In this thesis we present theoretical investigations of the effects of Andreev bound states on the current transport in superconducting interferometers. We also investigate the slow dynamics of the Andreev states in a superconducting point contact, and the possible application as a quantum bit. We consider superconductor-normal metal-superconductor (SNS) and normal metalsuperconductor (NS) interferometers, where the contact region is a Y-shaped normal metal wave guide, and the two connection points to the same superconducting electrode can have different phases. The electric current in the interferometer is calculated as a function of the applied voltage and the phase difference . Andreev reflection in SNS and NS interferometers incorporates two features: interference in the arms of the Y-shaped normal region, and interplay with Andreev resonances. The latter feature yields rich phase dependent current structures in the subgap voltage region. The interference effect leads to a suppression of the current structures at . We investigate the effects on the Josephson current in NS interferometers due to current injection from the normal electrode. The two main effects of the nonequilibrium situation are: nonequilibrium population of the Andreev levels, which can result in enhancement, suppression, or even sign reversal of the Josephson current, and an anomalous interference Josephson effect, which gives rise to a long range Josephson effect, increasing with the voltage up to the superconducting gap . The two Andreev states in a superconducting quantum point contact can be accessed for manipulation and measurement by embedding the point contact in a superconducting loop. We calculate an effective Hamiltonian for the slow dynamics of the Andreev two-level system in the ring. Furthermore, we discuss methods of manipulation of the Andreev levels, and coupling of qubits. The state of the Andreev two-level system can be read out by monitoring the macroscopic quantum tunneling in a current biased Josephson junction, which is embedded in the superconducting ring of the qubit. We discuss the effects on the qubit, the readout scheme and the signal-to-noise ratio. THESIS FOR THE DEGREE OF DOCTOR OF PHILOSOPHY Coherent processes in Superconducting quantum interferometers and qubits
In this thesis we present theoretical investigations of the effects of Andreev bound states on the current transport in superconducting interferometers. We also investigate the slow dynamics of the Andreev states in a superconducting point contact, and the possible application as a quantum bit. We consider superconductor-normal metal-superconductor (SNS) and normal metalsuperconductor (NS) interferometers, where the contact region is a Y-shaped normal metal wave guide, and the two connection points to the same superconducting electrode can have different phases. The electric current in the interferometer is calculated as a function of the applied voltage and the phase difference . Andreev reflection in SNS and NS interferometers incorporates two features: interference in the arms of the Y-shaped normal region, and interplay with Andreev resonances. The latter feature yields rich phase dependent current structures in the subgap voltage region. The interference effect leads to a suppression of the current structures at . We investigate the effects on the Josephson current in NS interferometers due to current injection from the normal electrode. The two main effects of the nonequilibrium situation are: nonequilibrium population of the Andreev levels, which can result in enhancement, suppression, or even sign reversal of the Josephson current, and an anomalous interference Josephson effect, which gives rise to a long range Josephson effect, increasing with the voltage up to the superconducting gap . The two Andreev states in a superconducting quantum point contact can be accessed for manipulation and measurement by embedding the point contact in a superconducting loop. We calculate an effective Hamiltonian for the slow dynamics of the Andreev two-level system in the ring. Furthermore, we discuss methods of manipulation of the Andreev levels, and coupling of qubits. The state of the Andreev two-level system can be read out by monitoring the macroscopic quantum tunneling in a current biased Josephson junction, which is embedded in the superconducting ring of the qubit. We discuss the effects on the qubit, the readout scheme and the signal-to-noise ratio. THESIS FOR THE DEGREE OF DOCTOR OF PHILOSOPHY Coherent processes in Superconducting quantum interferometers and qubits
A study of the Andreev level current through a weakly voltage-biased single-mode superconducting quantum point contact under microwave irradiation is presented. The applied microwave field induces resonant transitions between the current carrying Andreev states localized to the contact region, which results in an increase of the dc subgap current by several orders of magnitude. The applied voltage-bias couples to the superconductor phase difference across the junction, which will evolve in time. In turn the Andreev levels will oscillate adiabatically within the superconductor energy gap. Depending on the frequency of the applied field there can be either one or two resonances per oscillation period. When considering the case of two resonances the calculated dc-current exhibits an interference pattern as a function of inverse voltage. A measurement of the oscillation period would make it possible to reconstruct the Andreev level spectrum. Further, a detailed study is conducted concerning the microwave-induced current as a function of voltage bias, and the amplitude and frequency of the applied field. In realistic experimental situations there are equilibrium fluctuations of the applied voltage bias and sometimes impurity induced noise in the contact transparency. The amount of dephasing induced on the interference pattern by these fluctuations is estimated. In most cases the interference pattern will be subject to some amount of decay. However, there are parameter values for which this decay will be small. The decay originating from equilibrium fluctuations is predicted to have a non-monotonic dependence on the position of the resonances, while the decay induced by impurities should increase linearly when the separation between the resonances is increased. This difference could be used to distinguish between the two sources. The results also indicate that it should be possible to experimentally investigate the coupling between Andreev states and their environment, explicitly the impedance which the contact "sees" and the coupling strength between impurities and Andreev states.
