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Foundations of Chemistry

The irreducibility of chemistry to Everettian quantum mechanics

Ryan Michael Miller

Published Jan 29, 2025• 1 citation
Publisher

Abstract

Abstract The question of whether chemical structure is reducible to Everettian Quantum Mechanics (EQM) should be of interest to philosophers of chemistry and philosophers of physics alike. Among the three realist interpretations of quantum mechanics, EQM resolves the measurement problem by claiming that measurements (now interpreted as instances of decoherence) have indeterminate outcomes absolutely speaking, but determinate outcomes relative to emergent worlds—Maudlin (Topoi, 14:7-15, 1995). Philosophers who wish to be sensitive to the practice of quantum chemistry e.g. Scerri (The changing views of a philosopher of chemistry on the question of reduction, 2016) should be interested in EQM because Franklin and Seifert (J. Philos. Sci, 2020) claim that resolving the measurement problem also resolves the reducibility of chemical structure, and EQM is the interpretation which involves no mathematical structure beyond that used by practicing scientists. Philosophers interested in the quantum interpretation debate should be interested in the reducibility of chemistry because chemical structure is precisely the kind of determinate three-dimensional fact which EQM should be able to ground if it is to be empirically coherent—see Allori (Quantum Rep, 5:80-101, 2023). The prospects for reduction of chemical structure are poor if it cannot succeed in EQM; the prospects for EQM as a guide to ontology are poor if it cannot reduce chemical structure. Unfortunately for proponents of chemical reduction and EQM, there are three serious barriers to the reduction of chemistry to EQM. The first concern is that quantum treatments of chemical structure rely on the Born-Oppenheimer approximation, which holds nuclear locations fixed while minimizing the energy of the electronic configuration—Hendry (Philosophical Perspectives in Quantum Chemistry, 147-172, 2022), but this approximation is not licensed by EQM. The Born-Oppenheimer approximation relies on nuclei and molecular orbitals being simultaneously present, but in the three-dimensional ontology following from the Everett interpretation these only emerge at different energy scales and are not simultaneously present—Miller (Found. Chem, 25:405-417, 2023). The second concern is that the emergent worlds of EQM are supposed to be decoherent at the macro-scale—Wilson (The Nature of Contingency: Quantum Physics as Modal Realism 2020), but the recent development of superchemistry suggests that chemical reactions can occur in coherent states—Zhang et al. (Nat. Phys, 1-5, 2023). The third concern is that emergent worlds are only pragmatic pseudo-processes—Wallace (The Emergent Multiverse: Quantum Theory According to the Everett Interpretation, 2012b), but this means EQM trades realist physics for mere instrumentalism about chemistry. Absent a commitment to chemical realism, reduction is an empty promise. The prospects for reduction of chemical structure to EQM are therefore poor.

DOI
10.1007/s10698-025-09531-7

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Abstract The debate between ontological reductionists and emergentists in chemistry has revolved around quantum mechanics. What Franklin and Seifert (BJPS 2020) add to the long-running dispute is an attention to the measurement problem. They contend that all three realist interpretations of the quantum formalism capable of resolving the measurement problem also obviate any need for chemical emergence. I push their argument further, arguing that the realist interpretations of quantum mechanics actually subvert the basis for reduction as well, by undercutting the idea that fundamental physical particles are actual parts of molecules. With both reduction and traditional synchronic emergence pictures ruled out, the only option for realists about quantum chemistry is strong Thomistic emergence.

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The question of whether Everettian quantum mechanics (EQM) justifies the existence of metaphysical indeterminacy has recently come to the fore. Metaphysical indeterminacy has been argued to emerge from three sources: coherent superpositions, the indefinite number of branches in the quantum multiverse and the nature of these branches. This paper reviews the evidence and concludes that those arguments don't rely on EQM alone and rest on metaphysical auxiliary assumptions that transcend the physics of EQM. We show how EQM can be ontologically interpreted without positing metaphysical indeterminacy by adopting a deflationary attitude towards branches. Two ways of developing the deflationary view are then proposed: one where branches are eliminated, and another where they are reduced to the universal quantum state.

