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Bohmian Trajectories of the Two-Electron Helium Atom

Jeff Timko

Published Jan 17, 2008• 1 citation
OpenAlex

Abstract

We introduce the de Broglie-Bohm causal interpreation of quantum mechanics and compare it to the standard interpretation of quantum mechanics, the Copenhagen interpretation. We examine the possibility of experimentally distinguishing between the two theories, as well as the potential for the causal interpretation to more easily bridge the gap between the physics of the quantum and classical worlds. We then use the causal interpretation to construct a deterministic model of the helium atom in which the two electrons move along trajectories through space and time about a stationary nucleus. The dynamics are governed by the non-relativistic Schrödinger equation and the spin vectors of both electrons are assumed to be constant along their respective trajectories. We examine the Bohmian trajectories associated with (approximations to) eigenstates of the helium Hamiltonian as well as the trajectories associated with some non-eigenstates. We also compute an approximation to the ground state energy of the helium atom using a representation of the helium wavefunction in terms of hydrogenic eigenfunctions which is motivated by a perturbation approach.

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The de Broglie-Bohm causal interpretation of quantum mechanics is discussed, and applied to the hydrogen atom in several contexts. Prominent critiques of the causal program are noted and responses are given; it is argued that the de Broglie-Bohm theory is of notable interest to physics. Using the causal theory, electron trajectories are found for the conventional Schrödinger, Pauli and Dirac hydrogen eigenstates. In the Schrödinger case, an additional term is used to account for the spin; this term was not present in the original formulation of the theory but is necessary for the theory to be embedded in a relativistic formulation. In the Schrödinger, Pauli and Dirac cases, the eigenstate trajectories are shown to be circular, with electron motion revolving around the z-axis. Electron trajectories are also found for the 1s-2p0 transition problem under the Schrödinger equation; it is shown that the transition can be characterized by a comparison of the trajectory to the relevant eigenstate trajectories. The structures of the computed trajectories are relevant to the question of the possible evolution of a quantum distribution towards the standard quantum distribution (quantum equilibrium); this process is known as quantum relaxation. The transition problem is generalized to include all possible transitions in hydrogen stimulated by semi-classical radiation, and all of the trajectories found are examined in light of their implications for the evolution of the distribution to the standard distribution. Several promising avenues for future research are discussed.

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The Bohm causal theory of quantum mechanics with spin-dependence is used to determine electron trajectories when a hydrogen atom is subjected to (semi-classical) radiation. The transition between the 1s ground state and the 2p0 state is examined. It is found that transitions can be identified along Bohm trajectories. The trajectories lie on invariant hyperboloid surfaces of revolution in R 3. The energy along the trajectories is also discussed in relation to the hydrogen energy eigenvalues. PACS Nos: 3.65.Bz Keywords: de Broglie-Bohm quantum mechanics, causal interpretation

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De Broglie-Bohmova interpretacija kvantne mehanike

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On a new prediction of Causal Quantum Mechanics for the two-slit interference experiment with electrons

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The causal quantum mechanics (i.e. Bohmian or de Broglie-Bohm or Bohm-de Broglie quantum mechanics) has made possible to calculate the trajectories of electrons in a typical double-slit experiment [C. Philippidis et al., Il Nuovo Cimento, 52 B, 15-28 (1979)]. The trajectories do not correspond to an uniform movement but to an accelerated one. The acceleration is caused by the quantum potential. From the quantum theoretical point of view, there is a probability for the electron to emit photons, with a certain emission power, during its movement from the slits to the screen. We find a quantum general formula for the emission power of photons, valid independently of the interpretation. Then, according to the Copenhagen interpretation, this formula gives a strictly zero value for the emission power because the electron moves as a free particle after it leaves the slit and before reach the screen. Then, there is no emission of photons. In the case of the causal interpretation, the emission power results, for a concrete real experiment, in a very tiny but not a zero value, driven by the square of the quantum potential gradient. We give an idea of the type of spectrum that could be measured. A brief idea of a possible experimental arrangement in order to detect this effect, is given.

