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Physica Scripta

Virtual temperatures, passivity, and performance bounds on quantum thermal machines

Sachin Sonkar, Ramandeep S. Johal

Published Aug 25, 2026• 0 citations
Publisher

Abstract

Abstract We analyze the role of virtual temperatures in passive quantum states using majorization theory. A weighted mean virtual temperature is defined and used to compare the passive states resulting from isoenergetic and isoentropic transformations. We apply the majorization based criterion for the direction of heat flow in a quantum Otto engine, and derive a spectrum-dependent upper bound on the Otto efficiency. The upper bound which can also be related to the min-max virtual temperatures of the passive states, is illustrated for an interacting spin working medium. Thus, virtual temperatures serve as a unifying framework connecting passivity, majorization, and the optimal performance of quantum thermal machines.

DOI
10.1088/1402-4896/ae9e98

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Abstract We analyze the role of virtual temperatures in passive quantum states using majorization theory. A weighted mean virtual temperature is defined and used to compare the passive states resulting from isoenergetic and isoentropic transformations. We apply the majorization based criterion for the direction of heat flow in a quantum Otto engine, and derive a spectrum-dependent upper bound on the Otto efficiency. The upper bound which can also be related to the min-max virtual temperatures of the passive states, is illustrated for an interacting spin working medium. Thus, virtual temperatures serve as a unifying framework connecting passivity, majorization, and the optimal performance of quantum thermal machines.
We analyze the role of virtual temperatures for passive quantum states through the lens of majorization theory. A mean temperature over the virtual temperatures of adjacent energy levels is defined to compare the passive states of the system resulting from isoenergetic and isoentropic transformations. The role of the minimum and the maximum (min-max) values of the virtual temperatures in determining the direction of heat flow between the system and the environment is argued based on majorization relations. We characterize the intermediate passive states in a quantum Otto engine using these virtual temperatures and derive an upper bound for the Otto efficiency that can be expressed in terms of the min-max virtual temperatures of the working medium. An explicit example of the coupled-spins system is worked out. Moreover, virtual temperatures serve to draw interesting parallels between the quantum thermodynamic processes and their classical counterparts. Thus, virtual temperature emerges as a key operational quantity linking passivity and majorization to the optimal performance of quantum thermal machines.
Quantum thermal machines make use of non-classical thermodynamic resources, one of which include interactions between elements of the quantum working medium. In this paper, we examine the performance of a quasi-static quantum Otto engine based on two spins of arbitrary magnitudes subject to an external magnetic field and coupled via an isotropic Heisenberg exchange interaction. It has been shown earlier that the said interaction provides an enhancement of cycle efficiency, with an upper bound that is tighter than the Carnot efficiency. However, the necessary conditions governing engine performance and the relevant upper bound for efficiency are unknown for the general case of arbitrary spin magnitudes. By analyzing extreme case scenarios, we formulate heuristics to infer the necessary conditions for an engine with uncoupled as well as coupled spin model. These conditions lead us to a connection between performance of quantum heat engines and the notion of majorization. Furthermore, the study of complete Otto cycles inherent in the average cycle also yields interesting insights into the average performance.
The concept of majorization is explored as a tool to characterize the performance of a quantum Otto engine in the quasistatic regime. For a working substance in the form of a single spin of arbitrary magnitude, majorization yields a necessary and sufficient condition for the operation of the Otto engine, provided the canonical distribution of the working medium at the hot reservoir is majorized by its canonical distribution at the cold reservoir. We extend our analysis for two scenarios: a three-level atom and a bipartite system consisting of spin 1/2 interacting with an arbitrary spin via an isotropic Heisenberg exchange interaction. For both these cases, we find that while a majorization condition implies positive work extraction, it only yields sufficient conditions for the engine operation. Finally, we study the local thermodynamics of spins in the case of the bipartite system and infer an upper bound on the quantum Otto efficiency using the majorization relation.
Passive states, i.e., those states from which no work can be extracted via unitary operations, play an important role in the foundations and applications of quantum thermodynamics. They generalize the familiar Gibbs thermal states, which are the sole passive states being stable under tensor product. Here, we introduce a partial order on the set of passive states that captures the idea of a passive state being virtually cooler than another one. This partial order, which we build by defining the notion of relative passivity, offers a fine-grained comparison between passive states based on virtual temperatures (just like thermal states are compared based on their temperatures). We then characterize the quantum operations that are closed on the set of virtually cooler states with respect to some fixed input and output passive states. Viewing the activity, i.e., nonpassivity, of a state as a resource, our main result is then a necessary and sufficient condition on the transformation of a class of pure active states under these relative passivity-preserving operations. This condition gives a quantum thermodynamical meaning to the majorization relation on the set of nonincreasing vectors due to Hoffman. The maximum extractable work under relative passivity-preserving operations is then shown to be equal to the ergotropy of these pure active states. Finally, we are able to fully characterize passivity-preserving operations in the simpler case of qubit systems, and hence to derive a state interconversion condition under passivity-preserving qubit operations. The prospect of this work is a general resource-theoretical framework for the extractable work via quantum operations going beyond thermal operations.
The performance of a quantum Otto engine is analyzed with regard to the constraints on the modulation of energy gaps relative to the changes in probability distributions at the two given heat reservoirs. We performed a detailed analysis with a generic three-level system (3LS), which serves as a non-trivial working medium with two energy gaps. A three-level Otto engine becomes feasible if at least one energy gap shrinks during the first quantum adiabatic stage. The operating regimes are derived for each allowed energy gap modulation, and majorization is observed to play a crucial role in determining the engine operation. This results in an enhanced Otto efficiency when the probability distributions fulfill the majorization condition. Finally, we show that our formalism applies to a swap engine based on a working medium composed of two 3LSs.
We investigate a finite-time quantum Otto engine within the framework of gauge-invariant quantum thermodynamics, using the Lipkin-Meshkov-Glick model as the working medium. In this formulation, thermodynamic quantities are defined on equivalence classes of thermodynamically indistinguishable states, leading naturally to gauge-invariant notions of work, heat, entropy, and efficiency. We derive explicit expressions for these quantities and show that the usual work performed during the unitary strokes decomposes into an invariant contribution, associated with changes in the instantaneous energy spectrum and populations, and a coherent contribution arising from finite-time quantum coherences. This decomposition induces the corresponding splittings of engine efficiency and entropy production, providing a geometric interpretation of finite-time irreversibility and clarifying the role of coherence in work extraction. By analyzing the cycle's dependence on driving speed and system size, we identify the engine's operating region and investigate the influence of criticality. We show that crossing the critical region substantially reduces the parameter space in which the cycle operates as a heat engine. At the same time, whenever the engine condition remains satisfied, the discrepancy between the conventional and gauge-invariant descriptions becomes strongly suppressed, indicating that the gauge-invariant sector predominantly carries the extracted work. These results establish a direct connection between gauge-invariant thermodynamics, finite-time irreversibility, and work extraction in many-body quantum thermal machines.