Mechanics. Once the consistency of this original approach has been established, we investigate the predicted properties. For instance, we take into account the constants of motion (such as the energy) corresponding to the time evolution of the coordinates and the behaviour of simple chemical systems, e.g., the vibrational motion of single molecules interacting with a resonant field. In this way, unexpected features of the molecular motion are found. Secondly, we tackle the challenge of describing many components systems (like the chemical systems in ordinary conditions). As a matter of fact, the computation of the Bohm trajectory and of the wave function is extremely demanding. However, the statistical properties of the Bohm trajectory allow the derivation of stochastic theories for examining the dynamics of open quantum systems, i.e., few molecules (or few degrees of freedom) interacting with their environment (the other molecules). One of the developed stochastic methods correlates the dynamics of the reduced density matrix, for the degrees of freedom of interest, to the evolution of the corresponding Bohm coordinates. In other words, the Bohm equation, determining the set of all the particles velocities according to the full wave function, is replaced with a stochastic one that approximates the velocity of a subset of coordinates according to the reduced density matrix. In such a way, the quantum fluctuations induced by the environment are taken into account. The advantage of this method concerns its capability of describing quantum systems, including open quantum systems, in terms of a quantum trajectory. This could allow the understanding of the molecular motion during a spectroscopical experiment. The possibility of investigating reactive systems, such as conformational changes, is particularly interesting. As a matter of fact, chemical reactions can be completely characterised only through the particles motion and we define the suit- able quantum methodology providing a self-consistent description of the molecular motion.
Bohmian mechanics, also known as pilot-wave theory or de Broglie-Bohm theory, is a formulation of quantum mechanics whose fundamental axioms are not about what observers will see if they perform an experiment but about what happens in reality. It is therefore called a "quantum theory without observers," alongside with collapse theories and many-worlds theories and in contrast to orthodox quantum mechanics. It follows from these axioms that in a universe governed by Bohmian mechanics, observers will see outcomes with exactly the probabilities specified by the usual rules of quantum mechanics for empirical predictions. Specifically, Bohmian mechanics asserts that electrons and other elementary particles have a definite position at every time and move according to an equation of motion that is one of the fundamental laws of the theory and involves a wave function that evolves according to the usual Schrödinger equation. Bohmian mechanics is named after David Bohm (1917-1992), who was, although not the first to consider this theory, the first to realize (in 1952) that it actually makes correct predictions.
We critically examine the role and status probabilities, as they enter via the Quantum Equilibrium Hypothesis, play in the standard, deterministic interpretation of deBroglie’s and Bohm’s Pilot Wave Theory (dBBT), by considering interpretations of probabilities in terms of ignorance, typicality and Humean Best Systems, respectively. We argue that there is an inherent conflict between dBBT and probabilities, thus construed.\n The conflict originates in dBBT’s deterministic nature, rooted in the Guidance Equation. Inquiring into the latter’s role within dBBT, we find it explanatorily redundant (in particular for dBBT’s solution of the Measurement Problem, which only requires that the corpuscles possess definite positions), and subject to a number of difficulties. Following a suggestion from Bell, we propose to abandon the Guidance Equation, whilst retaining dBBT’s point particle-based Primitive Ontology, with positions as local beables. The resultant theory, which we identify as a stochastic, minimally deBroglie-Bohmian theory, describes a random walk through configuration space. Its probabilities, we propose, are best understood as dispositions of possible corpuscle configurations to manifest themselves. We subsequently evaluate the merits of sdBBT vis-à-vis dBBT, such as the justification of the Symmetrisation Postulate and the violation of the Action-Reaction Principle.\n Not only is sdBBT an attractive Bohmian theory that, whilst retaining dBBT's virtues, overcomes many of its shortcomings; it also sparks off a number of exciting follow-up questions, such as a comparison between sdBBT and other stochastic hidden-variable theories, e.g. Nelson Stochastics, or between sdBBT and the Everett interpretation.