We report on measurements of macroscopic quantum states in superconducting Josephson circuits using a highly sensitive hybrid quantum interferometer as the readout probe. The investigated Josephson circuit is one of the leading candidates as solid-state qubits (persistent current qubit), which are known to exhibit macroscopic quantum states with atomic-like properties. The readout device is a modified Andreev interferometer with semi-metallic normal segment in a “folded" geometry, and is designed to reduce the back action during measurement, as well as minimising the electromagnetic coupling between the circuit and the environment.\n A pulsed lock-in technique has been developed to perform continuous readout of the superconductor phase difference using pulse lengths down to 10 ns. The technique enables to control the energy of the probing quasiparticles in the normal segment of the interferometer, which in turn allows to control of the supercurrent owing in the SNS junction and prevents electron heating of the normal segment.\n An experimental set-up was designed and installed in a dilution fridge consisting of shielded wiring, magnetic screens, RF tight sample holder and printed circuit board to allow the injection of high frequency excitation signals, while minimising the environment effect on the qubit through careful electrical filtering. The effect of strong RF irradiation on Andreev interferometers allowed us to estimate the response time of the readout device to be less than 40 ps.\n The measurements show that two macroscopically distinct metastable states exist when the device is biased at the qubit degeneracy point, between which the system makes transitions that can be continuously monitored. Real time kinetics of the system has been investigated at different magnetic fluxes, pulse parameters, temperature and RF radiation. Based on statistical analysis of the transitions, we argue that the metastability is connected with macroscopic quantum tunnelling effects rather than thermal excitation. The experimental data support the hypothesis of a large low frequency noise causing low transition rates.
We present an extensive theoretical analysis of the supercurrent of a superconducting point contact of arbitrary transparency in the presence of a microwave field. Our paper is mainly based on two different approaches: a two-level model that describes the dynamics of the Andreev bound states in these systems and a fully microscopic method based on the Keldysh--Green function technique. This combination provides both a deep insight into the physics of irradiated Josephson junctions and quantitative predictions for arbitrary range of parameters. The main predictions of our analysis are: (i) for weak fields and low temperatures, the microwaves can induce transitions between the Andreev states, leading to a large suppression of the supercurrent at certain values of the phase; (ii) at strong fields, the current-phase relation is strongly distorted and the corresponding critical current does not follow a simple Bessel-function-like behavior; and (iii) at finite temperatures, the microwave field can enhance the critical current by means of transitions connecting the continuum of states outside the gap region and the Andreev states inside the gap. Our paper is of relevance for a large variety of superconducting weak links as well as for the proposals of using the Andreev bound states of a point contact for quantum computing applications.
Conventional tunnel Josephson junctions form the basic building blocks of superconducting electronics. Their operation is based on comparatively simple dynamics where the superconducting phases across the junctions is the only dynamical degree of freedom. The goal of the project on which this thesis is based, is to understand the physics and develop a consistent theoretical description of the quantum dynamics of unconventional Josephson structures: spin active junctions, junctions containing low energy quasiparticles, and junctions composed of d-wave superconductors. Spin active Josephson junctions involve the additional degree of freedom of quasiparticle spin. Here we theoretically investigate the spin-structure of the current carrying interface bound states - Andreev Bound States (ABS), and induced ground state spin polarization of a short (shorter than the superconducting coherence length) nanowire junction containing a localized magnetic moment. We show that temporal variation of the superconducting phase difference and magnetic moment induce rotations in spin polarized and unpolarized subspaces respectively, which is manifested by temporal oscillation of the Josephson current.The interlevel transitions obey a selection rule that forbids manipulations in a certain region ofexternal parameters and results from specific properties of Andreev bound states in magnetic contacts where, in a certain regime of phase bias and strength of magnetic scatterer, ABS belong to different eigenstates of the combined charge and parity inversion symmetry operator.A general framework is developed to include low energy quasiparticle states into the dynamics of Josephson junctions. Such states exist in e.g. constriction type junctions with high transparency channels or resonant states, as well as in junctions of unconventional superconductors. The existence of such states prevent the separation of energy scales which in conventional tunnel junctions freezes out the quasiparticle degrees of freedom. We show that the resonant interaction with such low energy states rather than the Josephson potential defines the nonlinear Josephson dynamics at small amplitudes.The framework is applied to high temperature Josephson junctions, whose unconventional order parameter admits ABS with energies in the middle of the superconducting gap - Mid Gap States (MGS). In addition to the non-linear dynamics induced by the MGS, we identify a reentrance effect in the transition between thermal activation and macroscopic quantum tunneling associated with the MGS, and connect this phenomenon to experimental observations.
