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Entropy

Operational Constraints in Quantum Otto Engines: Energy-Gap Modulation and Majorization

Sachin Sonkar, Ramandeep S. Johal

Published Jun 12, 2025• 0 citations
Publisher

Abstract

The performance of a quantum Otto engine is analyzed with regard to the constraints on the modulation of energy gaps relative to the changes in probability distributions at the two given heat reservoirs. We performed a detailed analysis with a generic three-level system (3LS), which serves as a non-trivial working medium with two energy gaps. A three-level Otto engine becomes feasible if at least one energy gap shrinks during the first quantum adiabatic stage. The operating regimes are derived for each allowed energy gap modulation, and majorization is observed to play a crucial role in determining the engine operation. This results in an enhanced Otto efficiency when the probability distributions fulfill the majorization condition. Finally, we show that our formalism applies to a swap engine based on a working medium composed of two 3LSs.

DOI
10.3390/e27060625

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The performance of a quantum Otto engine is analyzed with regard to the constraints on the modulation of energy gaps relative to the changes in probability distributions at the two given heat reservoirs. We performed a detailed analysis with a generic three-level system (3LS), which serves as a non-trivial working medium with two energy gaps. A three-level Otto engine becomes feasible if at least one energy gap shrinks during the first quantum adiabatic stage. The operating regimes are derived for each allowed energy gap modulation, and majorization is observed to play a crucial role in determining the engine operation. This results in an enhanced Otto efficiency when the probability distributions fulfill the majorization condition. Finally, we show that our formalism applies to a swap engine based on a working medium composed of two 3LSs.
A three-level quantum system having two energy gaps presents a nontrivial working medium for a quantum heat engine. Our focus lies in understanding the constraints on the ability to modulate these gaps relative to the changes in probability distributions at the two given heat reservoirs. It is seen that an Otto engine in the quasistatic limit is feasible if at least one energy gap shrinks during the first quantum adiabatic stage. We analyze operating conditions under different variations of the gaps, revealing that a definite majorization relation between the hot and cold distributions serves as a sufficient criterion for the engine when both gaps are shrinking. Further, Otto efficiency is enhanced in case majorization holds. On the other hand, majorization becomes a necessary condition when only one of the gaps is shrinking. In the special case where one gap remains fixed, majorization is both necessary and sufficient for engine operation. For an nnn-level system, we note that a well defined change in energy gaps aligns with the majorization relation, thus characterizing the operation of the engine.
The concept of majorization is explored as a tool to characterize the performance of a quantum Otto engine in the quasistatic regime. For a working substance in the form of a single spin of arbitrary magnitude, majorization yields a necessary and sufficient condition for the operation of the Otto engine, provided the canonical distribution of the working medium at the hot reservoir is majorized by its canonical distribution at the cold reservoir. We extend our analysis for two scenarios: a three-level atom and a bipartite system consisting of spin 1/2 interacting with an arbitrary spin via an isotropic Heisenberg exchange interaction. For both these cases, we find that while a majorization condition implies positive work extraction, it only yields sufficient conditions for the engine operation. Finally, we study the local thermodynamics of spins in the case of the bipartite system and infer an upper bound on the quantum Otto efficiency using the majorization relation.
Quantum thermal machines make use of non-classical thermodynamic resources, one of which include interactions between elements of the quantum working medium. In this paper, we examine the performance of a quasi-static quantum Otto engine based on two spins of arbitrary magnitudes subject to an external magnetic field and coupled via an isotropic Heisenberg exchange interaction. It has been shown earlier that the said interaction provides an enhancement of cycle efficiency, with an upper bound that is tighter than the Carnot efficiency. However, the necessary conditions governing engine performance and the relevant upper bound for efficiency are unknown for the general case of arbitrary spin magnitudes. By analyzing extreme case scenarios, we formulate heuristics to infer the necessary conditions for an engine with uncoupled as well as coupled spin model. These conditions lead us to a connection between performance of quantum heat engines and the notion of majorization. Furthermore, the study of complete Otto cycles inherent in the average cycle also yields interesting insights into the average performance.
Abstract The efficiency of a quantum heat engine is maximum when the unitary strokes of the quantum Otto cycle are adiabatic. On the other hand, this may not be always possible due to small energy gaps in the system, especially at the critical point (CP) where the gap between the ground state and the first excited state vanishes and the system gets excited. With the aim to regain this lost adiabaticity, we modify one of the unitary strokes of the Otto cycle by allowing the system to first evolve with a time dependent Hamiltonian as in the case of a usual Otto cycle, followed by an additional evolution with a different time independent Hamiltonian so that the system reaches a less excited state. This will help in increasing the magnitude of the heat absorbed from the hot bath so that the work output and efficiency of the engine can be increased. We demonstrate this method using an integrable model and a non-integrable model as the working medium and discuss the generality and limitations of this method. In the case of a two spin system, the optimal value for the time till which the system needs to be freely evolved is calculated analytically in the adiabatic limit. The results show that implementing this modified unitary stroke significantly improves the work output and efficiency of the engine, especially when it crosses the CP.
We present a detailed study of an asymmetrically driven quantum Otto engine with a time-dependent harmonic oscillator as its working medium. We obtain analytic expressions for the upper bounds on the efficiency of the engine for two different driving schemes having asymmetry in the expansion and compression work strokes. We show that the Otto cycle under consideration cannot operate as a heat engine in the low-temperature regime. Then, we show that the friction in the expansion stroke is significantly more detrimental to the performance of the engine as compared to the friction in the compression stroke. Further, by comparing the performance of the engine with sudden expansion, sudden compression, and both sudden strokes, we uncover a pattern of connections between the operational points, and we indicate the optimal operation regime for each case. Finally, we analytically characterize the complete phase diagram of the Otto cycle for both driving schemes and highlight the different operational modes of the cycle as a heat engine, refrigerator, accelerator, and heater.
Quantum heat machines, encompassing heat engines, refrigerators, heaters, and accelerators, represent the forefront of quantum thermodynamics, offering a novel paradigm for converting heat energy into useful mechanical work. Leveraging quantum mechanical principles, these machines promise superior efficiency and performance compared to classical counterparts, with potential applications in renewable energy and quantum computing. This paper investigates a quantum Otto engine operating in both ideal and finite-time scenarios, employing a two-level system interacting with a harmonic oscillator within the framework of the anisotropic quantum Rabi-Stark model (AQRSM) as the working medium. This model is notable for exhibiting both first-order and continuous quantum phase transitions. By focusing on quantum heat engines, our study reveals that these phase transitions critically modulate the efficiency and power of AQRSM-based engines, outperforming quantum engines fueled by working medium with harmonic spectrum. Additionally, we explore the impacts of quantum friction and conduct limit cycle analysis in finite-time operations, providing insights into optimizing quantum heat engines for practical implementation.