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arXiv:quant-ph/0211072

A simple quantum heat engine

Jacques Arnaud, Laurent Chusseau, Fabrice Philippe

Published Nov 13, 2002• 5 citations
arXivHTMLPDF

Abstract

Quantum heat engines employ as working agents multi-level systems instead of gas-filled cylinders. We consider particularly two-level agents such as electrons immersed in a magnetic field. Work is produced in that case when the electrons are being carried from a high-magnetic-field region into a low-magnetic-field region. In watermills, work is produced instead when some amount of fluid drops from a high-altitude reservoir to a low-altitude reservoir. We show that this purely mechanical engine may in fact be considered as a two-level quantum heat engine, provided the fluid is viewed as consisting of n molecules of weight one and N-n molecules of weight zero. Weight-one molecules are analogous to electrons in their higher energy state, while weight-zero molecules are analogous to electrons in their lower energy state. More generally, fluids consist of non-interacting molecules of various weights. It is shown that, not only the average value of the work produced per cycle, but also its fluctuations, are the same for mechanical engines and quantum (Otto) heat engines. The reversible Carnot cycles are approached through the consideration of multiple sub-reservoirs.

DOI
10.48550/arxiv.quant-ph/0211072

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Quantum heat engines employ as working agents multi-level systems instead of gas-filled cylinders. We consider particularly two-level agents such as electrons immersed in a magnetic field. Work is produced in that case when the electrons are being carried from a high-magnetic-field region into a low-magnetic-field region. In watermills, work is produced instead when some amount of fluid drops from a high-altitude reservoir to a low-altitude reservoir. We show that this purely mechanical engine may in fact be considered as a two-level quantum heat engine, provided the fluid is viewed as consisting of n molecules of weight one and N-n molecules of weight zero. Weight-one molecules are analogous to electrons in their higher energy state, while weight-zero molecules are analogous to electrons in their lower energy state. More generally, fluids consist of non-interacting molecules of various weights. It is shown that, not only the average value of the work produced per cycle, but also its fluctuations, are the same for mechanical engines and quantum (Otto) heat engines. The reversible Carnot cycles are approached through the consideration of multiple sub-reservoirs.
Quantum heat engines employ as working agents multilevel systems instead of classical gases. We show that under some conditions quantum heat engines are equivalent to a series of reservoirs at different altitudes containing balls of various weights. A cycle consists of picking up at random a ball from one reservoir and carrying it to the next, thereby performing or absorbing some work. In particular, quantum heat engines, employing two-level atoms as working agents, are modeled by reservoirs containing balls of weight 0 or 1. The mechanical model helps us prove that the maximum efficiency of quantum heat engines is the Carnot efficiency. Heat pumps and negative temperatures are considered.
Conventional heat engines convert thermal energy into mechanical work by using a working medium such as steam or gas that operates between a hot and a cold reservoir. The medium absorbs heat from the hot reservoir, produces work, then releases some heat to the cold reservoir and returns to the initial state. With the advancement of quantum technologies, researchers strive to understand whether quantum media, such as atoms, spins, superconducting circuits and semiconductor quantum dots, can be used in quantum counterparts of the classical heat engines. After a recap of the basics of classical heat engines, this review explores the theoretical foundations and advancements of quantum heat engines, focusing on the proposed two- and multilevel systems used as the working medium for the quantum Otto cycle, which is the ideal thermodynamic cycle that describes the operation of a spark-ignition internal combustion engine. The review compares the efficiency and the work extraction of these systems, discussing their performance in the high- and low-temperature limits. Alternative cycles and engines are also presented to establish the adaptability of the working media when operating under different processes and non-equilibrium conditions. In conclusion, the review offers possible applications and future developments of quantum heat engines.
The finite-time operation of a quantum-mechanical heat engine with a working fluid consisting of many noninteracting spin-1/2 systems is considered. The engine is driven by an external, time-dependent and nonrotating magnetic field. The cycle of operation consists of two adiabats and two isotherms. The analysis is based on the time derivatives of the first and second laws of thermodynamics. Explicit relations linking quantum observables to thermodynamic quantities are developed. The irreversible operation of this engine is studied in three cases: (1) The sudden limit, where the performance is found to be the same as that of the spin analog of the Otto cycle. This case provides the lower bound of efficiency. (2) The step-cycle operation scheme. Here, the optimization of power is carried out in the high-temperature limit (the ‘‘classical’’ limit). The results obtained are similar to those of Andresen et al. [Phys. Rev. A 15, 2086 (1977)]. (3) The Curzon–Ahlborn operation scheme. The semigroup approach is used to model the dynamics. Then the power production is optimized. All the results obtained for Newtonian engines operating by the same scheme, such as the Curzon–Ahlborn efficiency, apply in the high-temperature limit. These results are obtained without the additional assumption of proximity to thermal equilibrium, implicitly implied by the use of Newtonian heat conduction in the original derivation. It seems that the results of the Curzon–Ahlborn analysis are always obtained in the high-temperature limit, irrespective of the details of the model. The performance beyond the classical limit is optimized numerically. The classical approximation is found to be valid for most of the spin-polarization range. The deviations from the classical limit depend heavily upon the specific nature of both the working fluid and the heat baths and exhibit great diversity and complexity.
In this paper, we consider a model of two-level quantum heat engine to investigate the explicit analytic expression for the thermodynamics quantities in different condition under the finite-time operation. In this engine, the working substance is composed of a spin-half particles immersed in a magnetic field. The finite-time thermodynamic processes consisting of two quantum adiabatic and two quantum isothermal processes. This processes working between two heat reservoirs with an inverse temperatures β1β_{1}β1​ and β2β_{2}β2​ (<β1<β_{1}<β1​). In this processes, we obtain the work, heat, power and efficiency at maximum power output of the model. Our result of the efficiency at maximum power agree with the universal value in the first order of Carnot efficiency.
We studied the efficiency of two different schemes for a magnetically driven quantum heat engine, by considering as the "working substance" a single nonrelativistic particle trapped in a cylindrical potential well, in the presence of an external magnetic field. The first scheme is a cycle, composed of two adiabatic and two isoenergetic reversible trajectories in configuration space. The trajectories are driven by a quasistatic modulation of the external magnetic-field intensity. The second scheme is a variant of the former, where the isoenergetic trajectories are replaced by isothermal ones, along which the system is in contact with macroscopic thermostats. This second scheme constitutes a quantum analog of the classical Carnot cycle.
The quantum analog of Carnot cycles in few-particle systems consists of two quantum adiabatic steps and two isothermal steps. This construction is formally justified by use of a minimum work principle. It is then shown, using minimal assumptions of work or heat in nanoscale systems, that the heat-to-work efficiency of such quantum heat engine cycles can be further optimized via two conditions regarding the expectation value of some generalized force operators evaluated at equilibrium states. In general the optimized efficiency is system specific, lower than the Carnot efficiency, and dependent upon both temperatures of the cold and hot reservoirs. Simple computational examples are used to illustrate our theory. The results should be an important guide towards the design of favorable working conditions of a realistic quantum heat engine.