A salient feature of de Broglie-Bohm (dBB) quantum theory is that particles have determinate positions at all times and in all physical contexts. Hence, the trajectory of a particle is a well-defined concept. One then may expect that the closely related notion of inertial trajectory is also unproblematically defined. I show that this expectation is not met. I provide a framework that deploys six different ways in which dBB theory can be interpreted, and I state that only in the canonical interpretation the concept of inertial trajectory is the customary one. However, in this interpretation the description of the dynamical interaction between the pilot-wave and the particles, which is crucial to distinguish inertial from non-inertial trajectories, is affected by serious difficulties, so other readings of the theory intend to avoid them. I show that in the alternative interpretations the concept at issue gets either drastically altered, or plainly undefined. I also spell out further conceptual difficulties that are associated to the redefinitions of inertial trajectories, or to the absence of the concept.
We critically examine the role and status probabilities, as they enter via the Quantum Equilibrium Hypothesis, play in the standard, deterministic interpretation of deBroglie’s and Bohm’s Pilot Wave Theory (dBBT), by considering interpretations of probabilities in terms of ignorance, typicality and Humean Best Systems, respectively. We argue that there is an inherent conflict between dBBT and probabilities, thus construed. The conflict originates in dBBT’s deterministic nature, rooted in the Guidance Equation. Inquiring into the latter’s role within dBBT, we find it explanatorily redundant (in particular for dBBT’s solution of the Measurement Problem, which only requires that the corpuscles possess definite positions), and subject to a number of difficulties. Following a suggestion from Bell, we propose to abandon the Guidance Equation, whilst retaining dBBT’s point particle-based Primitive Ontology, with positions as local beables. The resultant theory, which we identify as a stochastic, minimally deBroglie-Bohmian theory, describes a random walk through configuration space. Its probabilities, we propose, are best understood as dispositions of possible corpuscle configurations to manifest themselves. We subsequently evaluate the merits of sdBBT vis-à-vis dBBT, such as the justification of the Symmetrisation Postulate and the violation of the Action-Reaction Principle. Not only is sdBBT an attractive Bohmian theory that, whilst retaining dBBT's virtues, overcomes many of its shortcomings; it also sparks off a number of exciting follow-up questions, such as a comparison between sdBBT and other stochastic hidden-variable theories, e.g. Nelson Stochastics, or between sdBBT and the Everett interpretation.
Given a normalized state-vector ψ, we define the conditional expectation $\mathbb{E }_{ψ} (A | B ) $ of a Hermitian operator $A $ with respect to a strongly commuting family of self-adjoint operators $B $ as the best approximation, in the operator mean square norm associated to ψ, of $A $ by a real-valued function of $B . $ A fundamental example is the conditional expectation of the momentum operator $P $ given the position operator $X $, which is found to be the Bohm momentum. After developing the Bohm theory from this point of view we treat conditional expectations with respect to general $B $, which we apply to non-relativistic spin 1/2-particles. We derive the dynamics of the conditional expectations of momentum and spin with respect to position and the third spin component. These dynamics can be interpreted in terms of classical continuum mechanics as a two-component fluid whose components carry intrinsic angular momentum. Interpreting the joint spectrum of the conditioning operators as a space of beables, we can introduce a classical-stochastic particle dynamics on this space which is compatible with the time-evolution of the Born probability, by combining the de Broglie-Bohm guidance condition with a Markov jump process, following an idea of J. Bell. This results in a new Bohm-type model for particles with spin. A basic problem is that such auxiliary particle dynamics are far from unique. We finally examine the relation of our conditional expectations with the conditional expectations of the theory of $C^* $-algebras and, as an application, derive a general evolution equation for conditional expectations for operators acting on finite dimensional Hilbert spaces. Two appendices re-interpret the classical Bohm model as an integrable constrained Hamiltonian system, and provide the details of the two-fluid interpretation.