A system put in contact with a large heat bath normally thermalizes. This means that the state of the system ρS(t) approaches an equilibrium state ρ(eq)(S), the latter depending only on macroscopic characteristics of the bath (e.g., temperature) but not on the initial state of the system. The above statement is the cornerstone of the equilibrium statistical mechanics; its validity and its domain of applicability are central questions in the studies of the foundations of statistical mechanics. In the present paper we concentrate on one aspect of thermalization, namely, on the system initial state independence (ISI) of ρ(eq)(S). A necessary condition for the system ISI is derived in the quantum framework. We use the derived condition to prove the absence of the system ISI in a specific class of models. Namely, we consider a single spin coupled to a large bath, the interaction term commuting with the bath self-Hamiltonian (but not with the system self-Hamiltonian). Although the model under consideration is nontrivial enough to exhibit the decoherence and the approach to equilibrium, the derived necessary condition is not fulfilled and thus ρ(eq)(S) depends on the initial state of the spin.
A system put in contact with a large heat bath normally thermalizes. This means that the state of the system ρS(t) approaches an equilibrium state ρ(eq)(S), the latter depending only on macroscopic characteristics of the bath (e.g., temperature) but not on the initial state of the system. The above statement is the cornerstone of the equilibrium statistical mechanics; its validity and its domain of applicability are central questions in the studies of the foundations of statistical mechanics. In the present paper we concentrate on one aspect of thermalization, namely, on the system initial state independence (ISI) of ρ(eq)(S). A necessary condition for the system ISI is derived in the quantum framework. We use the derived condition to prove the absence of the system ISI in a specific class of models. Namely, we consider a single spin coupled to a large bath, the interaction term commuting with the bath self-Hamiltonian (but not with the system self-Hamiltonian). Although the model under consideration is nontrivial enough to exhibit the decoherence and the approach to equilibrium, the derived necessary condition is not fulfilled and thus ρ(eq)(S) depends on the initial state of the spin.
A system put in contact with a large heat bath normally thermalizes. This means that the state of the system ρℐ(t) approaches an equilibrium state ρ eq ℐ , the latter depending only on macroscopic characteristics of the bath (e.g. temperature), but not on the initial state of the system. The above statement is the cornerstone of the equilibrium statistical mechanics; its validity and its domain of applicability are central questions in the studies of the foundations of statistical mechanics. In the present contribution we discuss the recently proven general theorems about thermalization and demonstrate how they work in exactly solvable models. In particular, we review a necessary condition for the system initial state independence (ISI) of ρ eq ℐ , which was proven in our previous work, and apply it for two exactly solvable models, the XX spin chain and a central spin model with a special interaction with the environment. In the latter case we are able to prove the absence of the system ISI. Also the Eigenstate Thermalization Hypothesis is discussed. It is pointed out that although it is supposed to be generically true in essentially not-integrable (chaotic) quantum systems, it is how-ever also valid in the integrable XX model.
In this review, we discuss the decoherence and thermalization of a quantum spin system interacting with a spin bath environment, by numerically solving the time-dependent Schrödinger equation of the whole system. The effects of the topologic structure and the initial state of the environment on the decoherence of the two-spin and many-spin system are discussed. The role of different spin-spin coupling is considered. We show under which conditions the environment drives the reduced density matrix of the system to a fully decoherent state, and how the diagonal elements of the reduced density matrix approach those expected for the system in the microcanonical or canonical ensemble, depending on the character of the additional integrals of motion. Our demonstration does not rely on time-averaging of observables nor does it assume that the coupling between system and bath is weak. Our findings show that the microcanonical distribution (in each eigenenergy subspace) and canonical ensemble are states that may result from pure quantum dynamics, suggesting that quantum mechanics may be regarded as the foundation of quantum statistical mechanics. Furthermore, our numerical results show that a fully decoherent quantum system prefers to stay in an equilibrium state with a maximum entropy, indicating the validity of the second law of thermodynamics in the decoherence process.
The circumstances under which a system reaches thermal equilibrium, and how to derive this from basic dynamical laws, has been a major question from the very beginning of thermodynamics and statistical mechanics. Despite considerable progress, it remains an open problem. Motivated by this issue, we address the more general question of equilibration. We prove, with virtually full generality, that reaching equilibrium is a universal property of quantum systems: almost any subsystem in interaction with a large enough bath will reach an equilibrium state and remain close to it for almost all times. We also prove several general results about other aspects of thermalization besides equilibration, for example, that the equilibrium state does not depend on the detailed microstate of the bath.
Providing the microscopic behavior of a thermalization process has always been an intriguing issue. There are several models of thermalization, which often require interaction of the system under consideration with the microscopic constituents of the macroscopic heat bath. With the aim to simulate such a thermalization process, here we look at the thermalization of a two-level quantum system under the action of a Markovian master equation corresponding to memory-less action of a heat bath, kept at a certain temperature, using a single-qubit ancilla. A two-qubit interaction Hamiltonian ( H th , say) is then designed —with a single-qubit thermal state as the initial state of the ancilla— which gives rise to thermalization of the system qubit in the infinite time limit. Further, we study the general form of Hamiltonian, of which ours is a special case, and look for the conditions for thermalization to occur. We also derive a Lindblad-type non-Markovian master equation for the system dynamics under the general form of system-ancilla Hamiltonian.
Focusing on isolated macroscopic systems, described either in terms of a quantum mechanical or a classical model, our two key questions are: In how far does an initial ensemble (usually far from equilibrium and largely unknown in detail) evolve towards a stationary long-time behavior ("equilibration")? In how far is this steady state in agreement with the microcanonical ensemble as predicted by Statistical Mechanics ("thermalization")? In the first part of the paper, a recently developed quantum mechanical treatment of the problem is briefly summarized, putting particular emphasis on the realistic modeling of experimental measurements and non-equilibrium initial conditions. Within this framework, equilibration can be proven under very weak assumptions about those measurements and initial conditions, while thermalization still requires quite strong additional hypotheses. In the second part, an analogous approach within the framework of classical mechanics is developed and compared with the quantum case. In particular, the assumptions to guarantee classical equilibration are now rather strong, while thermalization then follows under relatively weak additional conditions.
The emergence of classical behavior and the origin of thermal equilibrium are two central problems in the foundations of physics. In the standard accounts, both phenomena are typically explained through interactions with an external environment: decoherence suppresses quantum interference, while coupling to a thermal bath drives relaxation toward equilibrium. Over the last decades, however, it has become clear that equilibration and thermalization can arise even in fully isolated quantum systems, in the operational sense that the expectation values of relevant observables remain close to equilibrium values for most of the time. Here, we ask whether the same intrinsic equilibration mechanism can also account for the emergence of classical behavior. Using rigorous bounds on equilibration in closed systems, we derive sufficient conditions under which a time-evolved pure state becomes, for most times, operationally indistinguishable from a classical mixture associated with a chosen physical property. We identify two complementary routes to such operational classicality: either the chosen property almost commutes with the system Hamiltonian or the observables used to probe the system lose access to the remaining coherence after equilibration. Our results show that classical behavior need not be confined to the energy basis and may emerge even when substantial coherence remains present in the equilibrium state. This establishes a direct connection between two foundational questions: the origin of thermalization in isolated quantum systems and the quantum-to-classical transition