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Physica A Statistical Mechanics and its Applications

Thermodynamic and joint entropy of linear dissipative systems

Ronit Mahapatra

Published Sep 10, 2025• 0 citations
Publisher
DOI
10.1016/j.physa.2025.130917

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Exact results about the nonequilibrium thermodynamics of open quantum systems at arbitrary timescales are obtained by considering all possible variations of initial conditions of a system. First we obtain a quantum-information theoretic equality for entropy production, valid for an arbitrary initial joint state of system and environment. For any finite-time process with a fixed initial environment, we then show that the system's loss of distinction-relative to the minimally dissipative state-exactly quantifies its thermodynamic dissipation. The quantum component of this dissipation is the change in coherence relative to the minimally dissipative state. Implications for quantum state preparation and local control are explored. For nonunitary processes-like the preparation of any particular quantum state-we find that mismatched expectations lead to divergent dissipation as the actual initial state becomes orthogonal to the anticipated one.
The second law does more than set the direction of thermodynamic evolution: it endows nonequilibrium transformations with an underlying geometry. In this work, we provide a unified geometric description of entropy production in classical and quantum thermodynamics based on Wasserstein-2 structures arising from gradient flows of free energy. We review how relaxation to equilibrium, in overdamped diffusions, discrete detailed-balanced Markov chains, and dissipative Lindblad dynamics, can be formulated as a gradient flow on the space of states. The associated Wasserstein-2 distance bounds entropy production, yielding a finite-time refinement of the second law. We extend this framework beyond purely dissipative dynamics by introducing generalized Wasserstein-2 metrics that incorporate conservative (Hamiltonian) dynamics in both classical inertial systems and open quantum systems, yielding intrinsic distances that exactly characterize minimal entropy production under fixed dissipative mobilities. We establish equivalence bounds between purely dissipative and Hamiltonian-dissipative geometries, explicitly quantifying how inertial or coherent dynamics can reduce dissipation. Finally, when restricted to equilibrium distributions, we recover the thermodynamic length of linear response-including the quantum thermodynamic length-thereby linking optimal transport, thermodynamic length, and counterdiabatic protocols within a single geometric framework. All in all, our results extend the Riemannian program of thermodynamics further from equilibrium and provide a geometric foundation for optimal protocols beyond the overdamped setting.
In thermodynamics, entropy production and work quantify irreversibility and the consumption of useful energy, respectively, when a system is driven out of equilibrium. For quantum systems, these quantities can be identified at the stochastic level by unravelling the system's evolution in terms of quantum jump trajectories. We here derive a general formula for computing the joint statistics of work and entropy production in Markovian driven quantum systems, whose instantaneous steady states are of Gibbs form. If the driven system remains close to the instantaneous Gibbs state at all times, then we show that the corresponding two-variable cumulant generating function implies a joint detailed fluctuation theorem so long as detailed balance is satisfied. As a corollary, we derive a modified fluctuation-dissipation relation (FDR) for the entropy production alone, applicable to transitions between arbitrary steady states, and for systems that violate detailed balance. This FDR contains a term arising from genuinely quantum fluctuations, and extends an analogous relation from classical thermodynamics to the quantum regime.
The erasure of quantum information is governed by two fundamental thermodynamic bounds: Landauer’s principle, which establishes the absolute minimum energetic cost of resetting a state, and Nernst’s unattainability principle, which dictates that perfect cooling to absolute zero entropy requires infinite resources. Under finite constraints, conventional cooling protocols utilizing thermal baths composed of n non-interacting particles are bottlenecked by a linear dissipation barrier (O(1/n)). In this thesis, we establish the ultimate thermodynamic limits of finite-resource multiqubit erasure and introduce the most thermodynamically efficient cooling protocol currently known. Building upon the max-cooling framework—a global unitary operation that systematically sorts the eigenvalues of the joint system-bath state to pack the highest probability mass into the target’s ground state—we engineer a bath Hamiltonian with specific, target-dependent degeneracies for arbitrary m-qubit systems. This collective protocol achieves an optimal asymptotic entropy production scaling of Σ = O(mˆ2/nˆ2), successfully saturating the scaling of the fundamental theoretical lower bound. This degeneracy-optimized approach strictly outperforms both standard non-interacting reservoirs and the best-known protocol for the independent cooling of single qubits using a reservoir of interacting particles (O(mˆ3/nˆ2)). Furthermore, we establish that surpassing conventional dissipation barriers requires an operational threshold of just n ≥ 2mˆ2 bath particles to achieve this optimal scaling.