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arXiv:cond-mat/0310525 · Physical Review B

Quasiparticle number fluctuations in superconductors

Christopher M. Wilson, D. E. Prober

Published Mar 30, 2004• 53 citations
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Abstract

We present a general theory of quasiparticle number fluctuations in superconductors. The theory uses the master equation formalism. First, we develop the theory for a single occupation variable. Although this simple system is insufficient to describe fluctuations in a physical superconductor, it is illustrative, allowing this discussion to serve as a self-contained introduction. We go on to develop a multivariate theory that allows for an arbitrary number of levels with transitions of arbitrary size between levels. We specialize the multivariate theory for two particular cases. First, we consider intrinsic quasiparticle fluctuations. In a previous Letter, these results were used to describe time-resolved measurements of thermodynamic fluctuations in a superconducting Al box [C.M. Wilson, L. Frunzio, and D.E. Prober, Phys. Rev. Lett. 87, 067004 (2001)]. Finally, we extend these results to include fluctuations due to extrinsic loss processes.

DOI
10.1103/physrevb.69.094524

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We present a general theory of quasiparticle number fluctuations in superconductors. The theory uses the master equation formalism. First, we develop the theory for a single occupation variable. Although this simple system is insufficient to describe fluctuations in a physical superconductor, it is illustrative, allowing this discussion to serve as a self-contained introduction. We go on to develop a multivariate theory that allows for an arbitrary number of levels with transitions of arbitrary size between levels. We specialize the multivariate theory for two particular cases. First, we consider intrinsic quasiparticle fluctuations. In a previous Letter, these results were used to describe time-resolved measurements of thermodynamic fluctuations in a superconducting Al box [C.M. Wilson, L. Frunzio, and D.E. Prober, Phys. Rev. Lett. 87, 067004 (2001)]. Finally, we extend these results to include fluctuations due to extrinsic loss processes.
In superconducting qubits, the interaction of the qubit degree of freedom with quasiparticles defines a fundamental limitation for the qubit coherence. We develop a theory of the pure dephasing rate ${\ensuremath{\Gamma}}_{\ensuremath{\phi}}$ caused by quasiparticles tunneling through a Josephson junction and of the inhomogeneous broadening due to changes in the occupations of Andreev states in the junction. To estimate ${\ensuremath{\Gamma}}_{\ensuremath{\phi}}$, we derive a master equation for the qubit dynamics. The tunneling rate of free quasiparticles is enhanced by their large density of states at energies close to the superconducting gap. Nevertheless, we find that ${\ensuremath{\Gamma}}_{\ensuremath{\phi}}$ is small compared to the rates determined by extrinsic factors in most of the current qubit designs (phase and flux qubits, transmon, fluxonium). The split transmon, in which a single junction is replaced by a SQUID loop, represents an exception that could make possible the measurement of ${\ensuremath{\Gamma}}_{\ensuremath{\phi}}$. Fluctuations of the qubit frequency leading to inhomogeneous broadening may be caused by the fluctuations in the occupation numbers of the Andreev states associated with a phase-biased Josephson junction. This mechanism may be revealed in qubits with small-area junctions, since the smallest relative change in frequency it causes is of the order of the inverse number of transmission channels in the junction.
The quasiparticle density observed in low-temperature superconducting circuits is several orders of magnitude larger than the value expected at thermal equilibrium. The tunneling of this excess of quasiparticles across Josephson junctions is recognized as one of the main loss and decoherence mechanisms in superconducting qubits. Here we present a unified impedance theory that accounts for quasiparticle energy loss in circuit regions both far from and near to (across) junctions. Our theory leverages the recent experimental demonstration that the excess quasiparticles are in quasiequilibrium [Connolly et al., Phys. Rev. Lett. 132, 217001 (2024)] and uses a generalized fluctuation-dissipation theorem to predict the amount of charge and flux noise generated by them. We compute the resulting energy relaxation time T1{T}_{1}T1​ in transmon qubits with and without junction asymmetric gap engineering, and show that quasiparticles residing away from junctions can play a dominant role in the former case. They also may provide an upper limit for resonator quality factors if the density of amorphous two-level systems is reduced. In addition, we show that charge noise from quasiparticles leads to flux noise that is logarithmic in frequency, giving rise to a ``nearly white'' contribution that is comparable to the flux noise observed in flux qubits. This contrasts with amorphous two-level systems, whose associated flux noise is shown to be super-Ohmic. We discuss how this quasiparticle flux noise can limit ${T}_{2}^{\ensuremath{\ast}}$ coherence times in flux-tunable qubits. The final conclusion is that asymmetric gap engineering can greatly reduce noise and increase coherence times in superconducting qubits.
