Journal of Vacuum Science & Technology B Nanotechnology and Microelectronics Materials Processing Measurement and Phenomena
Voltage-tunable Josephson junctions on germanium quantum wells with in situ aluminum contacts
J. P. Thompson, J. T. Dong, B. Langa, Chomani Gaspe, R. Card, B. Bailey, Shiva Davari, Bethany E. Matthews, Matthew J. Olszta, S. Hoffman, Thomas Hazard, Kyle Serniak, Hugh Churchill, Kasra Sardashti, Christopher J. K. Richardson
Voltage-tunable Josephson junctions (VT-JJs) are an emerging element in superconducting quantum electronics with potential to expand the functionality of conventional designs. While VT-JJs are largely compatible with wafer-scale semiconductor processing, their integration into quantum circuits remains a challenge due to unmitigated semiconductor microwave loss. Here, a deep mesa etch process, wherein the epitaxial material is removed except the VT-JJ device, will facilitate the integration of VT-JJs with low-microwave-loss circuit elements by allowing these circuit elements to be placed directly on a low-loss substrate. A germanium quantum well is grown by molecular beam epitaxy (MBE) on a float zone silicon substrate with in situ deposited aluminum contacts. This combination allows the formation of an oxide-free superconductor-semiconductor interface. The deep mesa etch process is optimized to produce a sidewall taper sufficient for continuous metal deposition from the substrate to the top of the mesa for electrostatic gate electrodes and interconnects. The fabricated Josephson junctions demonstrate gate-tunable supercurrents with a maximum critical current over 100 nA and critical-current normal-resistance product of 8.63 μV. These results demonstrate a pathway toward improved integration of voltage-tunable superconducting circuit elements with quantum electronic building blocks such as couplers and qubits.
Voltage-tunable Josephson junctions (VT-JJs) are an emerging element in superconducting quantum electronics with potential to expand the functionality of conventional designs. While VT-JJs are largely compatible with wafer-scale semiconductor processing, their integration into quantum circuits remains a challenge due to unmitigated semiconductor microwave loss. Here, a deep mesa etch process, wherein the epitaxial material is removed except the VT-JJ device, will facilitate the integration of VT-JJs with low-microwave-loss circuit elements by allowing these circuit elements to be placed directly on a low-loss substrate. A germanium quantum well is grown by molecular beam epitaxy (MBE) on a float zone silicon substrate with in situ deposited aluminum contacts. This combination allows the formation of an oxide-free superconductor-semiconductor interface. The deep mesa etch process is optimized to produce a sidewall taper sufficient for continuous metal deposition from the substrate to the top of the mesa for electrostatic gate electrodes and interconnects. The fabricated Josephson junctions demonstrate gate-tunable supercurrents with a maximum critical current over 100 nA and critical-current normal-resistance product of 8.63 μV. These results demonstrate a pathway toward improved integration of voltage-tunable superconducting circuit elements with quantum electronic building blocks such as couplers and qubits.
Voltage-tunable Josephson junctions (VT-JJs) are an emerging element in superconducting quantum electronics with potential to expand the functionality of conventional designs. While VT-JJs are largely compatible with wafer-scale semiconductor processing, their integration into quantum circuits remains a challenge due to unmitigated semiconductor microwave loss. Here, a deep mesa etch process, wherein the epitaxial material is removed except the VT-JJ device, will facilitate the integration of VT-JJs with low-microwave-loss circuit elements by allowing these circuit elements to be placed directly on a low-loss substrate. A Germanium quantum well is grown by Molecular Beam Epitaxy (MBE) on a float zone silicon substrate with in-situ deposited aluminum contacts. This combination allows the formation of an oxide-free superconductor-semiconductor interface. The deep mesa etch process is optimized to produce a sidewall taper sufficient for continuous metal deposition from the substrate to the top of the mesa for electrostatic gate electrodes and interconnects. The fabricated Josephson junctions demonstrate gate-tunable supercurrents with a maximum critical current over 100 nA and critical-current normal-resistance product of 8.63μV. These results demonstrate a pathway toward improved integration of voltage-tunable superconducting circuit elements with quantum electronic building blocks such as couplers and qubits.
