Research of hot atomic vapor systems has a long history. Recently, much-improved technologies, such as lasers, microwaves and digital/analog control systems, have led to exciting progress in this reviving field. Due to its cryogenic-free and vacuum-free deployment potential, room-temperature and quantum-enabled sensing devices using gaseous atoms have become a popular research topic, and engineering such devices has received considerable attention. Proof-of-principle experiments have been performed demonstrating new ideas such as quantum-enhanced motion sensors, next-generation magnetometers, Rydberg enabled microwave sensors, etc. This thesis focuses on my work related to electromagnetic-field sensing using Rydberg atoms in vapor cells, where Rydberg atoms are excited and detected by electromagnetically induced transparency (EIT) spectroscopy. I first investigate the detection of strong magnetic fields ( $sim$ 1~T) in the Paschen-Back regime. The diamagnetic (quadratic) response of the Rydberg levels makes the atoms sensitive to small fluctuations in field strength on a large background. By implementing an isotope-mixed cell, we demonstrate that accurate measurement, within a relative uncertainty of $pm 0.12$ %. Many Rydberg-enabled radio frequency and microwave sensing applications require a capability of zeroing or intentional tuning of small DC electric fields inside the vapor cell. For this purpose, I explore an in-situ DC electric-field sensing and tuning method without using any bulk or thin film electrodes. I find that the photoelectric effect on the vapor cell walls (with invisible, atomic Rb aggregate layers covering the surfaces) can generate tuning fields up to 0.8~V/cm, with an inhomogeneity of about 2%. The spatial distribution of these fields can be directly monitored by quadratic Stark shifts of the Rydberg atoms. This work may inspire new approaches for DC-field control in miniaturized, metal-free atomic vapor-cell devices. Like many other quantum measurements on hot gaseous samples, short interaction time and other technical decoherence processes are the major factors which limit the precision and, in certain cases, the accuracy of the metrological results. In order to study these effects in the context of EIT, I performed an EIT experiment using a $Lambda$ -type quantum system consisting of the hyperfine ground states and the first excited electronic state of the Rb atoms contained in a buffer-gas-free thermal vapor cell without anti-relaxation coating. Technical line-broadening effects due to inhomogeneity of stray magnetic fields, laser frequency jitter, transverse beam intensity distribution, interaction time distribution, and atom-wall/impurity gas collisions are studied. Experimental results and numerical simulations are compared. These results provide crucial information and quantitative insights for vapor cell sensor design. The development of compact and multi-functional spectroscopy vapor cells is widely considered to be a critical engineering step towards manufacturing field-deployable sensors for real life applications. My R&D efforts towards fabrication of glass spectroscopy cells with integrated, highly-conductive silicon components are presented in the last part of my thesis. I explored various technical challenges and successfully developed a proof-of-principle prototype from scratch. The device allows the application of electric fields inside the cell for particle trapping and for tuning Rydberg transitions. Further, the highly-conductive silicon components enable microwave polarization filtering for microwave sensing applications, plasma-physics studies, etc. Preliminary experimental/technical data and simulations are presented. In summary, in my thesis I report on a comprehensive study of several spectroscopic and field sensing applications of Rydberg and ground-state atoms in vapor cells, as well as forays into novel methods to engineer vapor cells with embedded electrodes.Research of hot atomic vapor systems has a long history. Recently, much-improved technologies, such as lasers, microwaves and digital/analog control systems, have led to exciting progress in this reviving field. Due to its cryogenic-free and vacuum-free deployment potential, room-temperature and quantum-enabled sensing devices using gaseous atoms have become a popular research topic, and engineering such devices has received considerable attention. Proof-of-principle experiments have been performed demonstrating new ideas such as quantum-enhanced motion sensors, next-generation magnetometers, Rydberg enabled microwave sensors, etc. This thesis focuses on my work related to electromagnetic-field sensing using Rydberg atoms in vapor cells, where Rydberg atoms are excited and detected by electromagnetically induced transparency (EIT) spectroscopy. I first investigate the detection of strong magnetic fields ($sim$ 1~T) in the Paschen-Back regime. The diamagnetic (quadratic) response of the Rydberg levels makes the atoms sensitive to small fluctuations in field strength on a large background. By implementing an isotope-mixed cell, we demonstrate that accurate measurement, within a relative uncertainty of $pm 0.12$%. Many Rydberg-enabled radio frequency and microwave sensing applications require a capability of zeroing or intentional tuning of small DC electric fields inside the vapor cell. For this purpose, I explore an in-situ DC electric-field sensing and tuning method without using any bulk or thin film electrodes. I find that the photoelectric effect on the vapor cell walls (with invisible, atomic Rb aggregate layers covering the surfaces) can generate tuning fields up to 0.8~V/cm, with an inhomogeneity of about 2%. The spatial distribution of these fields can be directly monitored by quadratic Stark shifts of the Rydberg atoms. This work may inspire new approaches for DC-field control in miniaturized, metal-free atomic vapor-cell devices. Like many other quantum measurements on hot gaseous samples, short interaction time and other technical decoherence processes are the major factors which limit the precision and, in certain cases, the accuracy of the metrological results. In order to study these effects in the context of EIT, I performed an EIT experiment using a $Lambda$-type quantum system consisting of the hyperfine ground states and the first excited electronic state of the Rb atoms contained in a buffer-gas-free thermal vapor cell without anti-relaxation coating. Technical line-broadening effects due to inhomogeneity of stray magnetic fields, laser frequency jitter, transverse beam intensity distribution, interaction time distribution, and atom-wall/impurity gas collisions are studied. Experimental results and numerical simulations are compared. These results provide crucial information and quantitative insights for vapor cell sensor design. The development of compact and multi-functional spectroscopy vapor cells is widely considered to be a critical engineering step towards manufacturing field-deployable sensors for real life applications. My R&D efforts towards fabrication of glass spectroscopy cells with integrated, highly-conductive silicon components are presented in the last part of my thesis. I explored various technical challenges and successfully developed a proof-of-principle prototype from scratch. The device allows the application of electric fields inside the cell for particle trapping and for tuning Rydberg transitions. Further, the highly-conductive silicon components enable microwave polarization filtering for microwave sensing applications, plasma-physics studies, etc. Preliminary experimental/technical data and simulations are presented. In summary, in my thesis I report on a comprehensive study of several spectroscopic and field sensing applications of Rydberg and ground-state atoms in vapor cells, as well as forays into novel methods to engineer vapor cells with embedded electrodes.

