This thesis comprises a wide range of topics. The first work revolves around an active matter system, where a bound state between two run-and-tumble probe particles is induced by a thermal medium, whose interactions with the probe are purely repulsive. The bound state is then induced by the self-trapping behavior of the active particles and the density profile of the thermal particles. There is a surprising analogy between the formation of these bound states and the formation of Cooper pairs in superconductors. The electron, as described by the Dirac equation, may be seen as obeying a master equation of precisely the same form as the master equation of the run-and-tumble particle. Taking this view literally, Cooper pairs are bound states of two run-and-tumble particles whose binding is enabled by the thermal medium in which they reside. The second chapter revolves around these zig-zag electrons which are described by this master-equation formulation of the Dirac equation. This zig-zag behavior may be visualized by the calculation of trajectories that form an extension of Bohmian trajectories. These tools of visualization are then applied to the famous Stern-Gerlach experiment. The third part of the thesis concerns superconductivity, and more specifically the Josephson effect. Josephson junctions form the cornerstone of superconducting quantum technology, providing anharmonicity to qubits and phase sensitivity to SQUIDs. The physics of Josephson junctions is very rich, with features such as Andreev bound states playing a crucial part in the understanding of the Josephson current and the current-phase relation. Yet the microscopic modeling of Josephson junctions remains challenging, and many things remain unexplained. One of the issues addressed in this thesis is the issue of current conservation in the modeling of Josephson junctions, but also in mean-field superconductivity generally. We show that ensuring current conservation has a dramatic effect on the Andreev states and on the current-phase relation, challenging assumptions which have long become standard in the literature. The final part of the thesis is concerned with superconducting qubits, and the effect of the precise shape of the CPR on qubit properties. We uncover resonances of the Andreev bound states, and show that these resonances correspond to lessened anharmonicity for transmon qubits.
This thesis comprises a wide range of topics. The first work revolves around an active matter system, where a bound state between two run-and-tumble probe particles is induced by a thermal medium, whose interactions with the probe are purely repulsive. The bound state is then induced by the self-trapping behavior of the active particles and the density profile of the thermal particles. There is a surprising analogy between the formation of these bound states and the formation of Cooper pairs in superconductors. The electron, as described by the Dirac equation, may be seen as obeying a master equation of precisely the same form as the master equation of the run-and-tumble particle. Taking this view literally, Cooper pairs are bound states of two run-and-tumble particles whose binding is enabled by the thermal medium in which they reside. The second chapter revolves around these zig-zag electrons which are described by this master-equation formulation of the Dirac equation. This zig-zag behavior may be visualized by the calculation of trajectories that form an extension of Bohmian trajectories. These tools of visualization are then applied to the famous Stern-Gerlach experiment. The third part of the thesis concerns superconductivity, and more specifically the Josephson effect. Josephson junctions form the cornerstone of superconducting quantum technology, providing anharmonicity to qubits and phase sensitivity to SQUIDs. The physics of Josephson junctions is very rich, with features such as Andreev bound states playing a crucial part in the understanding of the Josephson current and the current-phase relation. Yet the microscopic modeling of Josephson junctions remains challenging, and many things remain unexplained. One of the issues addressed in this thesis is the issue of current conservation in the modeling of Josephson junctions, but also in mean-field superconductivity generally. We show that ensuring current conservation has a dramatic effect on the Andreev states and on the current-phase relation, challenging assumptions which have long become standard in the literature. The final part of the thesis is concerned with superconducting qubits, and the effect of the precise shape of the CPR on qubit properties. We uncover resonances of the Andreev bound states, and show that these resonances correspond to lessened anharmonicity for transmon qubits.