Superconducting qubit based on superconducting circuits consist of a superconducting capacitor and a Josephson junction with the transmon geometry is extensively used in advanced quantum processors, pursuing scalable quantum computing. The tuning of the qubit frequency of the transmon relies on magnetic flux-dependent interference between the supercurrents of two superconductor-insulator-superconductor (S-I-S) Josephson junctions in a superconducting loop. Josephson junction based on superconductor-semiconductor-superconductor (S-Sm-S) materials opens up a possibility to the gate-tunable transmon, referred to as the "gatemon", in which the qubit frequency can be tuned by electrostatic mean. Recent realizations of gatemons on III-V material platforms show impressive development on the alternative to the transmon, yet still leave a big question on the scalability. The silicon-germanium (SiGe) heterostructure is one of the potential platforms to host hybrid devices due to its high hole mobility and the low Schottky barrier at the Ge-metal interface. Additionally, the compatibility with the silicon-based semiconductor industry is a capable advantage for the scaling-up qubit platform.In this thesis, we develop gatemons based on the Al-Ge-Al Josephson junction in the SiGe heterostructure. Firstly, the robust fabrication recipe, found on a top-down approach, for Josephson Field Effect Transistors (JoFETs) is established. We perform measurements exhaustively on the JoFETs to study their properties as a function of the gate voltage, temperature, and magnetic field. The devices show gate-tunability of the critical current and the normal state resistance . The devices are estimated to have a high-transparency superconductor-semiconductor interface, as demonstrated by the high product on the SiGe heterostructure. In the finite-voltage regime, the features corresponded to multiple Andreev reflections (MARs) are observed. Then, we fabricate and characterize niobium nitride (NbN) superconducting resonators on SiGe heterostructure. We measure the resonators in the transmission mode and extract the resonant frequency , internal quality factor, and coupling quality factor from the transmission coefficient. Following that, we develop the fabrication process to integrate Al-Ge-Al junctions shunted with capacitors, or, in other words, gatemon, into the resonator scheme and perform the fabrication according to the design. We demonstrate the anticrossing feature in one of the fabricated gatemons. The resonant frequency of the gatemon is mapped using the two-tone spectroscopy technique and is found to be gate-tunable. The qubit has large spectral linewidth, implying a low coherence time. Additionally, we conduct the current-phase relationship (CPR) measurement on the junctions in the Superconducting QUantum Interference Device (SQUID) geometry. We can demonstrate that the junctions pose non-sinusoidal CPR. Further, the integer and half-integer Shapiro steps are observed in the current-voltage characteristic curves of irradiated junctions. This indicates that our junctions have the element, which can open up another possibility toward protected qubits.
Superconducting qubit based on superconducting circuits consist of a superconducting capacitor and a Josephson junction with the transmon geometry is extensively used in advanced quantum processors, pursuing scalable quantum computing. The tuning of the qubit frequency of the transmon relies on magnetic flux dependent interference between the supercurrents of two superconductor-insulator superconductor(S-I-S) Josephson junctions in a superconducting loop. Josephson junction based on superconductor-semiconductor-superconductor (S-Sm-S) materialsopens up a possibility to the gate-tunable transmon, referred to as the "gatemon", in which the qubit frequency can be tuned by electrostatic mean. Recent realizations of gatemons on III-V material platforms show impressive development on the alternative to the transmon, yet still leave a big question on the scalability. The silicon-germanium (SiGe) heterostructure is one of the potential platforms to host hybrid devices due to its high hole mobility and the low Schottky barrier at the Ge-metal interface. Additionally, the compatibility with the silicon-based semiconductor industry is a capable advantage for the scaling-up qubit platform.In this thesis, we develop gatemons based on the Al-Ge-Al Josephson junction in the SiGe heterostructure. Firstly, the robust fabrication recipe, found on a top down approach, for Josephson Field Effect Transistors (JoFETs) is established. We perform measurements exhaustively on the JoFETs to study their properties as a function of the gate voltage, temperature, and magnetic field. The devices show gate-tunability of the critical current (IC) and the normal state resistance (RN). The devices are estimated to have a high-transparency superconductor/semiconductor interface, as demonstrated by the high ICRN product on the SiGe heterostructure. In the finite-voltage regime, the features corresponded to multiple Andreev reflections (MARs) are observed. Then, we fabricate and characterize niobium nitride (NbN) superconducting resonators on SiGe heterostructure. We measure the resonators in the transmission mode and extract the resonant frequency (fr), internal quality factor (Qi), and coupling quality factor (Qc) from the transmission coefficient (S21). Following that, we develop the fabrication process to integrate Al-Ge-Al junctions shunted with capacitors, or, in other words,gatemon, into the resonator scheme and perform the fabrication according to the design. We demonstrate the anticrossing feature in one of the fabricated gatemons. The resonant frequency of the gatemon is mapped using the two-tone spectroscopy technique and is found to be gate-tunable. The qubit has large spectral linewidth, implying a low coherence time. Additionally, we conduct the current-phase relationship (CPR) measurement on the junctions in the Superconducting QUantum Interference Device (SQUID) geometry. We can demonstrate that the junctions pose non-sinusoidal CPR. Further, the integer and half-integer Shapiro steps are observed in the current-voltage characteristic curves of irradiated junctions. This indicates that our junctions have the cos 2φ element, which can open up another possibility toward protected qubits.
