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Quantum tunneling Mpemba effect

Hisao Hayakawa, Satoshi Takada

Published Jan 1, 2026• 0 citations
Publisher
DOI
10.2139/ssrn.7083537

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The Mpemba effect refers to faster relaxation of states that are initially farther from equilibrium, yet its characterization is often tied to a chosen distance or resource measure. We introduce resource-Markovianity, an extended concept of quantum Markovianity to quantum resource theories, and formulate the resource Mpemba effect operationally as the breaking of resource-Markovianity by a relaxation operation. This yields a measure-independent operational characterization of resource Mpemba effects in general resource theories, together with quantitative characterizations based on resource-non-Markovianity measures. We illustrate the framework with the Mpemba effect for distinguishability of states, due to its relation to quantum Markovianity, and with the thermomajorization Mpemba effect from an operational perspective. These results reveal a deep interplay between quantum resources, non-Markovianity, and the Mpemba effect.
We investigate a quantum tunneling Mpemba effect for a particle in a continuous one-dimensional symmetric double-well potential subject to irreversible boundary loss. The dissipation is described by a complex absorbing potential (CAP) and the corresponding conditional no-jump evolution. Using a biorthogonal spectral representation, we derive the exact non-Hermitian decomposition of the subnormalized density matrix and analyze the corresponding relaxation dynamics. We show that the off-diagonal coefficients exhibit a parity selection rule, leaving same-parity interference terms in general. To isolate the interplay between thermal spectral preparation and mode-dependent decay rates, we introduce a diagonal spectral relaxation measure S(t,Ti)S(t,T_i)S(t,Ti​). For a quartic double well, numerical calculations reveal finite-time crossings of S(t,Ti)S(t,T_i)S(t,Ti​) prepared at different initial temperatures, as well as a non-monotonic temperature dependence of selected diagonal spectral weights. These features are explained by the enhanced thermal population of spatially extended, rapidly leaking excited states. In contrast, the trace distance of the normalized conditional state to the asymptotic quasi-stationary state exhibits no crossing, demonstrating that the anomalous ordering is specifically a spectral Mpemba effect rather than a universal acceleration of the complete conditional state. Our continuous-space formulation provides a real-space perspective on anomalous quantum relaxation without invoking universal nodal or topological theorems.
The Mpemba effect (MpE), where a far-from-equilibrium state of a system relaxes faster compared to a state closer to it, is a well-known counterintuitive phenomenon in classical and quantum systems. Various system-specific theories have been proposed to explain this anomalous behavior in driven systems, though the fundamental mechanism of MpE in undriven systems, where MpE was first observed, remains unresolved. This paper provides a generic model of MpE for a quantum spin-1/21/21/2 system following Markovian relaxation dynamics, regardless of system structure or environment. The key lies in the overlap of initial states with the fast relaxation mode; here, the constituents create a fast decay mode via interaction through the shared environment to show MpE, indicating that MpE happens due to the collective behavior of the system. I also show that a system with anisotropic relaxation naturally exhibits MpE, even without a shared environment among the particles.