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New Journal of Physics

Fast switching of the rf trapping field in an ion trap

Laura Blackburn, Amber Shepherd, Matthias Keller

Published Mar 28, 2025• 1 citation
Publisher

Abstract

Abstract Radiofrequency ion traps are essential for many experiments, ranging from quantum computing to physical chemistry and fundamental science. However, in some circumstances the trapping fields may cause undesired effects and need to be switched off briefly during operation without compromising the trap stability. By employing interference in the trap resonator circuit to enable switching faster than the resonator’s natural decay, the electric field in the trap can be extinguished by > 50 dB. We have demonstrated that it is possible to switch a linear Paul trap off for several microseconds without the loss of 40Ca+ ions, even for large three-dimensional ion crystals, and have examined the effect of the switching parameters on the ion dynamics by monitoring the fluorescence rate. We have loaded N 2 + ions into a crystal of trapped calcium ions via photoionisation using this technique, demonstrating that it is also possible to capture ions despite the absence of a trapping field during the ionisation.

DOI
10.1088/1367-2630/adc6b0

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•May 21, 2012•1 citation
Abstract Radiofrequency ion traps are essential for many experiments, ranging from quantum computing to physical chemistry and fundamental science. However, in some circumstances the trapping fields may cause undesired effects and need to be switched off briefly during operation without compromising the trap stability. By employing interference in the trap resonator circuit to enable switching faster than the resonator’s natural decay, the electric field in the trap can be extinguished by > 50 dB. We have demonstrated that it is possible to switch a linear Paul trap off for several microseconds without the loss of 40Ca+ ions, even for large three-dimensional ion crystals, and have examined the effect of the switching parameters on the ion dynamics by monitoring the fluorescence rate. We have loaded N 2 + ions into a crystal of trapped calcium ions via photoionisation using this technique, demonstrating that it is also possible to capture ions despite the absence of a trapping field during the ionisation.
Trapped molecular ions in pure rovibronic states are desirable in experiments ranging from cold chemistry to searches for physics beyond the Standard Model. Resonance-enhanced multiphoton ionisation (REMPI) can be used to prepare molecular ions in specific internal states with high fidelities. However, in the presence of electric fields, ionisation spectra exhibit frequency shifts and the ionisation thresholds are broadened. For this reason, REMPI studies are normally conducted in low and highly homogeneous electric fields, whereas the operating principle of rf ion traps requires electric fields that vary in space and time. In order to investigate the impact of this on the state-selectivity of REMPI in ion traps, we have simulated the expected broadening of the ionisation threshold under various operating conditions of a typical linear Paul trap. In many cases, the width of the ionisation threshold exceeds the separation between rotational energy levels, preventing state-selective ionisation. Careful choice of the trapping and laser parameters during loading can reduce this broadening, enabling state-selective ionisation in some instances. Where this strategy is not sufficient, the broadening can be reduced further by rapidly switching the trapping voltages off and on again during loading. This has been demonstrated experimentally for a Coulomb crystal of [Formula: see text] ions without descrystallising it.
This thesis describes experimental work towards developing a trapped ion quantum information processor. An existing ion trap apparatus was capable of trapping and laser-cooling single ions or small ion strings of 40 Ca+, and had been used for studies of quantum jumps and natural lifetime measurements in Ca. This thesis describes improvements in this apparatus, which have allowed the stability and the flexibility of experimental control of the ions to be greatly increased. This enabled experiments to read out the spin state of a single trapped ion, and to load ions with isotope selectivity through photoionization. The optical systems were improved by installation of new lasers, optical reference cavities, and a system of acousto-optic modulators for laser intensity switching and frequency control. The photon counting for fluorescence detection was improved, and a new photon time-of-arrival correlation circuit developed. This has permitted rapid and more sensitive detection of micromotion, and hence cancellation of stray fields in the trap. A study of resonant circuits in the low RF, high voltage (10 MHz, 1 kV) regime was carried out with a view to developing a new RF supply for the Paul trap with reduced noise and increased power. A new supply based on a helical resonator was built and used to trap ions. This technique has reduced noise and will permit higher secular frequencies to be attained in the future. A magnetic field B in the ion trap is used to define a quantization axis, and in one series of experiments was required to be of order 100 G to provide a substantial Zeeman splitting. A set of magnetic field coils to control the size and direction of B is described. The design of these posed some problems owing to an unforseen issue with the vacuum chamber. In short, it is magnetizable and acts to first approximation like a magnetic shield. The field coils had to be sufficiently substantial to produce the desired field at the ion even in the presence of this shielding effect, and dark resonance (and other) spectra with Zeeman splitting were obtained to calibrate the field using the ion as a probe. Finally, the thesis describes the successful loading of the ion trap by laser photoionization from a weak atomic beam. This involved two new lasers at 423 nm and 389 nm. Saturated absorption spectroscopy of neutral calcium is first described, then transverse excitation of an atomic beam in our vacuum chamber is used to identify all the main isotopes of calcium and confirm their abundances in our source (a heated sample of natural calcium). Finally, photoionization is used to load the trap. This has three advantages over electron-impact ionization. By avoiding an electron gun, we avoid charging of insulating patches and subsequent electric field drift as they discharge; the flux in the atomic beam and hence calcium (and other) deposits on the electrodes can be greatly reduced; and most importantly, the photoionization is isotope selective. Evidence is presented which suggests that even with an non-enriched source, the rare isotope 43 Ca can be loaded with reasonable efficiency. This isotope is advantageous for quantum information experiments for several reasons, but chiefly because its ground state hyperfine structure can act as a stable qubit.
