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arXiv:2502.08087 · Nature Reviews Physics

The quantum Mpemba effects

Filiberto Ares, Pasquale Calabrese, Sara Murciano

Published Jul 3, 2025• 71 citations
arXivHTMLPDF
DOI
10.1038/s42254-025-00838-0

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Quantum Mpemba effects from symmetry perspectives

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Abstract Non-equilibrium dynamics have become a central research focus, exemplified by the counterintuitive Mpemba effect where initially hotter systems can cool faster than colder ones. Studied extensively in both classical and quantum regimes, this phenomenon reveals diverse and complex behaviors across different systems. This review provides a concise overview of the quantum Mpemba effect (QME), specifically emphasizing its connection to symmetry breaking and restoration in closed quantum many-body systems. We begin by outlining the classical Mpemba effect and its quantum counterparts, summarizing key findings. Subsequently, we introduce entanglement asymmetry and charge variance as key metrics for probing the QME from symmetry perspectives. Leveraging these tools, we analyze the early- and late-time dynamics of these quantities under Hamiltonian evolution and random unitary circuits. We conclude by discussing significant challenges and promising avenues for future research.

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The quantum Mpemba effect (QME) describes the counterintuitive phenomenon in which a system farther from equilibrium reaches steady state faster than one closer to equilibrium. However, ambiguity in defining a suitable distance measure between quantum states has led to varied interpretations across different contexts. Here we propose the intrinsic quantum Mpemba effect (IQME), defined using the trajectory length traced by the quantum state as a more appropriate measure of distance--distinct from previous trajectory-independent metrics. By treating quantum states as points in a Riemannian space defined by statistical distance, the trajectory length emerges as a more natural and accurate characterization of the counterintuitive dynamics, drawing an analogy to the classical Brachistochrone problem. We demonstrate the existence of IQME in Markovian systems and extend its definition to quantum circuits, thereby establishing a unified framework applicable to both open and closed systems. Notably, we observe an IQME in a U(1)U(1)U(1)-symmetric circuit, offering new insights into the rates of quantum thermalization for different initial states. This work deepens our understanding of quantum state evolution and lays the foundation for accurately capturing novel quantum dynamical behaviour.
The Mpemba effect, where a system initially farther from equilibrium relaxes faster than one closer to equilibrium, has been extensively studied in classical systems and recently explored in quantum settings. While previous studies of the quantum Mpemba effect (QME) have largely focused on isolated systems with global symmetries, we argue that the QME is ubiquitous in generic, nonintegrable many-body systems lacking such symmetries, including U(1) charge conservation, spatial symmetries, and even energy conservation. Using paradigmatic models such as the quantum Ising model with transverse and longitudinal fields, we show that the QME can be understood through the energy density of initial states and their inverse participation ratio in the energy eigenbasis. Our findings provide a unified framework for the QME, linking it with classical thermal relaxation.
In recent years, the quantum Mpemba effect (QME) which occurs when an out-of-equilibrium system reaches equilibrium faster than another that is closer to equilibrium has attracted significant attention from the scientific community as an intriguing and counterintuitive phenomenon. It generalizes its classical counterpart, extending the concept beyond thermal equilibration. This paper approaches the QME for Markovian open quantum systems from different perspectives. Firstly, we propose a physical mechanism based on decoherence-free subspaces. Secondly, we show that a macroscopic enhancement of the decay rate that scales linearly with system size can be obtained, leading to an extreme version of the phenomenon on Markovian open quantum systems. Thirdly, we study the Mpemba effect through the unravelings of Davies maps, revealing subtleties in the figures of merit which are chosen for obtaining the QME. Lastly, we propose a microscopic model for a better understanding of thermal bath dynamics in this context.
Abstract Non-equilibrium dynamics have become a central research focus, exemplified by the counterintuitive Mpemba effect where initially hotter systems can cool faster than colder ones. Studied extensively in both classical and quantum regimes, this phenomenon reveals diverse and complex behaviors across different systems. This review provides a concise overview of the quantum Mpemba effect (QME), specifically emphasizing its connection to symmetry breaking and restoration in closed quantum many-body systems. We begin by outlining the classical Mpemba effect and its quantum counterparts, summarizing key findings. Subsequently, we introduce entanglement asymmetry and charge variance as key metrics for probing the QME from symmetry perspectives. Leveraging these tools, we analyze the early- and late-time dynamics of these quantities under Hamiltonian evolution and random unitary circuits. We conclude by discussing significant challenges and promising avenues for future research.