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The World in the Wave Function

David J. Wallace

David Lewis famously quipped that he was willing to take metaphysical lessons from quantum mechanics only when it cleaned up its own act by providing interpretations or modifications of the formalism shorn of appeal to consciousness, irreducibly macroscopic notions, or outright instrumentalism. By the first decade of the twenty-first century, multiple approaches to quantum mechanics had been developed to a degree which met Lewis’s challenge: dynamical-collapse theories, Bohm-style hidden-variable theories, and Everett-style many-worlds theories, for all their respective problems and challenges, all offer ways of understanding quantum mechanics that metaphysicians can reasonably engage with. And so the last twenty years have seen a resurgence in the metaphysics of quantum mechanics, the question of what ontology and ideology is appropriate to a quantum universe. The metaphysics of quantum mechanics is not independent of the quantum measurement problem but does not coincide with it, either: there is a widespread view that adopting, say, the Everett interpretation still leaves significant ontological questions undecided, and conversely, a given answer to those questions might answer them for a dynamical-collapse theory too.Wave function realism has become a leading contender for the metaphysics of quantum mechanics, particularly in the case of dynamical-collapse and Everettian approaches. The starting point is nonrelativistic quantum mechanics expressed in configuration space: mathematically, the subject matter of the theory is a complex function of 3N variables, evolving under the Schrödinger equation (perhaps interrupted by occasional stochastic collapses). Traditionally those 3N variables are interpreted as the three coordinates of position of N particles—but in wave function realism, they are interpreted as points in a new, high-dimensional space. Quantum mechanics, according to the wave function realist, fundamentally concerns the undulations of the wave function in this space; three-dimensional goings-on are emergent, high-level, derivative.Alyssa Ney has been a leading figure in the development of wave function realism for most of its existence. Her articles advocating and developing the position have been highly influential, and the present book can be seen as the culmination of this line of her research and is the definitive statement of wave function realism as of 2021. Despite its comparative brevity, the book is too rich to be adequately described—far less critiqued—in this brief review; my goal is to give an overview of the main themes and arguments, and to make a few critical remarks along the way.The World in the Wavefunction is not formally divided into parts, but it can profitably be thought of that way. Chapters 1 through 3 develop the core case for wave function realism. Chapter 4 defends the position from the frequent criticism that it is restricted to nonrelativistic physics, by providing a version of wave function realism appropriate to quantum field theory. And chapters 5 through 7 are an extended exploration of how the observed three-dimensional world can be understood as emerging from a high-dimensional fundamental reality.The case Ney makes in chapters 1 through 3 for wavefunction realism is modest and cautious. In chapter 1 she provides a fairly standard—though elegantly expressed—case for the prima facie plausibility of wave function realism simply based on the fact that standard formulations of quantum mechanics are written in 3N dimensions, and on the (related) fact that entanglement means we cannot interpret quantum mechanics simply in terms of spatially localized particles and nothing else. But in chapter 2 she explicitly argues against any attempt to strengthen these plausibility arguments into reasons why wave function realism must be adopted; indeed, she provides a detailed and sympathetic taxonomy of the alternatives to wave function realism that have been developed, all of which she regards as entirely viable. (Chapter 2 of the book could profitably be used as introductory reading for a general graduate course on quantum metaphysics.) For Ney, the question of which metaphysics to adopt is a standard metaphysician’s question, to be answered by weighing strengths and weaknesses of the various alternatives against one another.In chapter 3, Ney identifies two such strengths for wave function realism. First, it is separable: we can specify the complete state of the universe point-by-point on the fundamental space, without any need to appeal to irreducible holism. Second, it is dynamically local: expressed in 3N-dimensional space, the Schrödinger dynamics involve no action at a distance.Ney makes the case for separability at length. Her case for dynamical locality is brief: she regards it as a straightforward consequence of the fact that the Schrödinger equation is a differential equation, so that the rate of change of the wave function at a point x depends only on the wave function arbitrarily close to x. But I think there is more worth investigating here: after all, the nonrelativistic Schrödinger equation may be a differential equation, but it is a parabolic differential equation, with no maximum speed of propagation: the rate of change of the wave function at x may depend only on a neighborhood of x, but the value of the wavefunction at x an arbitrarily short time later depends on the wave function everywhere in space. (And this is not—or not straightforwardly—just an artifact of ignoring relativity.)But in any case, why think that a separable, local theory is preferable to the alternative? Ney claims that separability and locality are more intuitive and lead to a more comprehensible ontology—and she makes an unabashed defense of intuitiveness and explicability as theoretical virtues. She is quite