Challenges
Datasets
Workspaces
Papers
Discussions
Leaderboard
Log inSign up
Challenges
Datasets
Workspaces
Papers
Discussions
Leaderboard
Blog
Job Board
Q3AS

© 2026 Aqora Quantum S.A.S.

TermsPrivacyLegal Notice

Journal of Chemical Theory and Computation

Investigating Non-Markovian Effects on Quantum Dynamics in Open Quantum Systems

Mariia Ivanchenko, Peter Walters, Fei Wang

Published Jun 12, 2025• 5 citations
Publisher

Abstract

The reduced description of the quantum dynamic processes in the condensed phase environment leads to the equation of motion with a memory kernel. Such a memory effect, termed non-Markovianity, presents more complex dynamics compared to its memoryless or Markovian counterpart, and many chemical systems have been demonstrated through numerical simulations to exhibit non-Markovian quantum dynamics. Explicitly how the memory impacts the dynamic process remains largely unexplored. In this work, we focus on ways to separate the non-Markovian contributions from the dynamics and study the non-Markovian effects. Specifically, we developed a rigorous procedure for mapping the exact non-Markovian quantum propagator to the Lindblad form. Consequently, it allows us to extract the negative decay rate from the Lindbladian that is the signature of the non-Markovianity. By including or excluding the negative rate in the time evolution, we can decisively pinpoint the influence of non-Markovianity on the system's properties such as coherence, entanglement, and equilibrium state distribution. The understanding of such memory effects on the dynamic process suggests the possibility of leveraging non-Markovianity for quantum control.

DOI
10.1021/acs.jctc.4c01632

Related papers

Exact decomposition of non-Markovian dynamics in open quantum systems

Mariia Ivanchenkoa, Peter Walters, Fei Wang

In this work, we developed a rigorous procedure for mapping the exact non-Markovian propagator to the generalized Lindblad form. It allows us to extract the negative decay rate that is the indicator of the non-Markovian effect. As a consequence, we can investigate the influence of the non-Markovian bath on the system's properties such as coherence and equilibrium state distribution. The understanding of the non-Markovian contribution to the dynamical process points to the possibility of leveraging non-Markovianity for quantum control.

arXiv:2412.00450•Nov 30, 2024•0 citations

Non-Markovian quantum processes: Complete framework and efficient characterization

Felix A. Pollock, César A. Rodríguez-Rosario, Thomas Frauenheim +2 more

Currently, there is no systematic way to describe a quantum process with memory solely in terms of experimentally accessible quantities. However, recent technological advances mean we have control over systems at scales where memory effects are non-negligible. The lack of such an operational description has hindered advances in understanding physical, chemical, and biological processes, where often unjustified theoretical assumptions are made to render a dynamical description tractable. This has led to theories plagued with unphysical results and no consensus on what a quantum Markov (memoryless) process is. Here, we develop a universal framework to characterize arbitrary non-Markovian quantum processes. We show how a multitime non-Markovian process can be reconstructed experimentally, and that it has a natural representation as a many-body quantum state, where temporal correlations are mapped to spatial ones. Moreover, this state is expected to have an efficient matrix-product-operator form in many cases. Our framework constitutes a systematic tool for the effective description of memory-bearing open-system evolutions.

arXiv:1512.00589•Physical Review A•Jan 25, 2018•331 citations

The Hidden Nature of Non-Markovianity

Jihong Cai, Advith Govindarajan, Marius Junge

The theory of open quantum systems served as a tool to prepare entanglement at the beginning stage of quantum technology and more recently provides an important tool for state preparation. Dynamics given by time dependent Lindbladians are Markovian and lead to decoherence, decay of correlation and convergence to equilibrium. In contrast Non-Markovian evolutions can outperform their Markovian counterparts by enhancing memory. In this letter we compare the trajectories of Markovian and Non-Markovian evolutions starting from a fixed initial value. It turns out that under mild assumptions every trajectory can be obtained from a family of time dependent Lindbladians. Hence Non-Markovianity is invisible if single trajectories are concerned.

quant-pharXiv:2602.17631•Feb 20, 2026•0 citations

How rare are Markovian quantum dynamics?