Ge/SiGe heterostructures represent a promising platform for hosting various quantum devices such as hole spin qubits and Andreev spin qubits. However, the compatibility of such heterostructures with high-quality-factor microwave superconducting cavities remains a challenge due to defects in the material stack. In this work, we present an approach to enhance the coherence of cavity modes on a reverse-graded Ge/SiGe heterostructure, which consists of etching the full ∼1.6μm-thick Ge/SiGe stack down to its starting high-resistivity Si substrate, in order to pattern superconducting cavities directly on it. We engineer the mesa step to be tapered, so that it can be easily climbed by the superconducting cavities to reach the quantum devices potentially hosted in the Ge quantum well. Using this approach, we observe internal quality factors of Qi≈10000−20000 for high-impedance frequency-tunable Josephson junction array resonators, limited by the junctions' fabrication, and Qi≈100000 for 50Ω coplanar waveguide Nb lift-off resonators. These Qi are preserved despite the overlap with the mesa structure in the climbing region, and are comparable to the ones obtained for identical resonators fabricated on a high-resistivity Si wafer reference. Thereby, this work paves a practical path toward superconductor-semiconductor hybrid devices, immediately applicable to emerging technologies on planar Ge.
Conventional superconducting quantum electronics rely on well-established Josephson junctions made of Al/AlOx where the weak link AlOx is amorphous and is believed to host two-level systems that limit coherence. Crystalline Josephson junctions exhibit atomically ordered interface quality but remain constrained by complex fabrication and intrinsic asymmetry of epitaxial growth. Here, we demonstrate a fully epitaxial approach based on superconductivity in gallium-doped germanium, enabling the realization of Josephson junctions entirely grown in situ by molecular beam epitaxy. These devices feature atomically sharp interfaces and crystalline weak links, resulting in strong Josephson coupling in the ultra-short regime. We observe an unconventional enhancement of the switching current under applied magnetic field, which we attribute to quasiparticle-assisted thermalization processes from the Al contacts. This platform combines structural coherence, fabrication simplicity, and scalability, offering a promising route toward low-disorder, CMOS-compatible superconducting qubits in a merged element transmon architecture.