explicit that her reasons are pragmatic: intuitive theories benefit students and teachers; they are better suited to help us develop new theories; they speak better to the reasons why many students (Ney included) want to study physics in the first place. The implied metaphilosophy here is fascinating and it would be good to see it developed further in subsequent work: Ney seems to reject the mainstream modern approach to ontology (in which these pragmatic virtues are not obviously relevant to the truth of wave function realism) in favor of something neo-Carnapian where (so far as I can see) the goal of a quantum ontology is to help us get a deeper understanding of quantum mechanics, and that’s all there is to it. This also fits naturally with the pluralism she urges, in which approaches other than hers can also be valuable.Chapter 4—on relativistic generalizations of wavefunction realism—attempts both a conceptual and a technical task. The conceptual task is to argue that wavefunction realism per se is not wedded to any particular theory or choice of Hilbert-space basis within the theory: rather, wave function realism is any strategy that reifies a high-dimensional space in order to produce a separable local quantum ontology. If so, there is no block in principle to a relativistic generalization of the approach: we just need to find some appropriate high-dimensional space to describe the quantum state in relativistic quantum theory.The general philosophical point is well taken and convincingly defended (though it’s important to note that while arbitrary choices of Hilbert-space basis will give a separable theory, there is no reason to assume they will give a dynamically local theory: even something as simple as shifting from the position to the momentum basis in nonrelativistic quantum mechanics transforms the Schrödinger equation into something explicitly nonlocal). Unfortunately, I don’t think Ney succeeds in giving a clear statement of the high-dimensional space she has in mind for quantum field theory. This is one place where her laudable goal of making the book intelligible to nonspecialists becomes problematic: she makes many suggestive and interesting comments on quantum field theory, but there is no explicit, precise, mathematical statement of her view that can be contrasted with the explicit, precise, mathematical representation of the state in nonrelativistic quantum mechanics as a complex function on 3N-dimensional space.In the last part of the book—concerned with the emergence of ordinary three-dimensional ontology—Ney begins (chapter 5) by rebutting influential arguments by Tim Maudlin, Valia Allori, Sheldon Goldstein, and others that it is empirically incoherent for a physical theory not to make precise, nonemergent, nonderivative statements about matter in three-dimensional space (for a theory not to have a primitive ontology, to use the standard term for it). Ney argues—persuasively, to me—that it is perfectly compatible with the way science usually works for a theory to make statements about the observable only in an indirect, derivative way, so that while it might be a desideratum for a theory to have a primitive ontology, it is not compulsory for it to do so in order to be empirically adequate. She goes on, though, to note that a satisfactory quantum metaphysics had better recover the existence of ordinary three-dimensional objects, on Moorean grounds: we are really confident that those objects exist!Chapter 6 is largely critical: an extended exegesis of the functionalist strategy for recovering higher-order ontology developed by David Albert, myself, and others. She raises two main criticisms of the functionalist strategy: it fails to distinguish between the wave function simulating three-dimensional objects and constituting those objects; it is restricted to recovering classical three-dimensional ontology, whereas we want to recover quantum-mechanical phenomena in three dimensions too. (The former objection is a development of criticisms by Bradley Monton, Tim Maudlin, and others; the latter is novel so far as I know.) For reasons of space, I won’t attempt to reply on behalf of the functionalist, but Ney certainly puts the challenge with admirable clarity.The final chapter of the book presents Ney’s positive account of emergent ontology, based not on functionalism but on considerations of symmetry (though she concedes that the separation is not completely sharp). Simplifying Ney’s subtle position: the permutation symmetries of quantum mechanics give a clear dynamical reason to regard certain decompositions of 3N-dimensional space (intuitively: those that decompose it into the N-fold product of Euclidean space) as preferred; that then licenses the metaphysical hypothesis that a localized wave function in 3N-dimensional space has, as its parts, particles in three-dimensional space. If the wave function is not localized (as will be the case generically, at least for the Everett interpretation), then we can think of those particles as being partially localized in various different regions of space.I have to say that I am not convinced this works, at least without a dynamical-collapse mechanism: in the Everett interpretation, it will yield an ontology where all the particles are completely delocalized. We only see a somewhat localized description of matter in three dimensions when we restrict to an Everett branch, and that restriction is normally motivated on functionalist grounds. But this may simply reflect subtleties of Ney’s intriguing proposal that I am not fully grasping at present.In summary, I congratulate Ney for a rich, subtle, and provocative account of wave function realism. Her edited collection of papers (coedited with Albert), The Wave Function, set the agenda for much of the metaphysics of quantum mechanics in the 2010s; The World in the Wave Function has a good chance of doing the same for the 2020s.

