Currently, there is no systematic way to describe a quantum process with memory solely in terms of experimentally accessible quantities. However, recent technological advances mean we have control over systems at scales where memory effects are non-negligible. The lack of such an operational description has hindered advances in understanding physical, chemical, and biological processes, where often unjustified theoretical assumptions are made to render a dynamical description tractable. This has led to theories plagued with unphysical results and no consensus on what a quantum Markov (memoryless) process is. Here, we develop a universal framework to characterize arbitrary non-Markovian quantum processes. We show how a multitime non-Markovian process can be reconstructed experimentally, and that it has a natural representation as a many-body quantum state, where temporal correlations are mapped to spatial ones. Moreover, this state is expected to have an efficient matrix-product-operator form in many cases. Our framework constitutes a systematic tool for the effective description of memory-bearing open-system evolutions.
Currently, there is no systematic way to describe a quantum process with memory solely in terms of experimentally accessible quantities. However, recent technological advances mean we have control over systems at scales where memory effects are non-negligible. The lack of such an operational description has hindered advances in understanding physical, chemical, and biological processes, where often unjustified theoretical assumptions are made to render a dynamical description tractable. This has led to theories plagued with unphysical results and no consensus on what a quantum Markov (memoryless) process is. Here, we develop a universal framework to characterize arbitrary non-Markovian quantum processes. We show how a multitime non-Markovian process can be reconstructed experimentally, and that it has a natural representation as a many-body quantum state, where temporal correlations are mapped to spatial ones. Moreover, this state is expected to have an efficient matrix-product-operator form in many cases. Our framework constitutes a systematic tool for the effective description of memory-bearing open-system evolutions.
Understanding temporal processes and their correlations in time is of paramount importance for the development of near-term technologies that operate under realistic conditions. Capturing the complete multi-time statistics that define a stochastic process lies at the heart of any proper treatment of memory effects. This is well understood in classical theory, where a hierarchy of joint probability distributions completely characterizes the process at hand. However, attempting to generalize this notion to quantum mechanics is problematic: observing realizations of a quantum process necessarily disturbs the state of the system, breaking an implicit, and crucial, assumption in the classical setting. This issue can be overcome by separating the experimental interventions from the underlying process, enabling an unambiguous description of the process itself and accounting for all possible multi-time correlations for any choice of interrogating instruments. In this paper, using a novel framework for the characterization of quantum stochastic processes, we first solve the long standing question of unambiguously describing the memory length of a quantum processes. This is achieved by constructing a quantum Markov order condition, which naturally generalizes its classical counterpart for the quantification of finite-length memory effects. As measurements are inherently invasive in quantum mechanics, one has no choice but to define Markov order with respect to the interrogating instruments that are used to probe the process at hand: different memory effects are exhibited depending on how one addresses the system, in contrast to the standard classical setting. We then fully characterize the structural constraints imposed on quantum processes with finite Markov order, shedding light on a variety of memory effects that can arise through various examples. Finally, we introduce an instrument-specific notion of memory strength that allows for a meaningful quantification of the temporal correlations between the history and the future of a process for a given choice of experimental intervention. These findings are directly relevant to both characterizing and exploiting memory effects that persist for a finite duration. In particular, immediate applications range from developing efficient compression and recovery schemes for the description of quantum processes with memory to designing coherent control protocols that efficiently perform information-theoretic tasks, amongst a plethora of others.
Every year, substantial theoretical and experimental progress is made towards the realisation of a genuinely new computational paradigm in the construction of a quantum computer. But progress is fractal; to make headway is to unearth the next set of obstacles. Decades of work has so far overcome physical, mathematical, engineering, and information theoretic obstacles to produce the remarkable high-fidelity devices we see today. But these devices must be near perfect to be useful. Indeed, advancements so far have precipitated sensitivity to a host of complex dynamical and control-based effects. Chief among these today are non-Markovian memory effects, where interactions between a quantum system and its surrounding environment can give rise to multi-time correlations. In this thesis, we address this issue and formally present a generalisation of quantum process tomography, called process tensor tomography (PTT). This establishes the ability to rigorously and systematically characterise non-Markovian open quantum systems, resolving many long-standing issues in the field. In the first part of this work, we present an original review of the literature and motivate the problem at hand. In the second, we develop the framework of PTT, including experiment design, post-processing algorithms, and both simulated and near-term device demonstrations. In particular, we demonstrate this as a tool for obtaining in-depth diagnostics about the nature and origin of temporal quantum correlations. Lastly, we dedicate our efforts to efficiency and self-consistency. To this effect, we explore theoretically processes with sparse memory structures. We then leverage this to develop various efficient estimation techniques tailored for different settings. The result is a robust and lightweight framework capable of both reconstructing and optimally controlling any non-Markovian open quantum dynamics.
