arXiv:physics/0611134 · Physical Review A
Measurement of the hyperfine structure of the S1∕2−D5∕2 transition in Ca+43
Jan Benhelm, Gerhard Kirchmair, Umakant D. Rapol, T. Körber, Christian F. Roos, R. Blatt
Abstract
The hyperfine structure of the $4s\phantom{\rule{0.2em}{0ex}}^{2}S_{1∕2}\text{\ensuremath{-}}3d\phantom{\rule{0.2em}{0ex}}^{2}S_{5∕2}$ quadrupole transition at $729\phantom{\rule{0.3em}{0ex}}\mathrm{nm}$ in $^{43}\mathrm{Ca}^{+}$ has been investigated by laser spectroscopy using a single trapped $^{43}\mathrm{Ca}^{+}$ ion. We determine the hyperfine structure constants of the metastable level as ${A}_{{D}_{5∕2}}=3.8931(2)\phantom{\rule{0.2em}{0ex}}\mathrm{MHz}$ and ${B}_{{D}_{5∕2}}=4.241(4)\phantom{\rule{0.2em}{0ex}}\mathrm{MHz}$. The isotope shift of the transition with respect to $^{40}\mathrm{Ca}^{+}$ was measured to be ${\ensuremath{\Delta}}_{\mathrm{iso}}^{43,40}=4134.713(5)\phantom{\rule{0.2em}{0ex}}\mathrm{MHz}$. We demonstrate the existence of transitions that become independent of the first-order Zeeman shift at nonzero low magnetic fields. These transitions might be better suited for building a frequency standard than the well-known ``clock transitions'' between $m=0$ levels at zero magnetic field.