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arXiv:1405.2990 · Physical Review E

Magnetically driven quantum heat engine

Enrique Muñoz, Francisco J. Peña

Published May 7, 2014• 26 citations
arXivHTMLPDF

Abstract

We studied the efficiency of two different schemes for a magnetically driven quantum heat engine, by considering as the "working substance" a single nonrelativistic particle trapped in a cylindrical potential well, in the presence of an external magnetic field. The first scheme is a cycle, composed of two adiabatic and two isoenergetic reversible trajectories in configuration space. The trajectories are driven by a quasistatic modulation of the external magnetic-field intensity. The second scheme is a variant of the former, where the isoenergetic trajectories are replaced by isothermal ones, along which the system is in contact with macroscopic thermostats. This second scheme constitutes a quantum analog of the classical Carnot cycle.

DOI
10.1103/physreve.89.052107

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We studied the efficiency of two different schemes for a magnetically driven quantum heat engine, by considering as the "working substance" a single nonrelativistic particle trapped in a cylindrical potential well, in the presence of an external magnetic field. The first scheme is a cycle, composed of two adiabatic and two isoenergetic reversible trajectories in configuration space. The trajectories are driven by a quasistatic modulation of the external magnetic-field intensity. The second scheme is a variant of the former, where the isoenergetic trajectories are replaced by isothermal ones, along which the system is in contact with macroscopic thermostats. This second scheme constitutes a quantum analog of the classical Carnot cycle.
We studied the efficiency of two different schemes for a quantum heat engine, by considering a single Dirac particle trapped in an infinite one-dimensional potential well as the "working substance." The first scheme is a cycle, composed of two adiabatic and two isoenergetic reversible trajectories in configuration space. The trajectories are driven by a quasistatic deformation of the potential well due to an external applied force. The second scheme is a variant of the former, where isoenergetic trajectories are replaced by isothermal ones, along which the system is in contact with macroscopic thermostats. This second scheme constitutes a quantum analog of the classical Carnot cycle. Our expressions, as obtained from the Dirac single-particle spectrum, converge in the nonrelativistic limit to some of the existing results in the literature for the Schrödinger spectrum.
A cyclic thermodynamic heat engine,which combines adiabatic and isothermal processes and consists of classical ideal gas as working substance,runs most efficiently if it is reversible.In this paper,A new cyclic model of quantum Carnot heat engine whose working substance consists of non-interacting extreme relativistic particles confined to an infinite potential well,is set up.It is shown that the engine whose cycle consists of adiabatic and isothermal quantum processes are close analogues of the corresponding classical processes and that the efficiency of this engine is equal to the Carnot efficiency because quantum dynamics is reversible.Consequently,the expectation value of the Hamiltonian in the expression of the efficiency is similar to the temperature in that of the classical one.
In this paper, we consider a model of two-level quantum heat engine to investigate the explicit analytic expression for the thermodynamics quantities in different condition under the finite-time operation. In this engine, the working substance is composed of a spin-half particles immersed in a magnetic field. The finite-time thermodynamic processes consisting of two quantum adiabatic and two quantum isothermal processes. This processes working between two heat reservoirs with an inverse temperatures β1β_{1}β1​ and β2β_{2}β2​ (<β1<β_{1}<β1​). In this processes, we obtain the work, heat, power and efficiency at maximum power output of the model. Our result of the efficiency at maximum power agree with the universal value in the first order of Carnot efficiency.
The finite-time operation of a quantum-mechanical heat engine with a working fluid consisting of many noninteracting spin-1/2 systems is considered. The engine is driven by an external, time-dependent and nonrotating magnetic field. The cycle of operation consists of two adiabats and two isotherms. The analysis is based on the time derivatives of the first and second laws of thermodynamics. Explicit relations linking quantum observables to thermodynamic quantities are developed. The irreversible operation of this engine is studied in three cases: (1) The sudden limit, where the performance is found to be the same as that of the spin analog of the Otto cycle. This case provides the lower bound of efficiency. (2) The step-cycle operation scheme. Here, the optimization of power is carried out in the high-temperature limit (the ‘‘classical’’ limit). The results obtained are similar to those of Andresen et al. [Phys. Rev. A 15, 2086 (1977)]. (3) The Curzon–Ahlborn operation scheme. The semigroup approach is used to model the dynamics. Then the power production is optimized. All the results obtained for Newtonian engines operating by the same scheme, such as the Curzon–Ahlborn efficiency, apply in the high-temperature limit. These results are obtained without the additional assumption of proximity to thermal equilibrium, implicitly implied by the use of Newtonian heat conduction in the original derivation. It seems that the results of the Curzon–Ahlborn analysis are always obtained in the high-temperature limit, irrespective of the details of the model. The performance beyond the classical limit is optimized numerically. The classical approximation is found to be valid for most of the spin-polarization range. The deviations from the classical limit depend heavily upon the specific nature of both the working fluid and the heat baths and exhibit great diversity and complexity.
A cyclic thermodynamic heat engine runs most efficiently if it is reversible. Carnot constructed such a reversible heat engine by combining adiabatic and isothermal processes for a system containing an ideal gas. Here, we present an example of a cyclic engine based on a single quantum mechanical particle confined to a potential well. The efficiency of this engine is shown to equal the Carnot efficiency because quantum dynamics is reversible. The quantum heat engine has a cycle consisting of adiabatic and isothermal quantum processes that are close analogues of the corresponding classical processes.
A quantum heat engine of a specific type is studied. This engine contains a single particle confined in the infinite square well potential with variable width and consists of three processes: the isoenergetic process (which has no classical analogs) as well as the isothermal and adiabatic processes. It is found that the engine possesses exotic properties in its performance. The efficiency takes the maximum value when the expansion ratio of the engine is appropriately set, and, in addition, the lower the temperature is, the higher the maximum efficiency becomes, highlighting aspects of the influence of quantum effects on thermodynamics. A comment is also made on the relevance of this engine to that of Carnot.