We investigate the energy and phase relaxation of a superconducting qubit caused by a single quasiparticle. In our model, the qubit is an isolated system consisting of a small island (Cooper-pair box) and a larger superconductor (reservoir) connected with each other by a tunable Josephson junction. If such a system contains an odd number of electrons, then even at lowest temperatures a single quasiparticle is present in the qubit. Tunneling of a quasiparticle between the reservoir and the Cooper-pair box results in the relaxation of the qubit. We derive master equations governing the evolution of the qubit coherences and populations. We find that the kinetics of the qubit can be characterized by two time scales---quasiparticle escape time from the reservoir to the box ${\ensuremath{\Gamma}}_{\text{in}}^{\ensuremath{-}1}$ and quasiparticle relaxation time $\ensuremath{\tau}$. The former is determined by the dimensionless normal-state conductance gT{g}_{T}gT​ of the Josephson junction and one-electron level spacing ${\ensuremath{\delta}}_{r}$ in the reservoir $({\ensuremath{\Gamma}}_{\text{in}}\ensuremath{\sim}{g}_{T}{\ensuremath{\delta}}_{r})$, and the latter is due to the electron-phonon interaction. We find that phase coherence is damped on the time scale of ${\ensuremath{\Gamma}}_{\text{in}}^{\ensuremath{-}1}$. The qubit energy relaxation depends on the ratio of the two characteristic times $\ensuremath{\tau}$ and ${\ensuremath{\Gamma}}_{\text{in}}^{\ensuremath{-}1}$ and also on the ratio of temperature TTT to the Josephson energy EJ{E}_{J}EJ​.
In this thesis a systematic, functional matrix field theory is developed to describe both clean and disordered s-wave and d-wave superconductors and the quantum phase transitions associated with them. The thesis can be divided into three parts. The first part includes chapters 1 to 3. In chapter one a general physical introduction is given. In chapters two and three the theory is developed and used to compute the equation of state as well as the number-density susceptibility, spin-density susceptibility, the sound attenuation coefficient, and the electrical conductivity in both clean and disordered s-wave superconductors. The second part includes chapter four. In this chapter we use the theory to describe the disorder-induced metal - superconductor quantum phase transition. The key physical idea here is that in addition to the superconducting order-parameter fluctuations, there are also additional soft fermionic fluctuations that are important at the transition. We develop a local field theory for the coupled fields describing superconducting and soft fermionic fluctuations. Using simple renormalization group and scaling ideas, we exactly determine the critical behavior at this quantum phase transition. Our theory justifies previous approaches. The third part includes chapter five. In this chapter we study the analogous quantum phase transition in disordered d-wave superconductors. This theory should be related to high TcT_cTc​ superconductors. Surprisingly, we show that in both the underdoped and overdoped regions, the coupling of superconducting fluctuations to the soft disordered fermionic fluctuations is much weaker than that in the s-wave case. The net result is that the disordered quantum phase transition in this case is a strong coupling, or described by an infinite disordered fixed point, transition and cannot be described by the perturbative RG description that works so well in the s-wave case. The transition appears to be related to the one that occurs in disordered quantum antiferromagnets.
We report on time-resolved measurements of thermodynamic fluctuations in the number of particles in a nondegenerate Fermi gas. The gas is comprised of thermal quasiparticles, confined in a superconducting Al box by large-gap Ta leads. The average number of quasiparticles is about 10(5). This number fluctuates due to quasiparticle generation and recombination. The number is measured from the tunneling current through a barrier that bisects the box. The recombination time is independently measured by single-photon excitation and agrees with the frequency dependence of the fluctuations.
A nonperturbative argument is used to derive a one-electron Hamiltonian whose eigenfunctions are in one-to-one correspondence with electron or hole quasiparticles of an N-electron system. Nonlocal exchange is included exactly, and self-energy terms due to electronic correlation are included at the level of approximation of a given N-electron wave function. When parametrized by quasiparticle occupation numbers, this one-electron Hamiltonian is the functional derivative of an exact N-electron energy functional, as in the Landau theory of interacting fermion systems. The present nonperturbative derivation extends the Landau theory to ordered or localized systems for which many-body perturbation theory is not directly applicable. Analysis of the Bardeen-Cooper-Schrieffer (BCS) reduced Hamiltonian for superconductors leads to a temperature-dependent energy gap and a transition temperature in good agreement with the BCS theory, in a formalism that conserves the number of electrons.