We actively stabilize the harmonic oscillation frequency of a laser-cooled atomic ion confined in a radiofrequency (rf) Paul trap by sampling and rectifying the high voltage rf applied to the trap electrodes. We are able to stabilize the 1 MHz atomic oscillation frequency to be better than 10 Hz or 10 ppm. This represents a suppression of ambient noise on the rf circuit by 34 dB. This technique could impact the sensitivity of ion trap mass spectrometry and the fidelity of quantum operations in ion trap quantum information applications.
A range of experimental techniques for application in reaction studies between ionic and neutral atoms/molecules and high resolution spectroscopy experiments with sympathetically cooled molecular ions are presented. A novel ion trap loading scheme using the photo-ionisation of atoms generated by the pulsed laser ablation of a solid calcium target has been characterised. We have identified the range of ablation laser fluences that must be used in order to produce a flux of neutral calcium atoms, which is a prerequisite for isotope selective ion trap loading. Calcium ions are trapped and laser cooled in a linear radio-frequency ion trap. We have developed a spectroscopy scheme that allows the entire fluorescence spectrum of trapped ions to be rapidly collected with high precision while maintaining a low ion temperature and good ion localisation throughout interrogation. The scheme has been demonstrated by measuring the saturation intensity of the calcium ion 4S1/2?4P1/2 transition. We have developed a novel scheme to measure the secular motion of trapped ions and demonstrated the application of the technique to ion-neutral collision reaction experiments. Employing pulsed excitation and Doppler velocimetry, we have measured the centre-of-mass mode frequency of single ions as well as large ion crystals with a frequency precision better than 2x10-3 within an interrogation time on the order of seconds. This method has been used to measure the mass of ions and observe charge exchange collisions between trapped calcium isotopes. In particular, we have measured the 44Ca++40Ca!40Ca++44Ca reaction cross section and demonstrated the single-event resolution of the technique. Finally, we have developed a novel all-optical broadband scheme for exciting, amplifying and measuring the secular motion of ions in the trap. Oscillation induced by optical excitation has been coherently amplified to control and measure the ion's secular motion. Requiring only a single interrogation laser, the ion's oscillation amplitude can be precisely controlled. The application of this technique to non-destructive spectroscopy of trapped molecular ions is discussed.
Linear Paul traps use radio frequency fields to confine ions for long times in deep potentials. The simplicity and versatility of these devices has led to their use in a wide variety of fields, from mass spectroscopy to quantum information. Within the past fifteen years, beginning with pioneering work at UConn, Paul traps have been combined with atom traps to form hybrid atom-ion traps. Hybrid traps serve as platforms for measuring ion-atom interaction rates, sympathetically cooling atomic and molecular ions, and studying the behavior of trapped ions. This work discusses simulations, analytical theory, and experiments in a hybrid trap that show a previously unknown dynamical effect in a population of trapped ions. The steady state trapped ion number in a Paul trap is non-monotonic with the loading rate of the Paul trap. This effect is universal to both Linear and 3D Paul traps and is likely to be found in other types of ion traps as well because it is the result of the Coulomb interaction in the presence of a trap. This behavior also affects the decay of ions from the trap. Understanding the loading and decay behavior from a saturated Linear Paul trap is important for the study of ion-atom interactions in a hybrid trap when the ions lack optical transitions.
Laser systems and a linear radiofrequency (rf) Paul trap with an integrated co-axial cavity have been developed for experiments in cavity QED and probabilistic entanglement. Single 40Ca+ ions and large Coulomb crystals have been trapped routinely and laser cooled with long trapping lifetimes. A technique to achieve precise overlap of the pseudopotential minimum of the rf-field with the cavity mode has been implemented through variable capacitors in the resonant rf-circuit used to drive the trap. Three-dimensional micromotion compensation has been implemented. An 894 nm laser has been frequency stabilised to a Pound-Drever-Hall cavity which is in turn stabilised to atomic Cs using polarisation spectroscopy. The Allan variance of the error signal has been reduced to less than a kilohertz on timescales greater than a second. A novel implementation of the scanning cavity transfer lock has been developed to transfer the stability of the 894 nm laser to the 397 nm ion cooling and 866 nm repumping lasers. The bandwidth of the system has been increased to 380 Hz and the Allan variance of the error signal has been reduced to less than ten kilohertz on timescales of greater than a second. The pseudopotential minimum of the rf field has been overlapped optimally with the optical cavity mode through mapping of the fluorescence from cavity-field repumped ions as a function of their displacement. Coupling to the cavity mode has been confirmed by observation of resonant fluorescence into the cavity mode using the cavity-assisted Raman transition process. The thesis demonstrates that the setup is ready for the controlled production of single photons with pre-determined polarisation states, and progression onto new schemes to entangle multiple ions that are coupled to the optical cavity mode.