The Philosophical Review•Oct 1, 2022•2 citations

On the Quantum Theory of Molecules: Rigour, Idealization, and Uncertainty

Nick Huggett, James Ladyman, Karim P. Y. Thébault

Abstract Philosophers have claimed that: (a) Born–Oppenheimer approximation methods for solving molecular Schrödinger equations violate the Heisenberg uncertainty relations; therefore, (b) ‘quantum chemistry’ is not fully quantum; and (c) therefore chemistry does not reduce to physics. This paper analyses the reasoning behind Born–Oppenheimer methods and shows that they are internally consistent and fully quantum mechanical, contrary to (a)–(c). Our analysis addresses important issues of mathematical rigour, physical idealization, reduction, and classicality in the quantum theory of molecules, and we propose an agenda for the philosophy of quantum chemistry more grounded in scientific practice.

arXiv:2411.01942•Philosophy of Science•Apr 22, 2026•2 citations

Branching (Almost) Everywhere And All at Once

Alyssa Ney

It is sometimes said that a reason to prefer Everettian quantum mechanics is that it allows one to avoid the kind of spooky action at a distance that is a consequence of quantum entanglement according to other approaches. There is a straightforward argument to show EQM has this virtue, however some advocates argue that this requires we see branching as a local causal process. I explain this reasoning and then show why, given the way Everettians standardly conceive of worlds and branching as emergent phenomena, branching need not be viewed as a causal process for EQM to be relativistically local. Forthcoming in Local Quantum Mechanics, OUP 2026.

