Conventional tunnel Josephson junctions form the basic building blocks of superconducting electronics. Their operation is based on comparatively simple dynamics where the superconducting phases across the junctions is the only dynamical degree of freedom. The goal of the project on which this thesis is based, is to understand the physics and develop a consistent theoretical description of the quantum dynamics of unconventional Josephson structures: spin active junctions, junctions containing low energy quasiparticles, and junctions composed of $d$-wave superconductors. Spin active Josephson junctions involve the additional degree of freedom of quasiparticle spin. Here we theoretically investigate the spin-structure of the current carrying interface bound states - Andreev Bound States (ABS), and induced ground state spin polarization of a short (shorter than the superconducting coherence length) nanowire junction containing a localized magnetic moment. We show that temporal variation of the superconducting phase difference and magnetic moment induce rotations in spin polarized and unpolarized subspaces respectively, which is manifested by temporal oscillation of the Josephson current.The interlevel transitions obey a selection rule that forbids manipulations in a certain region ofexternal parameters and results from specific properties of Andreev bound states in magnetic contacts where, in a certain regime of phase bias and strength of magnetic scatterer, ABS belong to different eigenstates of the combined charge and parity inversion symmetry operator.A general framework is developed to include low energy quasiparticle states into the dynamics of Josephson junctions. Such states exist in e.g. constriction type junctions with high transparency channels or resonant states, as well as in junctions of unconventional superconductors. The existence of such states prevent the separation of energy scales which in conventional tunnel junctions freezes out the quasiparticle degrees of freedom. We show that the resonant interaction with such low energy states rather than the Josephson potential defines the nonlinear Josephson dynamics at small amplitudes.The framework is applied to high temperature Josephson junctions, whose unconventional order parameter admits ABS with energies in the middle of the superconducting gap - Mid Gap States (MGS). In addition to the non-linear dynamics induced by the MGS, we identify a reentrance effect in the transition between thermal activation and macroscopic quantum tunneling associated with the MGS, and connect this phenomenon to experimental observations.
Conventional tunnel Josephson junctions form the basic building blocks of superconducting electronics. Their operation is based on comparatively simple dynamics where the superconducting phases across the junctions is the only dynamical degree of freedom. The goal of the project on which this thesis is based, is to understand the physics and develop a consistent theoretical description of the quantum dynamics of unconventional Josephson structures: spin active junctions, junctions containing low energy quasiparticles, and junctions composed of d-wave superconductors. Spin active Josephson junctions involve the additional degree of freedom of quasiparticle spin. Here we theoretically investigate the spin-structure of the current carrying interface bound states - Andreev Bound States (ABS), and induced ground state spin polarization of a short (shorter than the superconducting coherence length) nanowire junction containing a localized magnetic moment. We show that temporal variation of the superconducting phase difference and magnetic moment induce rotations in spin polarized and unpolarized subspaces respectively, which is manifested by temporal oscillation of the Josephson current.The interlevel transitions obey a selection rule that forbids manipulations in a certain region ofexternal parameters and results from specific properties of Andreev bound states in magnetic contacts where, in a certain regime of phase bias and strength of magnetic scatterer, ABS belong to different eigenstates of the combined charge and parity inversion symmetry operator.A general framework is developed to include low energy quasiparticle states into the dynamics of Josephson junctions. Such states exist in e.g. constriction type junctions with high transparency channels or resonant states, as well as in junctions of unconventional superconductors. The existence of such states prevent the separation of energy scales which in conventional tunnel junctions freezes out the quasiparticle degrees of freedom. We show that the resonant interaction with such low energy states rather than the Josephson potential defines the nonlinear Josephson dynamics at small amplitudes.The framework is applied to high temperature Josephson junctions, whose unconventional order parameter admits ABS with energies in the middle of the superconducting gap - Mid Gap States (MGS). In addition to the non-linear dynamics induced by the MGS, we identify a reentrance effect in the transition between thermal activation and macroscopic quantum tunneling associated with the MGS, and connect this phenomenon to experimental observations.