Conventional tunnel Josephson junctions form the basic building blocks of superconducting electronics. Their operation is based on comparatively simple dynamics where the superconducting phases across the junctions is the only dynamical degree of freedom. The goal of the project on which this thesis is based, is to understand the physics and develop a consistent theoretical description of the quantum dynamics of unconventional Josephson structures: spin active junctions, junctions containing low energy quasiparticles, and junctions composed of d-wave superconductors. Spin active Josephson junctions involve the additional degree of freedom of quasiparticle spin. Here we theoretically investigate the spin-structure of the current carrying interface bound states - Andreev Bound States (ABS), and induced ground state spin polarization of a short (shorter than the superconducting coherence length) nanowire junction containing a localized magnetic moment. We show that temporal variation of the superconducting phase difference and magnetic moment induce rotations in spin polarized and unpolarized subspaces respectively, which is manifested by temporal oscillation of the Josephson current.The interlevel transitions obey a selection rule that forbids manipulations in a certain region ofexternal parameters and results from specific properties of Andreev bound states in magnetic contacts where, in a certain regime of phase bias and strength of magnetic scatterer, ABS belong to different eigenstates of the combined charge and parity inversion symmetry operator.A general framework is developed to include low energy quasiparticle states into the dynamics of Josephson junctions. Such states exist in e.g. constriction type junctions with high transparency channels or resonant states, as well as in junctions of unconventional superconductors. The existence of such states prevent the separation of energy scales which in conventional tunnel junctions freezes out the quasiparticle degrees of freedom. We show that the resonant interaction with such low energy states rather than the Josephson potential defines the nonlinear Josephson dynamics at small amplitudes.The framework is applied to high temperature Josephson junctions, whose unconventional order parameter admits ABS with energies in the middle of the superconducting gap - Mid Gap States (MGS). In addition to the non-linear dynamics induced by the MGS, we identify a reentrance effect in the transition between thermal activation and macroscopic quantum tunneling associated with the MGS, and connect this phenomenon to experimental observations.
The research work discussed in this thesis deals with the study of superconducting Josephson qubits. Superconducting qubits are solid-state artificial atoms which are based on lithographically defined Josephson tunnel junctions properties. When sufficiently cooled, these superconducting devices exhibit quantized states of charge, flux or junction phase depending on their design parameters. This allows to observe coherent evolutions of their states. The results presented can be divided into two parts. In a first part we investigate operations of superconducting qubits based on the quantum coherence in superconducting quantum interference devices (SQUID). We explain experimental data which has been observed in a SQUID subjected to fast, large-amplitude modifications of its effective potential shape. The motivations for this work come from the fact that in the past few years there have been attempts to interpret the supposed quantum behavior of physical systems, such as Josephson devices, within a classical framework. Moreover, we analyze the possibility of generating GHZ states, namely maximally entangled states, in a quantum system made out of three Josephson qubits. In particular, we investigate the possible limitations of the GHZ state generation due to coupling to bosonic baths. In the second part of the thesis we address a particular cause of decoherence of flux qubits which has been disregarded until now: thermal gradients, which can arise due to accidental non equilibrium quasiparticle distributions. The reason for these detrimental effects is that heat currents flowing through Josephson tunnel junctions in response to a temperature gradient are periodic functions of the phase difference between the electrodes. The phase dependence of the heat current comes from Andreev reflection, namely an interplay between the quasiparticles which carry heat and the superconducting condensate which is sensitive to the superconducting phase difference. Generally speaking, the flux qubit states are characterized by different values of the phase difference through their Josephson junctions. Consequently, the phase-dependent thermal current through a device subject a temperature gradient is related to the phase-dependent qubit states. We study how the thermal currents change according to the state of the qubits hence yielding a measurement of the qubit state. This in turn leads to an impact of temperature gradient on the dynamics of the system. We show that flux qubits in the Delft qubit design can have limitations of the decoherence time to the order of microseconds as a result of this newly discovered source of decoherence. In contrast, the fluxonium qubit is found to be well protected due to its superinductance.
