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arXiv:2606.00698 · Physical Review Research

Wasserstein-2 gradient flows and the geometry of entropy production in classical and quantum stochastic thermodynamics

Olga Movilla Miangolarra, Ralph Sabbagh, Artemy Kolchinsky

cond-mat.stat-mechquant-phSubmitted May 30, 2026• Announced Jun 2, 2026• 0 citations
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Abstract

The second law does more than set the direction of thermodynamic evolution: it endows nonequilibrium transformations with an underlying geometry. In this work, we provide a unified geometric description of entropy production in classical and quantum thermodynamics based on Wasserstein-2 structures arising from gradient flows of free energy. We review how relaxation to equilibrium, in overdamped diffusions, discrete detailed-balanced Markov chains, and dissipative Lindblad dynamics, can be formulated as a gradient flow on the space of states. The associated Wasserstein-2 distance bounds entropy production, yielding a finite-time refinement of the second law. We extend this framework beyond purely dissipative dynamics by introducing generalized Wasserstein-2 metrics that incorporate conservative (Hamiltonian) dynamics in both classical inertial systems and open quantum systems, yielding intrinsic distances that exactly characterize minimal entropy production under fixed dissipative mobilities. We establish equivalence bounds between purely dissipative and Hamiltonian-dissipative geometries, explicitly quantifying how inertial or coherent dynamics can reduce dissipation. Finally, when restricted to equilibrium distributions, we recover the thermodynamic length of linear response-including the quantum thermodynamic length-thereby linking optimal transport, thermodynamic length, and counterdiabatic protocols within a single geometric framework. All in all, our results extend the Riemannian program of thermodynamics further from equilibrium and provide a geometric foundation for optimal protocols beyond the overdamped setting.

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30 pages 5 figures

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The second law does more than set the direction of thermodynamic evolution: it endows nonequilibrium transformations with an underlying geometry. In this work, we provide a unified geometric description of entropy production in classical and quantum thermodynamics based on Wasserstein-2 structures arising from gradient flows of free energy. We review how relaxation to equilibrium, in overdamped diffusions, discrete detailed-balanced Markov chains, and dissipative Lindblad dynamics, can be formulated as a gradient flow on the space of states. The associated Wasserstein-2 distance bounds entropy production, yielding a finite-time refinement of the second law. We extend this framework beyond purely dissipative dynamics by introducing generalized Wasserstein-2 metrics that incorporate conservative (Hamiltonian) dynamics in both classical inertial systems and open quantum systems, yielding intrinsic distances that exactly characterize minimal entropy production under fixed dissipative mobilities. We establish equivalence bounds between purely dissipative and Hamiltonian-dissipative geometries, explicitly quantifying how inertial or coherent dynamics can reduce dissipation. Finally, when restricted to equilibrium distributions, we recover the thermodynamic length of linear response-including the quantum thermodynamic length-thereby linking optimal transport, thermodynamic length, and counterdiabatic protocols within a single geometric framework. All in all, our results extend the Riemannian program of thermodynamics further from equilibrium and provide a geometric foundation for optimal protocols beyond the overdamped setting.
We derive geometrical bounds on the irreversibility in both quantum and classical Markovian open systems that satisfy the detailed balance condition. Using information geometry, we prove that irreversible entropy production is bounded from below by a modified Wasserstein distance between the initial and final states, thus strengthening the Clausius inequality in the reversible-Markov case. The modified metric can be regarded as a discrete-state generalization of the Wasserstein metric, which has been used to bound dissipation in continuous-state Langevin systems. Notably, the derived bounds can be interpreted as the quantum and classical speed limits, implying that the associated entropy production constrains the minimum time of transforming a system state. We illustrate the results on several systems and show that a tighter bound than the Carnot bound for the efficiency of quantum heat engines can be obtained.
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Modern theoretical physics rests on the interplay between quantum dynamics, thermodynamics, and spacetime geometry.Quantum mechanics describes microscopic evolution through unitary time dynamics, while thermodynamic systems exhibit irreversible entropy production. Meanwhile, geometric formulations of quantum mechanics and statistical physics suggest that physical laws may possess an underlying geometric structure. In this work we introduce a unified framework in which quantum evolution occurs on a complex-time manifold that incorporates both dynamical time and thermodynamic flow. We construct a geometric variational principle on this extended temporal manifold and derive a generalized quantum evolution equation that contains both Hamiltonian dynamics and geometric diffusion terms. The resulting theory provides a natural bridge between quantum mechanics, statistical mechanics, and informationgeometry. We explore the implications of the framework for quantum statistical systems, quantum field theory, and information flow in gravitational systems.
We develop a geometric formulation of stochastic dynamics in which noise, diffusion, path probabilities, fluctuation theorems, and entropy production arise from the intrinsic geometry of an evolving manifold rather than from externally imposed randomness. Within the theory of moving manifolds, we establish a curvature-noise correspondence: fluctuations are governed by the inverse curvature tensor, while entropy production is controlled by curvature deformation. The invariant continuity law on a moving hypersurface yields a geometric Fokker-Planck equation, and curvature-velocity coupling generates a quadratic Onsager-Machlup functional determining path weights. The resulting entropy functional satisfies a curvature-driven monotonicity law, providing a geometric derivation of the Second Law. In two dimensions, the curvature invariant reduces to Gaussian curvature and encodes topology, so topological transitions produce discrete entropy jumps. When the ambient space carries a Minkowskian signature, the same curvature-kinetic quadratic form that generates dissipative thermal weights produces oscillatory phase weights, and the Laplace-Beltrami operator governing entropy evolution acquires a Schrödinger-type structure. This provides a geometric resolution of the apparent distinction between classical stochastic behaviour and quantum dynamics. These results show that stochastic behaviour, thermodynamic irreversibility, and quantum transition amplitudes are unified within the moving manifold framework. Geometry does not merely accommodate stochasticity; stochastic behaviour arises as a consequence of deterministic geometric evolution. The theory predicts curvature-controlled anisotropic diffusion, entropy jumps at topology-changing events, and a geometric thermal-quantum crossover in which classical stochastic weights and quantum amplitudes are generated by the same curvature-kinetic action.
In this work, we present a geometrical formulation of quantum thermodynamics based on contact geometry and principal fiber bundles. The quantum thermodynamic state space is modeled as a contact manifold, with equilibrium Gibbs states forming a Legendrian submanifold that encodes the fundamental thermodynamic relations. A principal fiber bundle over the manifold of density operators distinguishes the quantum state structure from thermodynamic labels: its fibers represent non-equilibrium configurations, and their unique intersections with the equilibrium submanifold enforce thermodynamic consistency. Quasistatic processes correspond to minimizing geodesics under the Bures-Wasserstein metric, leading to minimal dissipation, while the divergence of geodesic length toward rank-deficient states geometrically derives the unattainability aspect of the third law. Non-equilibrium extensions, formulated through pseudo-Riemannian metrics and connections on the principal bundle, introduce curvature-induced holonomy that quantifies a geometric source of irreversibility in cyclic processes. In this framework, the thermodynamic laws in the quantum regime emerge naturally as geometric consequences.