Abstract Established methods for characterizing quantum information processes do not capture non-Markovian (history-dependent) behaviors that occur in real systems. These methods model a quantum process as a fixed map on the state space of a predefined system of interest. Such a map averages over the system’s environment, which may retain some effect of its past interactions with the system and thus have a history-dependent influence on the system. Although the theory of non-Markovian quantum dynamics is currently an active area of research, a systematic characterization method based on a general representation of non-Markovian dynamics has been lacking. In this article we present a systematic method for experimentally characterizing the dynamics of open quantum systems. Our method, which we call quantum process identification (QPI), is based on a general theoretical framework which relates the (non-Markovian) evolution of a system over an extended period of time to a time-local (Markovian) process involving the system and an effective environment. In practical terms, QPI uses time-resolved tomographic measurements of a quantum system to construct a dynamical model with as many dynamical variables as are necessary to reproduce the evolution of the system. Through numerical simulations, we demonstrate that QPI can be used to characterize qubit operations with non-Markovian errors arising from realistic dynamics including control drift, coherent leakage, and coherent interaction with material impurities.
Understanding whether the features of open quantum dynamics are genuinely quantum remains a central challenge in quantum dynamics. Even though the non-Markovian behavior of quantum dynamics has been widely investigated across different settings, there is still no consensus on which properties of a dynamics reflect genuine quantum features and which arise from classical or non-genuine quantum sources. In this review, we provide detailed information on recent developments in characterizing quantum non-Markovianity based on information backflow and the nature of its origin. We also present a survey on how various approaches separate classical and quantum contributions, as well as how they define operational tasks that reveal genuine quantum non-Markovianity. We analyze several frameworks, including state-distinguishability -based, channel-based (``CP-divisibility''), and process-tensor methods. For each framework, we outline the underlying physical motivation, the criteria proposed to distinguish genuine quantum non-Markovianity from practical or apparent memory effects. We further compare different approaches and their strengths and limitations. The review aims to clarify the conceptual and operational aspects of quantum non-Markovian processes based on their nature and to provide a foundation for future research on quantum non-Markovianity and its role in advancing quantum information science and technology.
The reduced description of the quantum dynamic processes in the condensed phase environment leads to the equation of motion with a memory kernel. Such a memory effect, termed non-Markovianity, presents more complex dynamics compared to its memoryless or Markovian counterpart, and many chemical systems have been demonstrated through numerical simulations to exhibit non-Markovian quantum dynamics. Explicitly how the memory impacts the dynamic process remains largely unexplored. In this work, we focus on ways to separate the non-Markovian contributions from the dynamics and study the non-Markovian effects. Specifically, we developed a rigorous procedure for mapping the exact non-Markovian quantum propagator to the Lindblad form. Consequently, it allows us to extract the negative decay rate from the Lindbladian that is the signature of the non-Markovianity. By including or excluding the negative rate in the time evolution, we can decisively pinpoint the influence of non-Markovianity on the system's properties such as coherence, entanglement, and equilibrium state distribution. The understanding of such memory effects on the dynamic process suggests the possibility of leveraging non-Markovianity for quantum control.
Recent advances in quantum technologies and related experiments have created a need for highly accurate, versatile, and computationally efficient simulation techniques for the dynamics of open quantum systems. Long-lived correlation effects (non-Markovianity), system-environment hybridization, and the necessity for accuracy beyond the Born-Markov approximation form particular challenges. Approaches to meet these challenges have been introduced, originating from different fields, such as hierarchical equations of motion, Lindblad-pseudomode formulas, chain-mapping approaches, quantum Brownian motion master equations, stochastic unravelings, and refined quantum master equations. This diversity, while indicative of the field's relevance, has inadvertently led to a fragmentation that hinders cohesive advances and their effective cross-community application to current problems for complex systems. How are different approaches related to each other? What are their strengths and limitations? Here we give a systematic overview and concise discussion addressing these questions. We make use of a unified framework which very conveniently allows to link different schemes and, this way, may also catalyze further progress. In line with the state of the art, this framework is formulated not in a fully reduced space of the system but in an extended state space which in a minimal fashion includes effective reservoir modes. This in turn offers a comprehensive understanding of existing methods, elucidating their physical interpretations, interconnections, and applicability.