Opportunités de manipulation directe d'un qubit de spin d'Andreev piloté en phase The research presented in this thesis delves into a theoretical exploration of Andreev bound states (ABS) hosted in Josephson junctions with spin-orbit coupling (SOC). ABS are fermionic bound states that appear at the junction between two superconducting electrodes forming a Josephson junction. These bound states are at the core of the microscopic description of the Josephson effect and provide an explanation for the transfer of Cooper pairs from one superconducting electrode to the other. Crucially, when the superconducting phase difference between the two electrodes is non-zero, a supercurrent can flow in the junction, depending on the occupancy of the ABS. The presence of this supercurrent facilitates the coupling between a microwave resonator and a junction due to its sensibility to the electromagnetic field. This coupling then allows for the detection and manipulation of ABS.Furthermore, in the presence of SOC along with a superconducting phase bias, the spin degeneracy of ABS can be lifted. Therefore such a junction provides a unique opportunity to realize a special kind of spin qubit known as Andreev spin qubit (ASQ). The qubit operation can be performed via an AC modulation of an electrostatic gate or magnetic flux, thanks to the sensitivity of the ABS to the electric potential or the phase difference, respectively. So far, the coherent manipulation of such qubits has been realized in gate-driven experiments as well as in flux-driven experiments with the use of additional Andreev levels. However, the direct transition between the two ABS forming the ASQ has remained out of reach in flux-driven experiments. In this thesis, we investigate two distinct types of Josephson junctions with SOC with the aim of estimating the amplitude of the matrix elements of the current operator between two ABS forming an ASQ. These elements characterize the coupling strength between the qubit and an external flux drive, indicating which transitions between ABS are within reach. Our first project focuses on a superconductor-normal-superconductor junction where the normal region consists of a nanowire with Rashba SOC. As a minimal model, we consider a generic scatterer located along the nanowire. Unless this scatterer possesses additional spatial (mirror) symmetries, it is responsible for inducing spin-flip transmission probability. Using the scattering formalism, we derive the energy spectrum of ABS and assess how SOC influences the spin-splitting between opposite spin states. We then obtain analytical expressions for the matrix elements of the current operator. Notably, our study reveals that SOC allows one to have finite elements between opposite spin states. In a second project, the system we study consists of a superconductor-double quantum dots-superconductor junction. A quantum dot consists of a tiny region defined by electrostatic gates or impurities. Due to its small size, Coulomb repulsion can be significant. However, in the simplest case of a quantum dot with a single level, even in the presence of SOC in the coupling between the dot and the leads, spin degeneracy of ABS is still preserved. However, recent experiments showed that additional levels allow to lift the spin degeneracy. Here, we introduce a second quantum dot which provides an additional level and offers more control on each level. By using an effective model, we identify the minimal ingredients that are necessary to lift the spin degeneracy. Our results reveal that this splitting is achievable through spin-dependent couplings with the leads and is reduced by the Coulomb repulsion. Additionally, the presence of a finite coupling between the two dots, combined with SOC in the couplings with the leads, allows one to have finite matrix elements of the current operator between opposite spin states, which we obtain numerically. In short, we present in this thesis two platforms for the realization of phase-driven ASQ.
