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arXiv:2005.02871 · Physical Review Letters

Geometrical Bounds of the Irreversibility in Markovian Systems

Tan Van Vu, Yoshihiko Hasegawa

Published Jan 4, 2021• 116 citations
arXivHTMLPDF

Abstract

We derive geometrical bounds on the irreversibility in both quantum and classical Markovian open systems that satisfy the detailed balance condition. Using information geometry, we prove that irreversible entropy production is bounded from below by a modified Wasserstein distance between the initial and final states, thus strengthening the Clausius inequality in the reversible-Markov case. The modified metric can be regarded as a discrete-state generalization of the Wasserstein metric, which has been used to bound dissipation in continuous-state Langevin systems. Notably, the derived bounds can be interpreted as the quantum and classical speed limits, implying that the associated entropy production constrains the minimum time of transforming a system state. We illustrate the results on several systems and show that a tighter bound than the Carnot bound for the efficiency of quantum heat engines can be obtained.

DOI
10.1103/physrevlett.126.010601

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We derive geometrical bounds on the irreversibility in both quantum and classical Markovian open systems that satisfy the detailed balance condition. Using information geometry, we prove that irreversible entropy production is bounded from below by a modified Wasserstein distance between the initial and final states, thus strengthening the Clausius inequality in the reversible-Markov case. The modified metric can be regarded as a discrete-state generalization of the Wasserstein metric, which has been used to bound dissipation in continuous-state Langevin systems. Notably, the derived bounds can be interpreted as the quantum and classical speed limits, implying that the associated entropy production constrains the minimum time of transforming a system state. We illustrate the results on several systems and show that a tighter bound than the Carnot bound for the efficiency of quantum heat engines can be obtained.
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We formulate a geometric framework in which physical laws emerge from restricted access to microscopic information. Measurement constraints are modeled as a gauge symmetry acting on density operators, inducing a gauge-reduced space of physically distinguishable states. In the case of quantum thermodynamics, this construction leads to a gauge-invariant formulation in which the invariant entropy admits a stochastic description and satisfies a general detailed fluctuation theorem. From this result, we derive an integrated fluctuation theorem and a Clausius-like inequality that unifies the first and second laws in terms of invariant work and coherent heat. Entropy production is identified with the relative entropy between forward and backward probability measures on the gauge-reduced space of thermodynamic trajectories, revealing irreversibility as a geometric consequence of limited observability. The third law emerges as a singular zero-temperature limit in which thermodynamic orbits collapse and entropy production vanishes. Since the framework applies to arbitrary information constraints, it encompasses energy-based thermodynamics as a particular case of more general measurement scenarios.
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