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arXiv:1105.3579 · Physical Review E

Test of fluctuation theorems in non-Markovian open quantum systems

Tatsuro Kawamoto, Naomichi Hatano

Published Sep 13, 2011• 15 citations
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Abstract

We study fluctuation theorems for open quantum systems with a non-Markovian heat bath using the approach of quantum master equations and examine the physical quantities that appear in those fluctuation theorems. The approach of Markovian quantum master equations to the fluctuation theorems was developed by Esposito and Mukamel [Phys. Rev. E 73, 046129 (2006)]. We show that their discussion can be formally generalized to the case of a non-Markovian heat bath when the local system is linearly connected to a Gaussian heat bath with the spectrum distribution of the Drude form. We found by numerically simulating the spin-boson model in non-Markovian regime that the "detailed balance" condition is well satisfied except in a strongly nonequilibrium transient situation, and hence our generalization of the definition of the "entropy production" is almost always legitimate. Therefore, our generalization of the fluctuation theorem seems meaningful in wide regions.

DOI
10.1103/physreve.84.031116

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We study fluctuation theorems for open quantum systems with a non-Markovian heat bath using the approach of quantum master equations and examine the physical quantities that appear in those fluctuation theorems. The approach of Markovian quantum master equations to the fluctuation theorems was developed by Esposito and Mukamel [Phys. Rev. E 73, 046129 (2006)]. We show that their discussion can be formally generalized to the case of a non-Markovian heat bath when the local system is linearly connected to a Gaussian heat bath with the spectrum distribution of the Drude form. We found by numerically simulating the spin-boson model in non-Markovian regime that the "detailed balance" condition is well satisfied except in a strongly nonequilibrium transient situation, and hence our generalization of the definition of the "entropy production" is almost always legitimate. Therefore, our generalization of the fluctuation theorem seems meaningful in wide regions.
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We study fluctuation theorems for open quantum systems using the approach of quantum master equations, and examine the thermodynamic quantities that appear in those fluctuation theorems. The approach of Markovian quantum master equations to the fluctuation theorems was developed by Esposito and Mukamel [Phys. Rev. E 73, 046129 (2006)]. We show that their discussion can be formally generalized to the case of a non-Markovian heat bath in the case where the local system is linearly connected to the Gaussian heat bath with the spectrum distribution of the Drude form. However, we found that the thermodynamic quantities that appear in those fluctuation theorems can be ill-defined or inconsistent with each other by numerically simulating the spin-boson model.
We present a general quantum fluctuation theorem for the entropy production of an open quantum system coupled to multiple environments, not necessarily at equilibrium. Such a general theorem, when restricted to the weak-coupling and Markovian regime, holds for both local and global master equations, corroborating the thermodynamic consistency of local quantum master equations. The theorem is genuinely quantum, as it can be expressed in terms of conservation of a Hermitian operator, describing the dynamics of the system state operator and of the entropy change in the baths. The integral fluctuation theorem follows from the properties of such an operator. Furthermore, it is also valid when the system is described by a time-dependent Hamiltonian. As such, the quantum Jarzynski equality is a particular case of the general result presented here. Moreover, our result can be extended to nonthermal baths, as long as microreversibility is preserved. We present some numerical examples to showcase the exact results previously obtained. We finally generalize the fluctuation theorem to the case where the interaction between the system and the bath is explicitly taken into account. We show that the fluctuation theorem amounts to a relation between time-reversed dynamics of the global density matrix and a two-time correlation function along the forward dynamics involving the baths' entropy alone.
We examine the elements of the balance equation of entropy in open quantum evolutions and their response as we go from a Markovian to a non-Markovian situation. In particular, we look at the heat current and entropy production rate in the non-Markovian reduced evolution, as well as a Markovian limit of the same, experienced by one of two interacting systems immersed in a Markovian bath. The analysis naturally leads us to define a heat current deficit and an entropy production rate deficit, which are differences between the global and local versions of the corresponding quantities. The investigation leads, in certain cases, to a complementarity of the time-integrated heat current deficit and the relative entropy of entanglement between the two systems.
Entropy production and the detailed fluctuation theorem are of fundamental importance for thermodynamic processes. In this paper we study the multiple entropy production for multitime quantum processes in a unified framework. For closed quantum systems and Markovian open quantum systems, the given entropy productions all satisfy the detailed fluctuation relation. This also shows that the entropy production rate under these processes is non-negative. For non-Markovian open quantum systems, the memory effect can lead to a negative-entropy production rate. Thus, in general, the entropy production of the marginal distribution does not satisfy the detailed fluctuation theorem relation. Our framework can be applied to a wide range of physical systems and dynamics. It provides a systematic tool for studying entropy production and its rate under arbitrary quantum processes.
Markovian quantum master equations (MQMEs) were established nearly half a century ago. They have often been used in the study of irreversible thermodynamics. However, the previous results were mainly concerned about ensemble averages; the stochastic thermodynamics of these systems went unnoticed for a very long time. This situation remained unchanged until a variety of fluctuation theorems in classical and quantum regimes were found in the past two decades. In this paper, we systematically summarize the current understanding on the stochastic heat and work in MQMEs using two distinct strategies. One strategy is to treat the system and its surrounding heat bath as a closed quantum system, to suppose that the evolution of the composite system is unitary under a time-dependent total Hamiltonian and to define the heat and work as the changes in energy by applying two energy measurements scheme to the composite system. The other strategy is to unravel these MQMEs into random quantum jump trajectories (QJTs) and to define the stochastic heat and work along the individual trajectories. Many important physical concepts, mathematical techniques, and fluctuation theorems at different descriptive levels are given in as detailed a manner as possible. We also use concrete models to illustrate these results.