In this thesis we present theoretical investigations of the effects of Andreev bound states on the current transport in superconducting interferometers. We also investigate the slow dynamics of the Andreev states in a superconducting point contact, and the possible application as a quantum bit. We consider superconductor-normal metal-superconductor (SNS) and normal metalsuperconductor (NS) interferometers, where the contact region is a Y-shaped normal metal wave guide, and the two connection points to the same superconducting electrode can have different phases. The electric current in the interferometer is calculated as a function of the applied voltage and the phase difference . Andreev reflection in SNS and NS interferometers incorporates two features: interference in the arms of the Y-shaped normal region, and interplay with Andreev resonances. The latter feature yields rich phase dependent current structures in the subgap voltage region. The interference effect leads to a suppression of the current structures at . We investigate the effects on the Josephson current in NS interferometers due to current injection from the normal electrode. The two main effects of the nonequilibrium situation are: nonequilibrium population of the Andreev levels, which can result in enhancement, suppression, or even sign reversal of the Josephson current, and an anomalous interference Josephson effect, which gives rise to a long range Josephson effect, increasing with the voltage up to the superconducting gap . The two Andreev states in a superconducting quantum point contact can be accessed for manipulation and measurement by embedding the point contact in a superconducting loop. We calculate an effective Hamiltonian for the slow dynamics of the Andreev two-level system in the ring. Furthermore, we discuss methods of manipulation of the Andreev levels, and coupling of qubits. The state of the Andreev two-level system can be read out by monitoring the macroscopic quantum tunneling in a current biased Josephson junction, which is embedded in the superconducting ring of the qubit. We discuss the effects on the qubit, the readout scheme and the signal-to-noise ratio. THESIS FOR THE DEGREE OF DOCTOR OF PHILOSOPHY Coherent processes in Superconducting quantum interferometers and qubits
Josephson junctions are the central nonlinear element of superconducting qubits, yet their standard description is reached through a chain of approximations. We propose a purely quantum-mechanical model of the junction, formulated directly in Hilbert space: a charged particle moves on a one-dimensional loop, and the junction is a point at which the wave function obeys self-adjoint boundary conditions, labelled by a coupling strength λ, which controls the transparency of the junction, and a phase jump δ, which plays the role of the superconducting phase difference. For a loop with a single junction we solve the spectral problem and show that the ground-state momentum expectation, identified with the supercurrent, factorises exactly as ⟨p^0⟩=Ic(δ,λ)sinδ. For opaque junctions Ic becomes independent of δ and the first Josephson relation I=Icsinδ is recovered; for strongly attractive coupling, where the ground state is bound to the junction, the sinδ law is also recovered, but with an exponentially suppressed amplitude. For more transparent junctions, however, the model \emph{predicts} deviations from the pure sinδ law: Ic acquires a dependence on δ already at order λ−2, compatible with the higher Josephson harmonics recently found necessary to describe superconducting qubit spectra, and a fully transparent contact yields a current linear in δ. When the phase varies in time, a gauge transformation shows that the voltage drop across the junction is proportional to δ˙, so that the second Josephson relation emerges without being imposed. The boundary-condition approach thus reproduces both Josephson relations from first principles and predicts corrections to them, offering a route towards higher-fidelity models of superconducting qubits.
Properties of weak links between two superconductors, or Josephson junctions, make them interesting for fundamental physics research. Since their discovery over four decades ago, they have provided a unique way to study the behavior of the superconducting quantum phase. More recently, ultra small, or mesoscopic, Josephson junctions with substantial single Cooper pair charging energy have gained interest due to their behavior as macroscopic quantum objects. In addition to the theoretical interest, Josephson junctions can be used as active elements in circuit applications. Particularly, in this Thesis we study two different devices. We develop the required theoretical treatments, derive device properties, and compare the results with experimental data. The first application is a Josephson voltage standard based on externally damped Superconductor - Insulator - Superconductor junctions. It consists of an array of large Josephson junctions connected in series and irradiated with a 70 GHz microwave signal. Phase locking the Josephson dynamics into the signal leads to the quantization of the voltage. This is utilized in metrology. We introduce a new circuit solution based on frequency dependent damping of the junctions. Optimization and some designs for practical arrays are presented. The purpose is to find such a design that the array is fast, has low power consumption and is as stable as possible. Arrays able to generate DC voltages of order 1 volt with metrological accuracy are demonstrated experimentally and their applicability in AC voltage calibrations is analyzed. The second application is the Bloch Oscillating Transistor (BOT). The BOT is based on controlling the Cooper pair current in an ultra small Josephson junction by means of quasiparticles tunneling through a normal junction. As part of the thesis work, the principle of operation is first demonstrated computationally. The model is then refined to yield quantitative predictions of the characteristics. Finally, an analytic theory for the device is developed and the properties as an amplifier are derived.