The performance and coherence of superconducting quantum systems are fundamentally tied to the quality of the materials from which they are built. In superconducting transmon qubits, many loss mechanisms and sources of decoherence originate from material imperfections or unwanted oxide formation. Likewise, semiconductor–superconductor hybrid systems depend on high-quality interfaces to ensure strong coupling between electronic states in the two materials. In such hybrid devices, the accessible operating regime is often dictated by the intrinsic material properties of either the semiconductor or the superconductor. Advancing quantum device performance therefore requires exploring new material systems and optimizing their physical characteristics. In this thesis, we present the development of several superconducting material platforms for quantum technologies, including superconducting qubits, single-photon detectors, and semiconductor superconductor hybrid devices. We focus on the growth and characterization of superconducting films and heterostructures, and we establish clear connections between their material properties and the resulting device performance. First, we will present a novel semiconductor-superconductor hybrid material based on in-situ deposited epitaxial layers of Nb and Al on a shallow InAs quantum well. In this structure, the Al interlayer provides an epitaxial connection between an in-situ magnetron sputtered Nb or NbTi thin film and a shallow InAs two dimensional electron gas. This metal-to-metal epitaxy is achieved by optimization of the material stack and results in an induced superconducting gap of approximately 1 meV, determined from transport measurements of superconductor semiconductor Josephson junctions. This induced gap is approximately five times larger than the values reported for Al-based hybrid materials and indicates the formation of highly-transparent interfaces that are required in high-quality hybrid material platforms. Then, we discuss a different approach in the next chapter where we develop a hybrid material based on a molecular beam epitaxy grown InAsSb surface quantum well with an in-situ deposited Nb layer directly on top of the quantum well. Relative to conventional Al-InAs based systems, the InAsSb surface quantum well offers a lower effective mass and stronger spin-orbit interaction, while the Nb layer has a higher critical temperature and a larger critical magnetic field. The in-situ deposition of the Nb layer directly on top of the quantum well results in a high-quality interface that enables strong coupling to the InAsSb quantum well. Transport measurements on Josephson junctions reveal an induced superconducting gap of 1.3 meV and a critical current density of 3.75 × 10³A/cm². Furthermore, a planar asymmetric SQUID is realized, exhibiting gate-tunable superimposed oscillations originating from both the individual Josephson junction and the full SQUID loop. The large induced superconducting gap combined with strong spin-orbit interaction position this material as an attractive platform for experiments exploring gate-tunable superconductivity and topological superconducting devices. In the next chapter, we will focus on establishing a link between Nb film crystal properties and their performance in superconducting circuits. In this study, we investigate the microwave properties of niobium resonators with different crystalline properties and related surface topographies. We analyze a series of magnetron sputtered films in which the Nb crystal orientation and surface topography are changed by varying the substrate temperatures between room temperature and 975 K. The lowest-loss resonators that we measure have quality factors of over 10⁶ at single-photon powers, among the best ever recorded using the Nb on sapphire platform. We observe the highest quality factors in films grown at an intermediate temperature regime of the growth series (550 K) where the films display both preferential ordering of the crystal domains and low surface roughness. Furthermore, we analyze the temperature-dependent behavior of our resonators to learn about how the quasi-particle density in the Nb film is affected by the niobium crystal structure and the presence of grain boundaries. Then, we explore yet a different material platform by attempting to realize onchip NbTiN single photon detectors on LiNbO₃, an emerging photonic platform with high potential for scalable quantum information processing. We use DC reactive magnetron sputtering to grow high-quality NbTiN thin films and investigate the impact of substrate temperature during NbTiN growth. We achieve four nm thick superconducting films with a critical temperature (𝑇𝑐) of 12.3 K grown at a substrate temperature of 825 K. We demonstrate that the increased substrate temperature reduces the oxygen concentration in our films and improves the overall stoichiometry. In addition, we integrate these films with the LiNbO3 platform and investigate the obtained interface quality. Finally, we fabricate superconducting nanowire single photon detectors from the NbTiN film on LiNbO₃ and characterize the detector performance. Lastly, we report a gate-tunable Josephson diode effect in hybrid nanowire junctions consisting of a spin-orbit-coupled semiconductor core coated with epitaxial ferromagnetic insulator and superconductor shells. The wires display a hysteretic superconducting window as a function of axial magnetic field. In the superconducting regime, the devices exhibit nonreciprocal current transport, with the diode efficiency showing a strong dependence on back-gate voltage. The effect persists in a remanent magnetization state following a controlled demagnetization procedure, establishing zero-field operation. The combination of results presented in this thesis stress the importance of a material-focused approach in advancing the performance of quantum hardware. The novel hybrid material platforms developed in this thesis expand the operating regime of devices, which could enable future experiments involving gate-tunable superconductivity or topological properties. Similarly, we demonstrate that optimizing superconductor crystal structure benefits quantum devices, such as single-photon detectors and superconducting resonators.