Opportunités de manipulation directe d'un qubit de spin d'Andreev piloté en phase The research presented in this thesis delves into a theoretical exploration of Andreev bound states (ABS) hosted in Josephson junctions with spin-orbit coupling (SOC). ABS are fermionic bound states that appear at the junction between two superconducting electrodes forming a Josephson junction. These bound states are at the core of the microscopic description of the Josephson effect and provide an explanation for the transfer of Cooper pairs from one superconducting electrode to the other. Crucially, when the superconducting phase difference between the two electrodes is non-zero, a supercurrent can flow in the junction, depending on the occupancy of the ABS. The presence of this supercurrent facilitates the coupling between a microwave resonator and a junction due to its sensibility to the electromagnetic field. This coupling then allows for the detection and manipulation of ABS.Furthermore, in the presence of SOC along with a superconducting phase bias, the spin degeneracy of ABS can be lifted. Therefore such a junction provides a unique opportunity to realize a special kind of spin qubit known as Andreev spin qubit (ASQ). The qubit operation can be performed via an AC modulation of an electrostatic gate or magnetic flux, thanks to the sensitivity of the ABS to the electric potential or the phase difference, respectively. So far, the coherent manipulation of such qubits has been realized in gate-driven experiments as well as in flux-driven experiments with the use of additional Andreev levels. However, the direct transition between the two ABS forming the ASQ has remained out of reach in flux-driven experiments. In this thesis, we investigate two distinct types of Josephson junctions with SOC with the aim of estimating the amplitude of the matrix elements of the current operator between two ABS forming an ASQ. These elements characterize the coupling strength between the qubit and an external flux drive, indicating which transitions between ABS are within reach. Our first project focuses on a superconductor-normal-superconductor junction where the normal region consists of a nanowire with Rashba SOC. As a minimal model, we consider a generic scatterer located along the nanowire. Unless this scatterer possesses additional spatial (mirror) symmetries, it is responsible for inducing spin-flip transmission probability. Using the scattering formalism, we derive the energy spectrum of ABS and assess how SOC influences the spin-splitting between opposite spin states. We then obtain analytical expressions for the matrix elements of the current operator. Notably, our study reveals that SOC allows one to have finite elements between opposite spin states. In a second project, the system we study consists of a superconductor-double quantum dots-superconductor junction. A quantum dot consists of a tiny region defined by electrostatic gates or impurities. Due to its small size, Coulomb repulsion can be significant. However, in the simplest case of a quantum dot with a single level, even in the presence of SOC in the coupling between the dot and the leads, spin degeneracy of ABS is still preserved. However, recent experiments showed that additional levels allow to lift the spin degeneracy. Here, we introduce a second quantum dot which provides an additional level and offers more control on each level. By using an effective model, we identify the minimal ingredients that are necessary to lift the spin degeneracy. Our results reveal that this splitting is achievable through spin-dependent couplings with the leads and is reduced by the Coulomb repulsion. Additionally, the presence of a finite coupling between the two dots, combined with SOC in the couplings with the leads, allows one to have finite matrix elements of the current operator between opposite spin states, which we obtain numerically. In short, we present in this thesis two platforms for the realization of phase-driven ASQ.
We investigate ac Josephson effects between two superconductors connected by a single-mode quantum point contact, where the gap amplitudes in the two superconductors are unequal. In these systems, it was found in previous studies on the dc effects that, besides the Andreev bound states, the continuum states can also contribute to the current. Using the quasiclassical formulation, we calculate the current-voltage characteristics for general transmission D of the point contact. To emphasize bound versus continuum states, we examine in detail the low bias, ballistic (D=1) limit. It is shown that in this limit the current-voltage characteristics can be determined from the current-phase relation, if we pay particular attention to the different behaviors of these states under the bias voltage. For unequal gap configurations, the continuum states give rise to nonzero sine components. We also demonstrate that in this limit, the temperature dependence of the dc component follows $\mathrm{tanh}({\ensuremath{\Delta}}_{s}∕2T)$, where ${\ensuremath{\Delta}}_{s}$ is the smaller gap, with the contribution coming entirely from the bound state.