Jan 1, 20211 citation

Reflection spectroscopy of an atomic vapour

Marcos Oriá, D. Blöch, Martine Chevrollier +2 more

Brazilian Journal of PhysicsJan 1, 19924 citations

Observation of Rb two-photon absorption directly excited by an erbium-fiber-laser-based optical frequency comb via spectral control

Jiutao Wu, Dong Hou, Zhengyu Qin +2 more

We present the observation of the Rb two-photon spectrum directly excited by an Er:fiber laser comb in a hot atomic vapor system. The influences of the atomic velocity distribution on direct and sequential two-photon transitions are discussed respectively and a combination of corresponding spectral control techniques is developed to eliminate the Doppler broadening background. A direct frequency comb spectroscopy is obtained with high-resolution two-photon transition lines. These techniques would benefit spectroscopy measurement in hot atomic vapor systems, and pave the way for establishing a high-stability optical frequency comb in 1.5 $\ensuremath{\mu}$m optical communication bands based on the Rb two-photon transitions.We present the observation of the Rb two-photon spectrum directly excited by an Er:fiber laser comb in a hot atomic vapor system. The influences of the atomic velocity distribution on direct and sequential two-photon transitions are discussed respectively and a combination of corresponding spectral control techniques is developed to eliminate the Doppler broadening background. A direct frequency comb spectroscopy is obtained with high-resolution two-photon transition lines. These techniques would benefit spectroscopy measurement in hot atomic vapor systems, and pave the way for establishing a high-stability optical frequency comb in 1.5 $\ensuremath{\mu}$m optical communication bands based on the Rb two-photon transitions.

arXiv:1306.2205Physical Review AApr 14, 201410 citations

sim

1~T) in the Paschen-Back regime. The diamagnetic (quadratic) response of the Rydberg levels makes the atoms sensitive to small fluctuations in field strength on a large background. By implementing an isotope-mixed cell, we demonstrate that accurate measurement, within a relative uncertainty of

pm 0.12

%. Many Rydberg-enabled radio frequency and microwave sensing applications require a capability of zeroing or intentional tuning of small DC electric fields inside the vapor cell. For this purpose, I explore an in-situ DC electric-field sensing and tuning method without using any bulk or thin film electrodes. I find that the photoelectric effect on the vapor cell walls (with invisible, atomic Rb aggregate layers covering the surfaces) can generate tuning fields up to 0.8~V/cm, with an inhomogeneity of about 2%. The spatial distribution of these fields can be directly monitored by quadratic Stark shifts of the Rydberg atoms. This work may inspire new approaches for DC-field control in miniaturized, metal-free atomic vapor-cell devices. Like many other quantum measurements on hot gaseous samples, short interaction time and other technical decoherence processes are the major factors which limit the precision and, in certain cases, the accuracy of the metrological results. In order to study these effects in the context of EIT, I performed an EIT experiment using a

Lambda

-type quantum system consisting of the hyperfine ground states and the first excited electronic state of the Rb atoms contained in a buffer-gas-free thermal vapor cell without anti-relaxation coating. Technical line-broadening effects due to inhomogeneity of stray magnetic fields, laser frequency jitter, transverse beam intensity distribution, interaction time distribution, and atom-wall/impurity gas collisions are studied. Experimental results and numerical simulations are compared. These results provide crucial information and quantitative insights for vapor cell sensor design. The development of compact and multi-functional spectroscopy vapor cells is widely considered to be a critical engineering step towards manufacturing field-deployable sensors for real life applications. My R&D efforts towards fabrication of glass spectroscopy cells with integrated, highly-conductive silicon components are presented in the last part of my thesis. I explored various technical challenges and successfully developed a proof-of-principle prototype from scratch. The device allows the application of electric fields inside the cell for particle trapping and for tuning Rydberg transitions. Further, the highly-conductive silicon components enable microwave polarization filtering for microwave sensing applications, plasma-physics studies, etc. Preliminary experimental/technical data and simulations are presented. In summary, in my thesis I report on a comprehensive study of several spectroscopic and field sensing applications of Rydberg and ground-state atoms in vapor cells, as well as forays into novel methods to engineer vapor cells with embedded electrodes.