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arXiv:cond-mat/0608319

Statistical mechanics of thermal contact between system and bath with long-range interactions

Ramandeep S. Johal, Renuka Rai

Published Aug 15, 2006• 0 citations
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Abstract

In this paper, we address the possibility of generalising the standard analysis of thermal contact between a sample system and a heat bath, by including long range interactions between them. As a concrete example, both system and bath are treated within the long range Ising model. For this model, we derive the equilibrium probability distribution of the energy of the sample system. Equilibrium properties of the system magnetisation and stability of the solutions is discussed. We find existence of a metastable phase below a critical temperature of the bath.

DOI
10.48550/arxiv.cond-mat/0608319

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In this paper, we address the possibility of generalising the standard analysis of thermal contact between a sample system and a heat bath, by including long range interactions between them. As a concrete example, both system and bath are treated within the long range Ising model. For this model, we derive the equilibrium probability distribution of the energy of the sample system. Equilibrium properties of the system magnetisation and stability of the solutions is discussed. We find existence of a metastable phase below a critical temperature of the bath.
We introduce a Hamiltonian dynamics for the description of long-range interacting systems in contact with a thermal bath (i.e., in the canonical ensemble). The dynamics confirms statistical mechanics equilibrium predictions for the Hamiltonian Mean Field model and the equilibrium ensemble equivalence. We find that long-lasting quasi-stationary states persist in presence of the interaction with the environment. Our results indicate that quasi-stationary states are indeed reproducible in real physical experiments.
A system put in contact with a large heat bath normally thermalizes. This means that the state of the system ρS(t) approaches an equilibrium state ρ(eq)(S), the latter depending only on macroscopic characteristics of the bath (e.g., temperature) but not on the initial state of the system. The above statement is the cornerstone of the equilibrium statistical mechanics; its validity and its domain of applicability are central questions in the studies of the foundations of statistical mechanics. In the present paper we concentrate on one aspect of thermalization, namely, on the system initial state independence (ISI) of ρ(eq)(S). A necessary condition for the system ISI is derived in the quantum framework. We use the derived condition to prove the absence of the system ISI in a specific class of models. Namely, we consider a single spin coupled to a large bath, the interaction term commuting with the bath self-Hamiltonian (but not with the system self-Hamiltonian). Although the model under consideration is nontrivial enough to exhibit the decoherence and the approach to equilibrium, the derived necessary condition is not fulfilled and thus ρ(eq)(S) depends on the initial state of the spin.
A system put in contact with a large heat bath normally thermalizes. This means that the state of the system ρℐ(t) approaches an equilibrium state ρ eq ℐ , the latter depending only on macroscopic characteristics of the bath (e.g. temperature), but not on the initial state of the system. The above statement is the cornerstone of the equilibrium statistical mechanics; its validity and its domain of applicability are central questions in the studies of the foundations of statistical mechanics. In the present contribution we discuss the recently proven general theorems about thermalization and demonstrate how they work in exactly solvable models. In particular, we review a necessary condition for the system initial state independence (ISI) of ρ eq ℐ , which was proven in our previous work, and apply it for two exactly solvable models, the XX spin chain and a central spin model with a special interaction with the environment. In the latter case we are able to prove the absence of the system ISI. Also the Eigenstate Thermalization Hypothesis is discussed. It is pointed out that although it is supposed to be generically true in essentially not-integrable (chaotic) quantum systems, it is how-ever also valid in the integrable XX model.
The circumstances under which a system reaches thermal equilibrium, and how to derive this from basic dynamical laws, has been a major question from the very beginning of thermodynamics and statistical mechanics. Despite considerable progress, it remains an open problem. Motivated by this issue, we address the more general question of equilibration. We prove, with virtually full generality, that reaching equilibrium is a universal property of quantum systems: almost any subsystem in interaction with a large enough bath will reach an equilibrium state and remain close to it for almost all times. We also prove several general results about other aspects of thermalization besides equilibration, for example, that the equilibrium state does not depend on the detailed microstate of the bath.
We consider non-equilibrium open statistical systems, subject to potentials and to external “heat baths” (hb) at thermal equilibrium at temperature T (either with ab initio dissipation or without it). Boltzmann’s classical equilibrium distributions generate, as Gaussian weight functions in momenta, orthogonal polynomials in momenta (the position-independent Hermite polynomialsHn’s). The moments of non-equilibrium classical distributions, implied by the Hn’s, fulfill a hierarchy: for long times, the lowest moment dominates the evolution towards thermal equilibrium, either with dissipation or without it (but under certain approximation). We revisit that hierarchy, whose solution depends on operator continued fractions. We review our generalization of that moment method to classical closed many-particle interacting systems with neither a hb nor ab initio dissipation: with initial states describing thermal equilibrium at T at large distances but non-equilibrium at finite distances, the moment method yields, approximately, irreversible thermalization of the whole system at T, for long times. Generalizations to non-equilibrium quantum interacting systems meet additional difficulties. Three of them are: (i) equilibrium distributions (represented through Wigner functions) are neither Gaussian in momenta nor known in closed form; (ii) they may depend on dissipation; and (iii) the orthogonal polynomials in momenta generated by them depend also on positions. We generalize the moment method, dealing with (i), (ii) and (iii), to some non-equilibrium one-particle quantum interacting systems. Open problems are discussed briefly.
We show that a large class of nonequilibrium many-body systems in contact with two thermal baths admit an exact mapping onto equivalent equilibrium systems. This mapping provides direct access to nonequilibrium phase transition points from known equilibrium results, irrespective of the model, interaction topology, or distance from equilibrium. We verify the universality of this correspondence using paradigmatic models (Ising, Potts, and Blume-Capel), and highlight distinctive features in entropy production close to critical and tricritical points. Our findings connect equilibrium and nonequilibrium statistical mechanics, with implications for microscopic thermal machines and stochastic thermodynamics.