arXiv:1801.02096•Jan 6, 2018•0 citations
We introduce the de Broglie-Bohm causal interpreation of quantum mechanics and compare it to the standard interpretation of quantum mechanics, the Copenhagen interpretation. We examine the possibility of experimentally distinguishing between the two theories, as well as the potential for the causal interpretation to more easily bridge the gap between the physics of the quantum and classical worlds. We then use the causal interpretation to construct a deterministic model of the helium atom in which the two electrons move along trajectories through space and time about a stationary nucleus. The dynamics are governed by the non-relativistic Schrödinger equation and the spin vectors of both electrons are assumed to be constant along their respective trajectories. We examine the Bohmian trajectories associated with (approximations to) eigenstates of the helium Hamiltonian as well as the trajectories associated with some non-eigenstates. We also compute an approximation to the ground state energy of the helium atom using a representation of the helium wavefunction in terms of hydrogenic eigenfunctions which is motivated by a perturbation approach.
The de Broglie-Bohm causal interpretation of quantum mechanics is discussed, and applied to the hydrogen atom in several contexts. Prominent critiques of the causal program are noted and responses are given; it is argued that the de Broglie-Bohm theory is of notable interest to physics. Using the causal theory, electron trajectories are found for the conventional Schrödinger, Pauli and Dirac hydrogen eigenstates. In the Schrödinger case, an additional term is used to account for the spin; this term was not present in the original formulation of the theory but is necessary for the theory to be embedded in a relativistic formulation. In the Schrödinger, Pauli and Dirac cases, the eigenstate trajectories are shown to be circular, with electron motion revolving around the z-axis. Electron trajectories are also found for the 1s-2p0 transition problem under the Schrödinger equation; it is shown that the transition can be characterized by a comparison of the trajectory to the relevant eigenstate trajectories. The structures of the computed trajectories are relevant to the question of the possible evolution of a quantum distribution towards the standard quantum distribution (quantum equilibrium); this process is known as quantum relaxation. The transition problem is generalized to include all possible transitions in hydrogen stimulated by semi-classical radiation, and all of the trajectories found are examined in light of their implications for the evolution of the distribution to the standard distribution. Several promising avenues for future research are discussed.
The non-relativistic quantum theory has been interpreted causally by de Broglie, David Bohm, and others, where a quantum entity is viewed as a particle with a definite position and momentum. This interpretation contrasts with the Copenhagen orthodox interpretation, which conveys uncertainty through the commutator relationship between position and momentum operators. This is further exacerbated by the de Broglie-Bohm interpretation, which uses no operators corresponding to these observables. We reconcile these opposing viewpoints by introducing mathematical nonlinear transforms in Bohmian mechanics for the momentum observable. While these nonlinear operator-like transforms cannot be easily represented as matrices in the Hilbert space, we show that they can be utilized in the de Broglie-Bohm interpretations of quantum theory.
The Bohm causal theory of quantum mechanics with spin-dependence is used to determine electron trajectories when a hydrogen atom is subjected to (semi-classical) radiation. The transition between the 1s ground state and the 2p0 state is examined. It is found that transitions can be identified along Bohm trajectories. The trajectories lie on invariant hyperboloid surfaces of revolution in R 3. The energy along the trajectories is also discussed in relation to the hydrogen energy eigenvalues. PACS Nos: 3.65.Bz Keywords: de Broglie-Bohm quantum mechanics, causal interpretation
The de Broglie–Bohm interpretation (Bohmian mechanics, hidden-variables theory, causal interpretation or pilot-wave theory) is one of the interpretations of quantum mechanics which opposes to the claim of standard interpretation on the completeness of description of the state of quantummechanical system, that description in Bohmian mechanics is completed by defining positions of the particles of the system i.e. hidden variables and their dynamics. These facts are the basis of motivation for the introduction of a new theory that can describe dubious axiomatic requirements of standard interpretation. The presented theory is deterministic and explicitly nonlocal. Originators of Bohmian mechanics were L. de Broglie (1927.) and D. Bohm (1952.) who presented mathematically more general and conceptual elaborate formulation. Along with the historical overview, a note is given about the main properties of the theory, such as the issue of nonlocality and hidden variables. The aim of this paper is to present and explain the main ideas and properties of the theory as well as to give a systematic overview of present and historical mathematical construction of the theory and most of all to discuss implications of de Broglie–Bohm theory on the ontology of quantum-mechanical picture, showcasing examples of the equivalency of the description of a free particle as a propagation of the plane wave in space or as the ensemble of the trajectories and of the spreading of the Gaussian wave packet. The main example of the obvious conceptual clashing of the interpretations is presented: the double-slit experiment, with a detailed examination of the Bohmian mechanics’ predictions using presented formalism on the two double-slit experiment. The graphs of trajectories for given examples are obtained.
The de Broglie–Bohm causal theory of quantum mechanics with spin-dependence is used to determine electron trajectories when a hydrogen atom is subjected to (semiclassical) radiation. The transition between the 1s ground state and the 2p 0 state is examined. It is found that transitions can be identified along Bohm trajectories. The trajectories lie on invariant hyperboloid surfaces of revolution in R 3 . The energy along the trajectories is also discussed in relation to the hydrogen energy eigenvalues.
The causal quantum mechanics (i.e. Bohmian or de Broglie-Bohm or Bohm-de Broglie quantum mechanics) has made possible to calculate the trajectories of electrons in a typical double-slit experiment [C. Philippidis et al., Il Nuovo Cimento, 52 B, 15-28 (1979)]. The trajectories do not correspond to an uniform movement but to an accelerated one. The acceleration is caused by the quantum potential. From the quantum theoretical point of view, there is a probability for the electron to emit photons, with a certain emission power, during its movement from the slits to the screen. We find a quantum general formula for the emission power of photons, valid independently of the interpretation. Then, according to the Copenhagen interpretation, this formula gives a strictly zero value for the emission power because the electron moves as a free particle after it leaves the slit and before reach the screen. Then, there is no emission of photons. In the case of the causal interpretation, the emission power results, for a concrete real experiment, in a very tiny but not a zero value, driven by the square of the quantum potential gradient. We give an idea of the type of spectrum that could be measured. A brief idea of a possible experimental arrangement in order to detect this effect, is given.