The topic of the PhD project is a comparative study of phase dynamics and macroscopic quantum phenomena in moderately damped NbN, YBaCuO grain boundary (GB) Josephson junctions (JJs) and hybrid devices. This type of research activity responds to the needs of better identifying phase dynamics in JJs in the moderately damped regime, which is going to be more and more common in hybrid nanostructures. Issues on a more detailed understanding of coherence, dissipation and noise in the various devices have a relevant role in the progress of quantum circuits.
In the last few years, studies of phase dynamics and macroscopic quantum phenomena have been extended to junctions composed of materials other than the traditional low critical temperature superconductors (LTS) and to novel types of structures with unconventional barriers composed for instance of graphene sheets or of grain boundaries. Progress in engineering new materials into junctions and in understanding and controlling the physics of interfaces may offer novel solutions for junctions of superior quality and complementary functionalities, and therefore may lead in the long run to improve also specific qubit performances.
For LTS JJs, once the barrier thickness and the critical current density (Jc) have been fixed, a reduction in its size unavoidably leads to a lowering of the critical current and determines a quite different phase dynamics re-normalized to the new scaling energy. Lower critical currents Ic result in lower Josephson energies EJ, and higher levels of dissipation are expected. The range of the energy dynamical parameters is significantly enlarged, and it is technologically easier to reproducibly realize nontrivial configurations. These devices are characterized by intermediate levels of dissipation (moderately damped regime) and by phase diffusion phenomena. The low Jc limit seems to be characteristic also of all futuristic nanohybrids devices incorporating nanowires, and the moderately damped regime (MDR) is intrinsically more common than it could be expected.
Measurements of switching current distribution (SCD) in these last years have turned to be standard tools to investigate phase dynamics in unconventional and hybrid systems and nanostructures. High critical temperature superconductors (HTS) are an example of unconventional systems, because of the d-wave order parameter symmetry and of the presence of low-energy quasiparticles, which are expected to induce high level of dissipation and as a consequence to spoil macroscopic quantum coherence. A comparative study in systems so different and complementary is of great interest.
During the PhD program, we have performed measurements of SCD, both in the thermal and quantum regime down to 20 mK, on moderately damped NbN/MgO/NbN JJs and on YBCO biepitaxial GB JJs. The NbN JJs exhibit a crossover from thermal activation (TA) to macroscopic quantum tunneling (MQT) regime at about 90 mK. After the MQT saturation, the width of the SCD follows the expected dependence in the TA regime. Deviations are evident in proximity and above the crossover temperature T* (about 1.6K) where we find effects of anti-correlation between the bath temperature and thermal fluctuations since the width of the histograms starts to collapse, and indications of a transition to a third regime called phase diffusion (PD) are evident, such as the change of the switching distributions symmetry.
Experimental data have been analyzed through numerical fitting of the switching probability and Monte Carlo simulations, and we found a good agreement with theoretical expectations based on multiple re-trapping processes, which strongly depend on the junction damping. The combined analysis of these three regimes allowed us to extract the fundamental parameters, which completely characterize the dynamics of such moderately damped NbN JJs. In addition, clear signatures of the PD regime have been detected and numerical methods have been developed to estimate the dissipation level in the MDR.
As a term of comparison, the studies on moderately damped systems have been also carried out on HTS junctions, which have different levels of intrinsic dissipation induced by low energy quasi-particles, and are for this reason of great impact as a reference.
In such JJs we have clearly observed a direct transition from the MQT to the PD regime. The width of the SCDs is constant below 100mK, which is a clearly indication of a quantum activation regime. Above 100mK the negative temperature derivative of the width is consistent with a diffusive motion due to multiple escape and re-trapping in the potential wells. Thermal behavior of the width has been fitted through numerical simulations, thus providing the estimate of the damping factor. These conclusions of a PD regime also in YBaCuO JJs are supported by data in presence of an externally applied magnetic field, and are consistent with the numerical outcomes.
