Recent technological advances have allowed the construction of many-body quantum systems that operate below the thermodynamic limit. This has given rise to the field of quantum thermodynamics (QTD), which describes heat, work, and entropy while accounting for quantum effects. Within the framework of QTD, numerous theoretical and experimental quantum thermal machines (QTMs) have been proposed, aiming to exploit quantum effects as a resource. Hence, understanding the relationship between quantum effects and thermodynamic properties is essential for creating efficient QTMs. We explore the use of Nth-root controlled-not gates (NRCGs) in QTD, modelling our system as multiple QTMs. These gates allow for a fractional application of two-qubit operations, facilitating access to intermediary states inaccessible by full controlled-not (CNOT) gates. The system presented is a closed, out-of-equilibrium multi-qubit quantum system in which we employ NRCGs in three distinct protocols, comparing them using regime-specific performance measures. First, we consider a quantum battery, where we optimise initial parameters to maximise performance measures related to ergotropy and charging potential. Our results show that, across all protocols considered, initial quantum coherence in a single qubit improves the battery’s performance. Moreover, some NRCG protocols demonstrate better performance than CNOTs. We then characterise our system as a quantum heat engine, where initial quantum coherence increases extractable work which is achieved at high efficiencies. Furthermore, we uncover a strong linear correlation between work production and many-body correlations. Finally, we demonstrate the system can operate as different thermal machines without changes to protocol design or system size, with regime selection dictated by the initialisation parameters of a single qubit. Two uniquely interesting regimes are accessed: a work producing refrigerator and reverse flow heat engine, both of which produce work and provide cooling simultaneously. These regimes could reduce the energetic cost of cooling in quantum computer architecture.
Recent technological advances have allowed the construction of many-body quantum systems that operate below the thermodynamic limit. This has given rise to the field of quantum thermodynamics (QTD), which describes heat, work, and entropy while accounting for quantum effects. Within the framework of QTD, numerous theoretical and experimental quantum thermal machines (QTMs) have been proposed, aiming to exploit quantum effects as a resource. Hence, understanding the relationship between quantum effects and thermodynamic properties is essential for creating efficient QTMs. We explore the use of Nth-root controlled-not gates (NRCGs) in QTD, modelling our system as multiple QTMs. These gates allow for a fractional application of two-qubit operations, facilitating access to intermediary states inaccessible by full controlled-not (CNOT) gates. The system presented is a closed, out-of-equilibrium multi-qubit quantum system in which we employ NRCGs in three distinct protocols, comparing them using regime-specific performance measures. First, we consider a quantum battery, where we optimise initial parameters to maximise performance measures related to ergotropy and charging potential. Our results show that, across all protocols considered, initial quantum coherence in a single qubit improves the battery’s performance. Moreover, some NRCG protocols demonstrate better performance than CNOTs. We then characterise our system as a quantum heat engine, where initial quantum coherence increases extractable work which is achieved at high efficiencies. Furthermore, we uncover a strong linear correlation between work production and many-body correlations. Finally, we demonstrate the system can operate as different thermal machines without changes to protocol design or system size, with regime selection dictated by the initialisation parameters of a single qubit. Two uniquely interesting regimes are accessed: a work producing refrigerator and reverse flow heat engine, both of which produce work and provide cooling simultaneously. These regimes could reduce the energetic cost of cooling in quantum computer architecture.
Nth-root gates allow for a paced application of two-qubit operations. We apply them in quantum thermodynamic protocols for operating a quantum heat engine. A set of circuits for two and three qubits is compared by considering maximum work production and related efficiency. Our results show that for all circuits considered and most regions of initial parameter space, quantum coherence of one of the qubits strongly increases the maximum work production and improves the system's performance as a quantum heat engine. In such circuits, coherence is initially imprinted into one of the qubits, improving the overall maximum extractable work. We focus here on the efficiency of such work extraction, assuming the initialisation of the qubits is a free resource. For the novel protocol that employs fractional control gates, work is generated with 84% up to 100% efficiency. Further, we uncover a strong linear correlation between work production and many-body correlations in the working medium generated by these gates.
We explore the use of fractional controlled-not gates in quantum thermodynamics. The Nth-root gate allows for a paced application of two-qubit operations. We apply it in quantum thermodynamic protocols for charging a quantum battery. Circuits for three (and two) qubits are analysed by considering the generated ergotropy and other measures of performance. We also perform an optimisation of initial system parameters, e.g.,the initial quantum coherence of one of the qubits strongly affects the efficiency of protocols and the system's performance as a battery. Finally, we briefly discuss the feasibility for an experimental realization.
This paper explores quantum heat engines based on qubit and qutrit working media interacting with thermal environments through generalized amplitude damping (GAD) channels. We investigate how quantum channels can be employed to model heat absorption, dissipation, and work extraction in open quantum thermal machines, and derive the conditions required for positive work extraction. The effects of quantum correlations, emission probability, population redistribution, and system--environment interactions on the thermodynamic performance of the engine are systematically analyzed across different operational regimes. In addition, we examine the ergotropy of qubit and qutrit systems under dissipative dynamics to understand how environmental effects influence the maximum extractable work. Our results demonstrate that multilevel quantum systems exhibit enhanced work extraction capability and improved robustness against decoherence compared to two-level systems, providing further insight into the role of dissipative dynamics and quantum resources in realistic quantum thermodynamic devices.
