Quantum extensions of the Gallavotti–Cohen fluctuation theorem (FT) for the entropy production have been discussed by several authors. There is a practical gap between microscopic forms of FT and mesoscopic (i.e. not purely Hamiltonian) forms for open systems. In a microscopic setup, it is easy to state and to prove FT. In a mesoscopic setup, it is difficult to identify fluctuations of the entropy production. (This difficulty is absent in the classical case.) We discuss a particular mesoscopic model: a Lindblad master equation, in which we state FT and, more importantly, connect it rigorously with the underlying microscopic FT. We also remark that FT is satisfied by the Lesovik–Levitov formula for statistics of charge transport.
Quantum extensions of the Gallavotti–Cohen fluctuation theorem (FT) for the entropy production have been discussed by several authors. There is a practical gap between microscopic forms of FT and mesoscopic (i.e. not purely Hamiltonian) forms for open systems. In a microscopic setup, it is easy to state and to prove FT. In a mesoscopic setup, it is difficult to identify fluctuations of the entropy production. (This difficulty is absent in the classical case.) We discuss a particular mesoscopic model: a Lindblad master equation, in which we state FT and, more importantly, connect it rigorously with the underlying microscopic FT. We also remark that FT is satisfied by the Lesovik–Levitov formula for statistics of charge transport.
The celebrated Evans--Searles, respectively Gallavotti--Cohen, fluctuation theorem concerns certain universal statistical features of the entropy production rate of a classical system in a transient, respectively steady, state. In this paper, we review and compare several possible extensions of these fluctuation theorems to quantum systems. We present, in an introductory way, the approach proposed in a recent series of works [Lett. Math. Phys. 114, 32 (2024): doi:10.1007/s11005-024-01777-0], [Rev. Math. Phys 38, 2461006 (2026): doi:10.1142/S0129055X24610063], [Commun. Math. Phys. 406, 201 (2025): 10.1007/s00220-025-05360-z] and [J. Math. Phys. 67, 022101 (2026): doi:10.1063/5.0311182] including a previously missing extension of the Gallavotti--Cohen (steady state) version of the FT to two-time measurement entropy production in the algebraic setting of quantum dynamical systems. We focus on the open quantum systems, where a small system interacts with several (infinitely extended) reservoirs, and discuss the following approaches: naive, two-time measurement, phase space contraction and ancilla state tomography. We review the connection with modular theory. The latter provides a way to extend the classical notions to the quantum domain. We discuss the quantum version of the principle of regular entropic fluctuations, introduced in the classical context in [Nonlinearity 24, 699 (2011): doi:10.1088/0951-7715/24/3/003]. Finally, we relate the statistical properties of these various notions of entropy production to spectral resonances of quantum transfer operators and apply this approach to a paradigmatic model of non-equilibrium statistical mechanics: the spin-fermion model. The results presented here shed a new light on the nature of entropic fluctuations in quantum statistical mechanics.
We study fluctuation theorems for open quantum systems with a non-Markovian heat bath using the approach of quantum master equations and examine the physical quantities that appear in those fluctuation theorems. The approach of Markovian quantum master equations to the fluctuation theorems was developed by Esposito and Mukamel [Phys. Rev. E 73, 046129 (2006)]. We show that their discussion can be formally generalized to the case of a non-Markovian heat bath when the local system is linearly connected to a Gaussian heat bath with the spectrum distribution of the Drude form. We found by numerically simulating the spin-boson model in non-Markovian regime that the "detailed balance" condition is well satisfied except in a strongly nonequilibrium transient situation, and hence our generalization of the definition of the "entropy production" is almost always legitimate. Therefore, our generalization of the fluctuation theorem seems meaningful in wide regions.
Abstract The celebrated Evans–Searles, respectively Gallavotti–Cohen, fluctuation theorem concerns certain universal statistical features of the entropy production rate of a classical system in a transient, respectively steady, state. In this paper, we consider and compare several possible extensions of these fluctuation theorems to quantum systems. In addition to the direct two-time measurement approach whose discussion is based on Benoist et al. (Lett Math Phys 114:32, 2024. https://doi.org/10.1007/s11005-024-01777-0 ), we discuss a variant where measurements are performed indirectly on an auxiliary system called ancilla, and which allows to retrieve non-trivial statistical information using ancilla state tomography. We also show that modular theory provides a way to extend the classical notion of phase space contraction rate to the quantum domain, which leads to a third extension of the fluctuation theorems. We further discuss the quantum version of the principle of regular entropic fluctuations, introduced in the classical context in Jakšić et al. (Nonlinearity 24:699, 2011. https://doi.org/10.1088/0951-7715/24/3/003 ). Finally, we relate the statistical properties of these various notions of entropy production to spectral resonances of quantum transfer operators. The obtained results shed a new light on the nature of entropic fluctuations in quantum statistical mechanics.
We study fluctuation theorems for open quantum systems with a non-Markovian heat bath using the approach of quantum master equations and examine the physical quantities that appear in those fluctuation theorems. The approach of Markovian quantum master equations to the fluctuation theorems was developed by Esposito and Mukamel [Phys. Rev. E {\bf73}, 046129 (2006)]. We show that their discussion can be formally generalized to the case of a non-Markovian heat bath when the local system is linearly connected to a Gaussian heat bath with the spectrum distribution of the Drude form. We found by numerically simulating the spin-boson model in non-Markovian regime that the detailed balance condition is well satisfied except in a strongly non-equilibrium transient situation, and hence our generalization of the definition of the entropy production is almost always legitimate. Therefore, our generalization of the fluctuation theorem seems meaningful in wide regions.
We present a general quantum fluctuation theorem for the entropy production of an open quantum system coupled to multiple environments, not necessarily at equilibrium. Such a general theorem, when restricted to the weak-coupling and Markovian regime, holds for both local and global master equations, corroborating the thermodynamic consistency of local quantum master equations. The theorem is genuinely quantum, as it can be expressed in terms of conservation of a Hermitian operator, describing the dynamics of the system state operator and of the entropy change in the baths. The integral fluctuation theorem follows from the properties of such an operator. Furthermore, it is also valid when the system is described by a time-dependent Hamiltonian. As such, the quantum Jarzynski equality is a particular case of the general result presented here. Moreover, our result can be extended to nonthermal baths, as long as microreversibility is preserved. We present some numerical examples to showcase the exact results previously obtained. We finally generalize the fluctuation theorem to the case where the interaction between the system and the bath is explicitly taken into account. We show that the fluctuation theorem amounts to a relation between time-reversed dynamics of the global density matrix and a two-time correlation function along the forward dynamics involving the baths' entropy alone.
We introduce a numerical method to sample the distributions of charge, heat, and entropy production in open quantum systems coupled strongly to macroscopic reservoirs, with both temporal and energy resolution and beyond the linear-response regime. Our method exploits the mesoscopic-leads formulation, where macroscopic reservoirs are modeled by a finite collection of modes that are continuously damped toward thermal equilibrium by an appropriate Gorini-Kossakowski-Sudarshan-Lindblad master equation. Focussing on noninteracting fermionic systems, we access the time-resolved full counting statistics through a trajectory unraveling of the master equation. We show that the integral fluctuation theorems for the total entropy production, as well as the martingale and uncertainty entropy production, hold. Furthermore, we investigate the fluctuations of the dissipated heat in finite-time information erasure. Conceptually, our approach extends the continuous-time trajectory description of quantum stochastic thermodynamics beyond the regime of weak system-environment coupling.