Numerical simulations of the thermal behavior of the SCD width for different values of the quality factor ranging from 1 to 10 have been carried out. Such numerical simulations allow us to reconstruct a (Q, kBT/EJ) phase diagram summarizing the various activation regimes. The transition curve between the PD regime and the running state following thermal or quantum activation has been determined numerically by varying the damping factor Q as function of the ratio between the thermal energy and the Josephson energy. The result of the calculation is a universal curve. A phase diagram valid in a large range of dissipation conditions emerges as a functional guide to classify the switching behavior and to settle the fundamental junction parameters and energies in the MDR. It is therefore a reference for phase dynamics of novel types of junction and system for which the nature of the current induced transition from the superconducting to the normal state has not been completely clarified.
We develop a theoretical description of nonadiabatic Josephson dynamics in superconducting junctions containing low energy quasiparticles. Within this approach we investigate the effects of midgap states in junctions of unconventional d-wave superconductors. We identify a reentrance effect in the transition between thermal activation and macroscopic quantum tunneling, and connect this phenomenon to the experimental observations in Phys. Rev. Lett. 94, 087003 (2005). It is also shown that nonlinear Josephson dynamics can be defined by resonant interaction with midgap states reminiscent of nonlinear optical phenomena in media of two-level atoms.
We theoretically propose and analyze a Josephson-like magnetic tunnel junction (MTJ) structure that exhibits quantum spin dynamics analogous to those in superconducting Josephson junctions. By exploiting the isomorphism between the equations of motion for low-dissipation MTJs with easy-plane anisotropy and the Josephson phase dynamics, we construct a theoretical framework for realizing spintronic qubits. Within this framework, we identify the physical parameters, such as anisotropy constants, Gilbert damping, spin current amplitude, and geometric factors, that govern the transition from classical to quantum behavior. We show that different types of spintronic qubits, including analogs of charge, flux, and transmon superconducting qubits, can be implemented depending on the hierarchy of energy scales. A Hamiltonian formalism is developed for each regime, enabling an analytical treatment of the two-level quantum dynamics and estimation of coherence times. In particular, we demonstrate that the spin current can be used not only to excite but also to stabilize the qubit states through dissipation control. These findings provide a route toward integrating spintronic qubits into complementary metal-oxide-semiconductor compatible architectures and lay the groundwork for a fully spintronic platform for quantum computation.
Quasiparticle (QP) effects play a significant role in the coherence and fidelity of superconducting quantum circuits.The Andreev bound states of high-transparency Josephson junctions can act as low-energy traps for QPs, providing a mechanism for studying the dynamics and properties of both the QPs and the junction.Using locally injected and thermal QPs, we study QP loss and QP poisoning in epitaxial Al-InAs Josephson junctions incorporated in a superconducting quantum interference device (SQUID) galvanically shorting a superconducting resonator to ground.We observe changes in the resonance line shape and frequency shifts consistent with QP trapping into and clearing out of the ABSs of the junctions when the junctions are phase biased.By monitoring the QP trapping and clearing mechanisms in time, we find a time scale of O(1 µs) for these QP dynamics, consistent with the presence of phonon-mediated QP-QP interactions.Our measurements suggest that electron-phonon interactions play a significant role in the relaxation mechanisms of our system, while electron-photon interactions and electron-phonon interactions govern the clearing mechanisms.Our results highlight the QP-induced dissipation and complex QP dynamics in superconducting quantum circuits fabricated on superconductor-semiconductor heterostructures.