Although the idea of combining thermodynamics with quantum mechanics is more than a century old, quantum thermodynamics has seen significant development over the past few decades. Understanding work, heat, and entropy in the quantum regime has become increasingly important, particularly in light of advances in quantum technologies. This thesis investigates work processes in quantum spin chains. Quantum work processes can involve genuinely quantum features such as entanglement, coherence, and measurement back-action, which are absent in classical thermodynamic descriptions, making their characterization an area of ongoing interest in quantum thermodynamics. Focusing first on a single work step, we show that the frictional work due to finite-time driving for a non-integrable quantum spin chain can be well quantified by the diagonal entropy production. We further demonstrate that integrability breaking enhances work extraction in the adiabatic limit, while suppressing it in the non-adiabatic regime. We then study a quantum Otto cycle using the transverse-field Ising model as the working substance. We determine how different types of operation (engine, refrigerator, accelerator, heater) can emerge for different parameter regimes. We show that with infinitesimal work strokes, a thermal machine behaves either as an engine or an accelerator, and that these regimes can be characterized by equilibrium transverse magnetization. At low temperatures, these regimes are governed by low-energy excitations, while at high temperatures they follow from a free-energy expansion in inverse temperature. Frictional effects can emerge and suppress the engine performance during non-adiabatic driving. We show that these effects can be mitigated using an optimised drive protocol based on a geometric formulation of the path of the system through parameter space. Overall, this thesis provides a comprehensive understanding of how integrability, coherence, finite-time driving, and non-adiabatic transitions govern work extraction and thermal machine operation in quantum spin chains, and paves the way for understanding these processes in other quantum many-body systems.
Quantum thermodynamics (QT) is an emerging field of research that aims to investigate how the laws of thermodynamics and quantum mechanics merge together in small quantum systems.With advances at the necessary technology to control and measure those small physical systems this field has acquired even more importance, not only in the sense that it can be tested, which is a good thing for basic research, but that new applications could be implemented at these scales, so a better comprehension of the limitations imposed by quantum thermodynamics turns out to be of crucial importance for these goals, which forces theoreticians to produce experimentally relevant versions of these new concepts.Another important aspect present at those systems is that part of them work in a regime where its constituents are described by non-thermal states, and in particular non-thermal steady states, which brings to light a different thermodynamic description, usually called steady-state thermodynamics, therefore one of the goals that we are willing to achieve with this thesis is to give an introduction to QT of systems out-of-equilibrium.One of the related subtopics that physicists deal with in QT and the one that we will be focusing on this work are the use of non-thermal stationary states to build heat engines in the quantum domain, and the analyses of the features that this new regime could possibly allow, like the use of quantum resources as a way to overcome classical limitations imposed on its performance, like to attain efficiencies higher than Carnot's or operate in certain regimes unattainable using only classical resources.Therefore, in order to clarify the underlying physics of those systems in a non-thermal regime, any experimentally well suited content is more than welcome.So keeping that in mind we devised an experimentally relevant thermodynamic cycle for a transmon qubit WS interacting with a non-thermal environment composed by two subsystems, an externally excited cavity and a classical heat bath with temperature T. The WS undergoes a non-conventional cycle (different from Otto, Carnot, etc.) through a succession of non-thermal stationary states obtained by slowly varying its bare frequency and the amplitude of the field applied on the cavity.The efficiency of this engine obtains a maximum value up to 47% in the regime of operation used.We also wanted to look for the role played by the different types of coherences, present at the WS, on the behavior of the engine and its efficiency.By different types of coherence we mean the so called modes of coherence, whose definition is based on how they respond to symmetry transformations.We did that for the trivial case of the qubit, that only contains the modes 1 and -1, and that has shown to be extremely important for the efficiency of the machine.The same procedure was repeated for a 3-level system WS.The modes 1 and -1 was again very important, not only to the absolute value of the engine's efficiency but to the regime of operation of the machine.The additional modes, 2 and -2, had a negative impact on the efficiency, reducing its absolute value.This result appears to show some evidences that quantumness won't necessarily bring improvements to the operation of those machines.
Quantum mechanics has given us a new playground in which to experiment that boasts several unique features. In this thesis, we explore it in the context of thermodynamics: looking at what kind of thermal devices can be constructed and how quantum behaviour affects them. We consider three research strands. In the first part we formulate a selection of heat engines with two-qubit systems, utilising environments that induce quantum correlations into the system. We see that these correlations can have some effects on the work of the engine, but this effect is system dependent. Describing the dynamics of a quantum system in contact with an external environment is often achieved with a master equation. When considering systems comprised of multiple subsystems, the description becomes more complicated and some of the master equations that have been used previously produce unphysical results. In the second part of this thesis we show that if one does the proper analysis of the microscopic derivation of these master equations, then no thermodynamical inconsistencies occur. When one considers a system connected to three or more environments, a whole new set of possible thermodynamical machines becomes available. One notable case of these is the absorption refrigerator, which performs refrigeration without the need for an external work source. For the third part, we show how one can construct an absorption refrigerator using a three-qubit system with two-body interactions and describe its operation. We also show some thermal control properties of the three-qubit system.