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arXiv:2412.00450

Exact decomposition of non-Markovian dynamics in open quantum systems

Mariia Ivanchenkoa, Peter Walters, Fei Wang

Published Nov 30, 2024• 0 citations
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Abstract

In this work, we developed a rigorous procedure for mapping the exact non-Markovian propagator to the generalized Lindblad form. It allows us to extract the negative decay rate that is the indicator of the non-Markovian effect. As a consequence, we can investigate the influence of the non-Markovian bath on the system's properties such as coherence and equilibrium state distribution. The understanding of the non-Markovian contribution to the dynamical process points to the possibility of leveraging non-Markovianity for quantum control.

DOI
10.48550/arxiv.2412.00450

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In this work, we developed a rigorous procedure for mapping the exact non-Markovian propagator to the generalized Lindblad form. It allows us to extract the negative decay rate that is the indicator of the non-Markovian effect. As a consequence, we can investigate the influence of the non-Markovian bath on the system's properties such as coherence and equilibrium state distribution. The understanding of the non-Markovian contribution to the dynamical process points to the possibility of leveraging non-Markovianity for quantum control.
The reduced description of the quantum dynamic processes in the condensed phase environment leads to the equation of motion with a memory kernel. Such a memory effect, termed non-Markovianity, presents more complex dynamics compared to its memoryless or Markovian counterpart, and many chemical systems have been demonstrated through numerical simulations to exhibit non-Markovian quantum dynamics. Explicitly how the memory impacts the dynamic process remains largely unexplored. In this work, we focus on ways to separate the non-Markovian contributions from the dynamics and study the non-Markovian effects. Specifically, we developed a rigorous procedure for mapping the exact non-Markovian quantum propagator to the Lindblad form. Consequently, it allows us to extract the negative decay rate from the Lindbladian that is the signature of the non-Markovianity. By including or excluding the negative rate in the time evolution, we can decisively pinpoint the influence of non-Markovianity on the system's properties such as coherence, entanglement, and equilibrium state distribution. The understanding of such memory effects on the dynamic process suggests the possibility of leveraging non-Markovianity for quantum control.
We investigate signatures of non-Markovianity in the dynamics of a periodically driven qubit coupled to a dissipative bosonic environment. We propagate the dynamics of the reduced density matrix of the qubit by integrating the numerically exact hierarchical equations of motion. Non-Markovian features are quantified by comparing on an equal footing the predictions from diverse and complementary approaches to quantum dissipation. In particular, we analyze the distinguishability of quantum states, the decay of the volume accessible to the qubit on the Hilbert space, the negativity of the canonical rates in the generalized Lindblad equation, and the relaxation of the memory kernels in the Nakajima-Zwanzig generalized quantum master equation. We study the effects of controlled driving on the coherent dynamics of the system. We show that a suitable external field can offset the ergodic relaxation of time-correlation functions, increase distinguishability over time, and strengthen non-Markovian effects witnessed by the canonical dissipation channels. We furthermore observe the phenomenon of eternal non-Markovianity for sufficiently small system-bath coupling and we discuss how this can be enhanced by modulating the frequency of the external drive. This work provides a broad theoretical analysis of quantum dissipation in the framework of open quantum dynamics and quantum information.
The initial stages of the evolution of an open quantum system encode the key information of its underlying dynamical correlations, which in turn can predict the trajectory at later stages. We propose a general approach based on non-Markovian dynamical maps to extract this information from the initial trajectories and compress it into non-Markovian transfer tensors. Assuming time-translational invariance, the tensors can be used to accurately and efficiently propagate the state of the system to arbitrarily long time scales. The non-Markovian transfer tensor method (TTM) demonstrates the coherent-to-incoherent transition as a function of the strength of quantum dissipation and predicts the noncanonical equilibrium distribution due to the system-bath entanglement. TTM is equivalent to solving the Nakajima-Zwanzig equation and, therefore, can be used to reconstruct the dynamical operators (the system Hamiltonian and memory kernel) from quantum trajectories obtained in simulations or experiments. The concept underlying the approach can be generalized to physical observables with the goal of learning and manipulating the trajectories of an open quantum system.
We define non-Markovian quantum dynamics as evolution in which the current state depends on all past states, and completely characterize its structure under the assumptions of complete positivity and non-signalling. The resulting continuous-time dynamics is an integro-differential equation that augments the Gorini-Kossakowski-Sudarshan-Lindblad equation with a memory integral, and is capable of describing the quantum state of systems exposed to noise with any integrable power spectral density with no further approximations. We then establish a formalism to evaluate multi-time correlations of measurement outcomes in this general setting, obviating the need for a regression theorem. As an application, we derive the emission spectrum of a driven two-level system coupled to a non-Markovian bath: the familiar Mollow triplet acquires a frequency-dependent linewidth that encodes the memory of the bath. Our work provides a rigorous yet transparent description of the quantum state of non-Markovian systems, opening the door for state estimation and state-based quantum control beyond the Markovian regime.
We develop an exact framework for describing the non-Markovian dynamics of an open quantum system interacting with an environment modeled by a generalized spectral density function.The approach relies on mapping the initial system onto an auxiliary configuration, comprising the original open system coupled to a small number of discrete modes, which in turn are each coupled to an independent Markovian reservoir.Based on the connection between the discrete modes and the poles of the spectral density function, we show how expanding the system using the discrete modes allows for the full inclusion non-Markovian effects within an enlarged open system whose dynamics is governed by an exact Lindblad master equation.Initially we apply this result to obtain a generalization of the pseudomode method [B.M. Garraway, Phys. Rev. A. 55, 2290 (1997)] in cases where the spectral density function has a Lorentzian structure.For many other types of spectral density function, we extend our proof to show that an open system dynamics may be modeled physically using discrete modes which admit a non-Hermitian coupling to the system and for such cases determine the equivalent master equation to no longer be of Lindblad form.For applications involving two discrete modes, we demonstrate how to convert between pathological and Lindblad forms of the master equation using the techniques of the pseudomode method.
We introduce a systematic framework to derive the effective Hamiltonian governing the coherent dynamics of non-Markovian open quantum systems. By applying the minimal dissipation principle, we uniquely isolate the coherent contribution to the time-local generator of the reduced dynamics. We derive a general expression for the effective Hamiltonian and develop a recursive perturbative expansion that expresses it in terms of system-bath interaction terms and bath correlation functions. This expansion provides a systematic tool for analyzing energy renormalization effects across different coupling regimes. Applying our framework to paradigmatic spin systems, we reveal how environmental correlations influence energy shifts and eigenbasis rotations, offering insights into strong-coupling effects and non-Markovian quantum thermodynamics.