Charlotte Bäcker, Nick Maryshchak, Walter T. Strunz

A profound understanding of decoherence and dissipation in quantum dynamics is crucial for the realistic modeling of the evolution of quantum systems. In open quantum dynamics one distinguishes between a memoryless, so-called Markovian evolution and dynamics incorporating memory effects, termed non-Markovian. In this work we study how prevalent memory effects are in the set of all such dynamics. We thus investigate how often a Markovian description is applicable. This question is approached by investigating randomly generated two-step qubit dynamics with respect to different concepts and witnesses of non-Markovianity. We observe that almost all dynamics are non-Markovian, and only a small (yet finite) fraction is Markovian. Furthermore, we study how this proportion changes when considering certain subclasses such as lower rank or mixed-unitary dynamics. Importantly, our results shed light on the relative ratios of -- and interrelations between -- the sets of dynamics that are non-Markovian with respect to different criteria. Finally, we investigate the fraction of dynamics in which the memory effects are necessarily of quantum nature and establish a connection between two recently developed concepts that characterize the quantumness of memory in non-Markovian dynamics.

quant-pharXiv:2606.24511•Jun 24, 2026•0 citations

Memory Effects in Quantum Dynamics Modelled by Quantum Renewal Processes

Nina Megier, Manuel Ponzi, Andrea Smirne +1 more

Simple, controllable models play an important role in learning how to manipulate and control quantum resources. We focus here on quantum non-Markovianity and model the evolution of open quantum systems by quantum renewal processes. This class of quantum dynamics provides us with a phenomenological approach to characterise dynamics with a variety of non-Markovian behaviours, here described in terms of the trace distance between two reduced states. By adopting a trajectory picture for the open quantum system evolution, we analyse how non-Markovianity is influenced by the constituents defining the quantum renewal process, namely the time-continuous part of the dynamics, the type of jumps and the waiting time distributions. We focus not only on the mere value of the non-Markovianity measure, but also on how different features of the trace distance evolution are altered, including times and number of revivals.

arXiv:2106.07697•Entropy•Jul 16, 2021•6 citations

Dynamical signatures of non-Markovianity in a dissipative-driven qubit

Graziano Amati

We investigate signatures of non-Markovianity in the dynamics of a periodically driven qubit coupled to a dissipative bosonic environment. We propagate the dynamics of the reduced density matrix of the qubit by integrating the numerically exact hierarchical equations of motion. Non-Markovian features are quantified by comparing on an equal footing the predictions from diverse and complementary approaches to quantum dissipation. In particular, we analyze the distinguishability of quantum states, the decay of the volume accessible to the qubit on the Hilbert space, the negativity of the canonical rates in the generalized Lindblad equation, and the relaxation of the memory kernels in the Nakajima-Zwanzig generalized quantum master equation. We study the effects of controlled driving on the coherent dynamics of the system. We show that a suitable external field can offset the ergodic relaxation of time-correlation functions, increase distinguishability over time, and strengthen non-Markovian effects witnessed by the canonical dissipation channels. We furthermore observe the phenomenon of eternal non-Markovianity for sufficiently small system-bath coupling and we discuss how this can be enhanced by modulating the frequency of the external drive. This work provides a broad theoretical analysis of quantum dissipation in the framework of open quantum dynamics and quantum information.

