A system put in contact with a large heat bath normally thermalizes. This means that the state of the system ρℐ(t) approaches an equilibrium state ρ eq ℐ , the latter depending only on macroscopic characteristics of the bath (e.g. temperature), but not on the initial state of the system. The above statement is the cornerstone of the equilibrium statistical mechanics; its validity and its domain of applicability are central questions in the studies of the foundations of statistical mechanics. In the present contribution we discuss the recently proven general theorems about thermalization and demonstrate how they work in exactly solvable models. In particular, we review a necessary condition for the system initial state independence (ISI) of ρ eq ℐ , which was proven in our previous work, and apply it for two exactly solvable models, the XX spin chain and a central spin model with a special interaction with the environment. In the latter case we are able to prove the absence of the system ISI. Also the Eigenstate Thermalization Hypothesis is discussed. It is pointed out that although it is supposed to be generically true in essentially not-integrable (chaotic) quantum systems, it is how-ever also valid in the integrable XX model.
A system put in contact with a large heat bath normally thermalizes. This means that the state of the system ρℐ(t) approaches an equilibrium state ρ eq ℐ , the latter depending only on macroscopic characteristics of the bath (e.g. temperature), but not on the initial state of the system. The above statement is the cornerstone of the equilibrium statistical mechanics; its validity and its domain of applicability are central questions in the studies of the foundations of statistical mechanics. In the present contribution we discuss the recently proven general theorems about thermalization and demonstrate how they work in exactly solvable models. In particular, we review a necessary condition for the system initial state independence (ISI) of ρ eq ℐ , which was proven in our previous work, and apply it for two exactly solvable models, the XX spin chain and a central spin model with a special interaction with the environment. In the latter case we are able to prove the absence of the system ISI. Also the Eigenstate Thermalization Hypothesis is discussed. It is pointed out that although it is supposed to be generically true in essentially not-integrable (chaotic) quantum systems, it is how-ever also valid in the integrable XX model.
A system put in contact with a large heat bath normally thermalizes. This means that the state of the system ρS(t) approaches an equilibrium state ρ(eq)(S), the latter depending only on macroscopic characteristics of the bath (e.g., temperature) but not on the initial state of the system. The above statement is the cornerstone of the equilibrium statistical mechanics; its validity and its domain of applicability are central questions in the studies of the foundations of statistical mechanics. In the present paper we concentrate on one aspect of thermalization, namely, on the system initial state independence (ISI) of ρ(eq)(S). A necessary condition for the system ISI is derived in the quantum framework. We use the derived condition to prove the absence of the system ISI in a specific class of models. Namely, we consider a single spin coupled to a large bath, the interaction term commuting with the bath self-Hamiltonian (but not with the system self-Hamiltonian). Although the model under consideration is nontrivial enough to exhibit the decoherence and the approach to equilibrium, the derived necessary condition is not fulfilled and thus ρ(eq)(S) depends on the initial state of the spin.
We study the validity of the eigenstate thermalization hypothesis (ETH) and its role for the occurrence of initial-state independent (ISI) equilibration in closed quantum many-body systems. Using the concept of dynamical typicality, we present an extensive numerical analysis of energy exchange in integrable and nonintegrable spin-1/2 systems of large size outside the range of exact diagonalization. In the case of nonintegrable systems, our finite-size scaling shows that the ETH becomes valid in the thermodynamic limit and can serve as the underlying mechanism for ISI equilibration. In the case of integrable systems, however, indication of ISI equilibration has been observed despite the violation of the ETH. We establish a connection between this observation and the need of choosing a proper parameter within the ETH.
Identifying the general mechanics behind the equilibration of a complex isolated quantum system towards a state described by only a few parameters has been the focus of attention in non-equilibrium thermodynamics. And several experimentally unproven conjectures are proposed for the statistical description of quantum (non-)integrable models. The plausible eigenstate thermalization hypothesis (ETH), which suggests that each energy eigenstate itself is thermal, plays a crucial role in understanding the quantum thermalization in non-integrable systems; it is commonly believed that it does not exist in integrable systems. Nevertheless, integrable systems can still relax to the generalized Gibbs ensemble. From a microscopic perspective, understanding the origin of this generalized thermalization that occurs in an isolated integrable system is a fundamental open question lacking experimental investigations. Herein, we experimentally investigated the spin subsystem relaxation in an isolated spin-orbit coupling quantum system. By applying the quantum state engineering technique, we initialized the system with various distribution widths in the mutual eigenbasis of the conserved quantities. Then, we compared the steady state of the spin subsystem reached in a long-time coherent dynamics to the prediction of a generalized version of ETH and the underlying mechanism of the generalized thermalization is experimentally verified for the first time. Our results facilitate understanding the origin of quantum statistical mechanics.
If we prepare an isolated, interacting quantum system in an eigenstate and perturb a local observable at an initial time, its expectation value will relax towards a thermal expectation value, even though the time evolution of the system is deterministic. The eigenstate thermalization hypothesis (ETH) of Deutsch and Srednicki suggests that this is possible because each eigenstate of the full quantum system acts as a thermal bath to its subsystems, such that the reduced density matrices of the subsystems resemble thermal density matrices. Here, we use the observation that the eigenvalue distribution of interacting quantum systems is a Gaussian under very general circumstances, and Dyson Brownian motion random matrix theory, to derive the ETH and thereby elevate it from hypothesis to theory. Our analysis provides a derivation of statistical mechanics which neither requires the concepts of ergodicity or typicality, nor that of entropy. Thermodynamic equilibrium follows solely from the applicability of quantum mechanics to large systems and the absence of integrability.
In their seminal work, Fermi, Pasta, Ulam and Tsingou explored the connection between statistical mechanics and dynamical properties, such as chaos and ergodicity. Even today, seventy years later, the topic is not fully understood: while most results of statistical mechanics require the ergodic hypothesis to be rigorously proved, there are many indications that these predictions, both in and out of equilibrium, hold even in the absence of a rigorous form of ergodicity. Motivated by the above considerations, in this work we reconsider the point of view that the relevant ingredients for the validity of statistical mechanics are the large number of degrees of freedom and the choice of extensive observables, while the details of the dynamics do not play an essential role. This is the idea behind Khinchin's famous proof of the typicality of macroscopic observables at equilibrium. We extend this perspective to the context of non equilibrium, by investigating the thermalization properties of both harmonic (integrable) and nonharmonic (chaotic) oscillator chains initially prepared in out-of-equilibrium conditions. In integrable systems, thermalization occurs, or not, depending on the observable. In the chaotic regime, instead, thermalization is reached by any observable, although the relaxation timescale might be larger than the observation time.
In this review, we discuss the decoherence and thermalization of a quantum spin system interacting with a spin bath environment, by numerically solving the time-dependent Schrödinger equation of the whole system. The effects of the topologic structure and the initial state of the environment on the decoherence of the two-spin and many-spin system are discussed. The role of different spin-spin coupling is considered. We show under which conditions the environment drives the reduced density matrix of the system to a fully decoherent state, and how the diagonal elements of the reduced density matrix approach those expected for the system in the microcanonical or canonical ensemble, depending on the character of the additional integrals of motion. Our demonstration does not rely on time-averaging of observables nor does it assume that the coupling between system and bath is weak. Our findings show that the microcanonical distribution (in each eigenenergy subspace) and canonical ensemble are states that may result from pure quantum dynamics, suggesting that quantum mechanics may be regarded as the foundation of quantum statistical mechanics. Furthermore, our numerical results show that a fully decoherent quantum system prefers to stay in an equilibrium state with a maximum entropy, indicating the validity of the second law of thermodynamics in the decoherence process.