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arXiv:cond-mat/9608039 · Physical Review Letters

Impurity Driven Phase Transition in the Antiferromagnetic Spin-1 Chain

R. A. Hyman, Kun Yang

Published Mar 3, 1997• 111 citations
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Abstract

We study the random antiferromagnetic spin-1 chain by mapping to a random dimerized spin-1/2 chain with antiferromagnetic and ferromagnetic bonds and applying an asymptotically exact real space renormalization procedure. We find that the chain undergoes an impurity driven second order phase transition from the Haldane phase to the random singlet phase as the bond distribution broadens. In the Haldane phase and near the critical point, there is a Griffiths region in which the excitation gap is filled and the magnetic susceptibility diverges in a nonuniversal manner. The correlation length critical exponent is $\ensuremath{\nu}\ensuremath{\approx}2.3$.

DOI
10.1103/physrevlett.78.1783

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We study the random antiferromagnetic spin-1 chain by mapping to a random dimerized spin-1/2 chain with antiferromagnetic and ferromagnetic bonds and applying an asymptotically exact real space renormalization procedure. We find that the chain undergoes an impurity driven second order phase transition from the Haldane phase to the random singlet phase as the bond distribution broadens. In the Haldane phase and near the critical point, there is a Griffiths region in which the excitation gap is filled and the magnetic susceptibility diverges in a nonuniversal manner. The correlation length critical exponent is \ensuremathν\ensuremath≈2.3\ensuremath{\nu}\ensuremath{\approx}2.3\ensuremathν\ensuremath≈2.3.
We use extensive density matrix renormalization group (DMRG) calculations to explore the phase diagram of the random S=1S=1S=1 antiferromagnetic Heisenberg chain with a power-law distribution of the exchange couplings. We use open chains and monitor the lowest gaps, the end-to-end correlation function and the string order parameter. For this distribution at weak disorder, the system is in the gapless Haldane phase with a disorder dependent dynamical exponent, zzz, and z=1z=1z=1 signals the border between the nonsingular and singular regions of the local susceptibility. For strong enough disorder, which approximately corresponds to a uniform distribution, a transition into the random singlet phase is detected, at which the string order parameter as well as the average end-to-end correlation function are vanishing and at the same time the dynamical exponent is divergent. Singularities of physical quantities are found to be somewhat different in the random singlet phase and in the critical point.
We study the random antiferromagnetic spin-1 chain following the evolution of the bond probability distributions under a renormalization group transformation. We use a mapping of the spin-1 chain into an effective spin-1/2 chain with both ferromagnetic (odd bonds) and antiferromagnetic (even and odd bonds) interactions. We obtain a recursion relation for the coupling constants, solving exactly up to a four-spin cluster. Our improved perturbation treatment on these larger clusters shows that the random singlet phase in the spin-1 chain, differently from previous results, is obtained only when 100100%100 of the odd bonds are strong ferromagnetic, i.e., larger than the even antiferromagnetic bonds. Otherwise the ground state is that of a dimerized spin-1/2 chain.
We use a tensor network renormalization group method to study random S=2S=2S=2 antiferromagnetic Heisenberg chains with alternating bond strength distributions. In the absence of randomness, an imposed dimerization with bond alternation induces two quantum critical points between the S=2S=2S=2 Haldane phase, a partially dimerized phase, and a fully dimerized phase, depending on the strength of dimerization. These three phases, called ($\ensuremath{\sigma},4\ensuremath{-}\ensuremath{\sigma}$) = (2,2), (3,1), and (4,0) phases, are valence-bond solid (VBS) states characterized by $\ensuremath{\sigma}$ valence bonds (effective spin-1/2 singlet pairs) forming across even links and $4\ensuremath{-}\ensuremath{\sigma}$ valence bonds on odd links. Here we study the effects of bond randomness on the ground states of the dimerized spin chain, calculating disorder-averaged twist order parameters and spin correlations. We classify the types of random VBS phases depending on the strength of bond randomness RRR and dimerization DDD using the twist order parameter, which has a negative/positive sign for a VBS phase with odd/even $\ensuremath{\sigma}$. Our results demonstrate the existence of a multicritical point in the intermediate disorder regime with finite dimerization, where (2,2), (3,1), and (4,0) phases meet. This multicritical point is at the junction of three phase boundaries in the $R\text{\ensuremath{-}}D$ plane: the (2,2)-(3,1) and (3,1)-(4,0) boundaries that extend to zero randomness, and the (2,2)-(4,0) phase boundary that connects another multicritical point in the undimerized limit. The undimerized multicritical point separates a gapless Haldane phase and an infinite-randomness critical line with the diverging dynamic critical exponent in the large-RRR limit at D=0D=0D=0. Furthermore, we identify the (3,1)-(4,0) phase boundary as an infinite-randomness critical line even at small RRR and find the signature of infinite randomness at the (2,2)-(3,1) phase boundary only in the vicinity of the multicritical point.
The effect of bond randomness on the spin-gapped ground state of the spin-1 bond-alternating antiferromagnetic Heisenberg chain is discussed. By using the loop cluster quantum Monte Carlo method, we investigate the stability of topological order in terms of the recently proposed twist order parameter [M. Nakamura and S. Todo: Phys. Rev. Lett. 89 (2002) 077204]. It is observed that the dimer phases as well as the Haldane phase of the spin-1 Heisenberg chain are robust against a weak randomness, though the valence-bond-solid-like topological order in the latter phase is destroyed by introducing a disorder stronger than the critical value.
The properties of spin-1/2 antiferromagnetic chains with various types of random exchange coupling are studied via an asymptotically exact decimation renormalization-group transformation, which is a generalization of that introduced by Dasgupta and Ma. Random-singlet phases occur in which each spin is paired with one other spin that may be very far away; more exotic phases also occur. The behavior of typical and mean correlation functions is analyzed and found to be very different, with very small sets of spins dominating the latter at long distances as well as the low-temperature thermodynamics. Some of the phase transitions that occur between antiferromagnetically ordered phases and random singlet or other antiferromagnetic phases are also analyzed. For example, if a small uniaxial anisotropy perturbation is added to a random Heisenberg antiferromagnetic chain, a transition occurs from a random-singlet phase to an Ising antiferromagnetic phase, as the anisotropy changes sign from easy plane to easy axis. The staggered magnetization vanishes at the transition with critical exponent \ensuremath{\beta}=8/(1+ \ensuremath{\surd}7 ). Possible implications for the properties of random quantum magnetic systems in higher dimensions are briefly discussed.