arXiv:2401.09298•Physical Review A•May 22, 2024•6 citations
The reduced description of the quantum dynamic processes in the condensed phase environment leads to the equation of motion with a memory kernel. Such a memory effect, termed non-Markovianity, presents more complex dynamics compared to its memoryless or Markovian counterpart, and many chemical systems have been demonstrated through numerical simulations to exhibit non-Markovian quantum dynamics. Explicitly how the memory impacts the dynamic process remains largely unexplored. In this work, we focus on ways to separate the non-Markovian contributions from the dynamics and study the non-Markovian effects. Specifically, we developed a rigorous procedure for mapping the exact non-Markovian quantum propagator to the Lindblad form. Consequently, it allows us to extract the negative decay rate from the Lindbladian that is the signature of the non-Markovianity. By including or excluding the negative rate in the time evolution, we can decisively pinpoint the influence of non-Markovianity on the system's properties such as coherence, entanglement, and equilibrium state distribution. The understanding of such memory effects on the dynamic process suggests the possibility of leveraging non-Markovianity for quantum control.
In this work, we developed a rigorous procedure for mapping the exact non-Markovian propagator to the generalized Lindblad form. It allows us to extract the negative decay rate that is the indicator of the non-Markovian effect. As a consequence, we can investigate the influence of the non-Markovian bath on the system's properties such as coherence and equilibrium state distribution. The understanding of the non-Markovian contribution to the dynamical process points to the possibility of leveraging non-Markovianity for quantum control.
Currently, there is no systematic way to describe a quantum process with memory solely in terms of experimentally accessible quantities. However, recent technological advances mean we have control over systems at scales where memory effects are non-negligible. The lack of such an operational description has hindered advances in understanding physical, chemical, and biological processes, where often unjustified theoretical assumptions are made to render a dynamical description tractable. This has led to theories plagued with unphysical results and no consensus on what a quantum Markov (memoryless) process is. Here, we develop a universal framework to characterize arbitrary non-Markovian quantum processes. We show how a multitime non-Markovian process can be reconstructed experimentally, and that it has a natural representation as a many-body quantum state, where temporal correlations are mapped to spatial ones. Moreover, this state is expected to have an efficient matrix-product-operator form in many cases. Our framework constitutes a systematic tool for the effective description of memory-bearing open-system evolutions.
The theory of open quantum systems served as a tool to prepare entanglement at the beginning stage of quantum technology and more recently provides an important tool for state preparation. Dynamics given by time dependent Lindbladians are Markovian and lead to decoherence, decay of correlation and convergence to equilibrium. In contrast Non-Markovian evolutions can outperform their Markovian counterparts by enhancing memory. In this letter we compare the trajectories of Markovian and Non-Markovian evolutions starting from a fixed initial value. It turns out that under mild assumptions every trajectory can be obtained from a family of time dependent Lindbladians. Hence Non-Markovianity is invisible if single trajectories are concerned.
A profound understanding of decoherence and dissipation in quantum dynamics is crucial for the realistic modeling of the evolution of quantum systems. In open quantum dynamics one distinguishes between a memoryless, so-called Markovian evolution and dynamics incorporating memory effects, termed non-Markovian. In this work we study how prevalent memory effects are in the set of all such dynamics. We thus investigate how often a Markovian description is applicable. This question is approached by investigating randomly generated two-step qubit dynamics with respect to different concepts and witnesses of non-Markovianity. We observe that almost all dynamics are non-Markovian, and only a small (yet finite) fraction is Markovian. Furthermore, we study how this proportion changes when considering certain subclasses such as lower rank or mixed-unitary dynamics. Importantly, our results shed light on the relative ratios of -- and interrelations between -- the sets of dynamics that are non-Markovian with respect to different criteria. Finally, we investigate the fraction of dynamics in which the memory effects are necessarily of quantum nature and establish a connection between two recently developed concepts that characterize the quantumness of memory in non-Markovian dynamics.
Simple, controllable models play an important role in learning how to manipulate and control quantum resources. We focus here on quantum non-Markovianity and model the evolution of open quantum systems by quantum renewal processes. This class of quantum dynamics provides us with a phenomenological approach to characterise dynamics with a variety of non-Markovian behaviours, here described in terms of the trace distance between two reduced states. By adopting a trajectory picture for the open quantum system evolution, we analyse how non-Markovianity is influenced by the constituents defining the quantum renewal process, namely the time-continuous part of the dynamics, the type of jumps and the waiting time distributions. We focus not only on the mere value of the non-Markovianity measure, but also on how different features of the trace distance evolution are altered, including times and number of revivals.
We investigate signatures of non-Markovianity in the dynamics of a periodically driven qubit coupled to a dissipative bosonic environment. We propagate the dynamics of the reduced density matrix of the qubit by integrating the numerically exact hierarchical equations of motion. Non-Markovian features are quantified by comparing on an equal footing the predictions from diverse and complementary approaches to quantum dissipation. In particular, we analyze the distinguishability of quantum states, the decay of the volume accessible to the qubit on the Hilbert space, the negativity of the canonical rates in the generalized Lindblad equation, and the relaxation of the memory kernels in the Nakajima-Zwanzig generalized quantum master equation. We study the effects of controlled driving on the coherent dynamics of the system. We show that a suitable external field can offset the ergodic relaxation of time-correlation functions, increase distinguishability over time, and strengthen non-Markovian effects witnessed by the canonical dissipation channels. We furthermore observe the phenomenon of eternal non-Markovianity for sufficiently small system-bath coupling and we discuss how this can be enhanced by modulating the frequency of the external drive. This work provides a broad theoretical analysis of quantum dissipation in the framework of open quantum dynamics and quantum information.