Opportunités de manipulation directe d'un qubit de spin d'Andreev piloté en phase The research presented in this thesis delves into a theoretical exploration of Andreev bound states (ABS) hosted in Josephson junctions with spin-orbit coupling (SOC). ABS are fermionic bound states that appear at the junction between two superconducting electrodes forming a Josephson junction. These bound states are at the core of the microscopic description of the Josephson effect and provide an explanation for the transfer of Cooper pairs from one superconducting electrode to the other. Crucially, when the superconducting phase difference between the two electrodes is non-zero, a supercurrent can flow in the junction, depending on the occupancy of the ABS. The presence of this supercurrent facilitates the coupling between a microwave resonator and a junction due to its sensibility to the electromagnetic field. This coupling then allows for the detection and manipulation of ABS.Furthermore, in the presence of SOC along with a superconducting phase bias, the spin degeneracy of ABS can be lifted. Therefore such a junction provides a unique opportunity to realize a special kind of spin qubit known as Andreev spin qubit (ASQ). The qubit operation can be performed via an AC modulation of an electrostatic gate or magnetic flux, thanks to the sensitivity of the ABS to the electric potential or the phase difference, respectively. So far, the coherent manipulation of such qubits has been realized in gate-driven experiments as well as in flux-driven experiments with the use of additional Andreev levels. However, the direct transition between the two ABS forming the ASQ has remained out of reach in flux-driven experiments. In this thesis, we investigate two distinct types of Josephson junctions with SOC with the aim of estimating the amplitude of the matrix elements of the current operator between two ABS forming an ASQ. These elements characterize the coupling strength between the qubit and an external flux drive, indicating which transitions between ABS are within reach. Our first project focuses on a superconductor-normal-superconductor junction where the normal region consists of a nanowire with Rashba SOC. As a minimal model, we consider a generic scatterer located along the nanowire. Unless this scatterer possesses additional spatial (mirror) symmetries, it is responsible for inducing spin-flip transmission probability. Using the scattering formalism, we derive the energy spectrum of ABS and assess how SOC influences the spin-splitting between opposite spin states. We then obtain analytical expressions for the matrix elements of the current operator. Notably, our study reveals that SOC allows one to have finite elements between opposite spin states. In a second project, the system we study consists of a superconductor-double quantum dots-superconductor junction. A quantum dot consists of a tiny region defined by electrostatic gates or impurities. Due to its small size, Coulomb repulsion can be significant. However, in the simplest case of a quantum dot with a single level, even in the presence of SOC in the coupling between the dot and the leads, spin degeneracy of ABS is still preserved. However, recent experiments showed that additional levels allow to lift the spin degeneracy. Here, we introduce a second quantum dot which provides an additional level and offers more control on each level. By using an effective model, we identify the minimal ingredients that are necessary to lift the spin degeneracy. Our results reveal that this splitting is achievable through spin-dependent couplings with the leads and is reduced by the Coulomb repulsion. Additionally, the presence of a finite coupling between the two dots, combined with SOC in the couplings with the leads, allows one to have finite matrix elements of the current operator between opposite spin states, which we obtain numerically. In short, we present in this thesis two platforms for the realization of phase-driven ASQ.
A practical quantum computer demands a physical quantum bit (qubit) that is scalable, has a well-defined initial state, and brings together coherence with reliable control and read-out. A compelling idea is to put together a locally protected Majorana qubit with a superconducting qubit. The superconducting qubit is used to read out the Majorana states while the Majorana qubit may act as a quantum memory. This thesis presents a series of studies on quantum transport in semiconducting nanowires coupled to superconductors to investigate various platforms for realizing Majorana. These studies are followed by microwave measurements on superconducting circuits compatible with semiconducting-superconducting heterostructures. We first evaluate the potential of Ge/Si core/shell nanowires by achieving induced superconductivity as well as estimating spin-orbit coupling. Next we explore the transport mediated by Andreev bound states formed in InSb nanowire quantum. A subgap negative differential conductance is investigated together with the coalescing Andreev resonances at zero bias relevant for the correct interpretation of Majorana experiments done on the same structures. We conclude our studies of semiconducting nanowires by exploring tunnel junctions in Sn-InSb nanowires that are prepared by in-situ shadowing using nearby nanowires and flakes. Tin shells are found to induce a hard superconducting gap persisting up to high magnetic fields. We observe the two-electron charging effect from a small superconducting island of Sn-InSb. This effect is attributed to charge parity stability, which makes this nanowire system an intriguing candidate for superconducting and topological quantum circuits. These Sn-InSb junctions are then used as the nonlinear element in a transmon qubit design where we observe a dispersive coupling between this nanowire Josephson junction and a superconducting resonator. We also present our progress towards building a magnetic field resilient superconducting circuit that allows integration with semiconducting and topological structures. In the last chapter, InSb semiconducting nanowires are utilized as shadow masks prior to superconductor deposition on an InAs quantum well. We study Josephson current properties in Josephson junctions made from these nanowire shadows. Our results point to highly transparent junctions that can be developed further for hybrid superconductor-semiconductor qubit systems.