quant-pharXiv:2608.18644•Aug 20, 2026
Abstract The question of whether chemical structure is reducible to Everettian Quantum Mechanics (EQM) should be of interest to philosophers of chemistry and philosophers of physics alike. Among the three realist interpretations of quantum mechanics, EQM resolves the measurement problem by claiming that measurements (now interpreted as instances of decoherence) have indeterminate outcomes absolutely speaking, but determinate outcomes relative to emergent worlds—Maudlin (Topoi, 14:7-15, 1995). Philosophers who wish to be sensitive to the practice of quantum chemistry e.g. Scerri (The changing views of a philosopher of chemistry on the question of reduction, 2016) should be interested in EQM because Franklin and Seifert (J. Philos. Sci, 2020) claim that resolving the measurement problem also resolves the reducibility of chemical structure, and EQM is the interpretation which involves no mathematical structure beyond that used by practicing scientists. Philosophers interested in the quantum interpretation debate should be interested in the reducibility of chemistry because chemical structure is precisely the kind of determinate three-dimensional fact which EQM should be able to ground if it is to be empirically coherent—see Allori (Quantum Rep, 5:80-101, 2023). The prospects for reduction of chemical structure are poor if it cannot succeed in EQM; the prospects for EQM as a guide to ontology are poor if it cannot reduce chemical structure. Unfortunately for proponents of chemical reduction and EQM, there are three serious barriers to the reduction of chemistry to EQM. The first concern is that quantum treatments of chemical structure rely on the Born-Oppenheimer approximation, which holds nuclear locations fixed while minimizing the energy of the electronic configuration—Hendry (Philosophical Perspectives in Quantum Chemistry, 147-172, 2022), but this approximation is not licensed by EQM. The Born-Oppenheimer approximation relies on nuclei and molecular orbitals being simultaneously present, but in the three-dimensional ontology following from the Everett interpretation these only emerge at different energy scales and are not simultaneously present—Miller (Found. Chem, 25:405-417, 2023). The second concern is that the emergent worlds of EQM are supposed to be decoherent at the macro-scale—Wilson (The Nature of Contingency: Quantum Physics as Modal Realism 2020), but the recent development of superchemistry suggests that chemical reactions can occur in coherent states—Zhang et al. (Nat. Phys, 1-5, 2023). The third concern is that emergent worlds are only pragmatic pseudo-processes—Wallace (The Emergent Multiverse: Quantum Theory According to the Everett Interpretation, 2012b), but this means EQM trades realist physics for mere instrumentalism about chemistry. Absent a commitment to chemical realism, reduction is an empty promise. The prospects for reduction of chemical structure to EQM are therefore poor.
Abstract The debate between ontological reductionists and emergentists in chemistry has revolved around quantum mechanics. What Franklin and Seifert (BJPS 2020) add to the long-running dispute is an attention to the measurement problem. They contend that all three realist interpretations of the quantum formalism capable of resolving the measurement problem also obviate any need for chemical emergence. I push their argument further, arguing that the realist interpretations of quantum mechanics actually subvert the basis for reduction as well, by undercutting the idea that fundamental physical particles are actual parts of molecules. With both reduction and traditional synchronic emergence pictures ruled out, the only option for realists about quantum chemistry is strong Thomistic emergence.
The question of whether Everettian quantum mechanics (EQM) justifies the existence of metaphysical indeterminacy has recently come to the fore. Metaphysical indeterminacy has been argued to emerge from three sources: coherent superpositions, the indefinite number of branches in the quantum multiverse and the nature of these branches. This paper reviews the evidence and concludes that those arguments don't rely on EQM alone and rest on metaphysical auxiliary assumptions that transcend the physics of EQM. We show how EQM can be ontologically interpreted without positing metaphysical indeterminacy by adopting a deflationary attitude towards branches. Two ways of developing the deflationary view are then proposed: one where branches are eliminated, and another where they are reduced to the universal quantum state.
Quantum chemistry is the branch of chemistry whose primary focus is the application of quantum mechanics to chemical systems at the molecular level. Precisely due to its peculiar position between chemistry and physics, in the last times it has begun to engage the interest of the philosophers of chemistry. Nevertheless, in this philosophical field, quantum chemistry has been studied mainly from a historical viewpoint or from a perspective interested on methodological issues. By contrast, the question that will guide this article is: what kind of ontic items are those studied by quantum chemistry? In order to develop the argumentation, first the relevance of the ontological questions will be addressed. Then, it will be considered in what measure the Born-Oppenheimer approximation and the quantum-chemistry concept of electron fit in the quantum theoretical context. Finally, some issues about what quantum chemistry refers to will be discussed.
David Lewis famously quipped that he was willing to take metaphysical lessons from quantum mechanics only when it cleaned up its own act by providing interpretations or modifications of the formalism shorn of appeal to consciousness, irreducibly macroscopic notions, or outright instrumentalism. By the first decade of the twenty-first century, multiple approaches to quantum mechanics had been developed to a degree which met Lewis’s challenge: dynamical-collapse theories, Bohm-style hidden-variable theories, and Everett-style many-worlds theories, for all their respective problems and challenges, all offer ways of understanding quantum mechanics that metaphysicians can reasonably engage with. And so the last twenty years have seen a resurgence in the metaphysics of quantum mechanics, the question of what ontology and ideology is appropriate to a quantum universe. The metaphysics of quantum mechanics is not independent of the quantum measurement problem but does not coincide with it, either: there is a widespread view that adopting, say, the Everett interpretation still leaves significant ontological questions undecided, and conversely, a given answer to those questions might answer them for a dynamical-collapse theory too.Wave function realism has become a leading contender for the metaphysics of quantum mechanics, particularly in the case of dynamical-collapse and Everettian approaches. The starting point is nonrelativistic quantum mechanics expressed in configuration space: mathematically, the subject matter of the theory is a complex function of 3N variables, evolving under the Schrödinger equation (perhaps interrupted by occasional stochastic collapses). Traditionally those 3N variables are interpreted as the three coordinates of position of N particles—but in wave function realism, they are interpreted as points in a new, high-dimensional space. Quantum mechanics, according to the wave function realist, fundamentally concerns the undulations of the wave function in this space; three-dimensional goings-on are emergent, high-level, derivative.Alyssa Ney has been a leading figure in the development of wave function realism for most of its existence. Her articles advocating and developing the position have been highly influential, and the present book can be seen as the culmination of this line of her research and is the definitive statement of wave function realism as of 2021. Despite its comparative brevity, the book is too rich to be adequately described—far less critiqued—in this brief review; my goal is to give an overview of the main themes and arguments, and to make a few critical remarks along the way.The World in the Wavefunction is not formally divided into parts, but it can profitably be thought of that way. Chapters 1 through 3 develop the core case for wave function realism. Chapter 4 defends the position from the frequent criticism that it is restricted to nonrelativistic physics, by providing a version of wave function realism appropriate to quantum field theory. And chapters 5 through 7 are an extended exploration of how the observed three-dimensional world can be understood as emerging from a high-dimensional fundamental reality.The case Ney makes in chapters 1 through 3 for wavefunction realism is modest and cautious. In chapter 1 she provides a fairly standard—though elegantly expressed—case for the prima facie plausibility of wave function realism simply based on the fact that standard formulations of quantum mechanics are written in 3N dimensions, and on the (related) fact that entanglement means we cannot interpret quantum mechanics simply in terms of spatially localized particles and nothing else. But in chapter 2 she explicitly argues against any attempt to strengthen these plausibility arguments into reasons why wave function realism must be adopted; indeed, she provides a detailed and sympathetic taxonomy of the alternatives to wave function realism that have been developed, all of which she regards as entirely viable. (Chapter 2 of the book could profitably be used as introductory reading for a general graduate course on quantum metaphysics.) For Ney, the question of which metaphysics to adopt is a standard metaphysician’s question, to be answered by weighing strengths and weaknesses of the various alternatives against one another.In chapter 3, Ney identifies two such strengths for wave function realism. First, it is separable: we can specify the complete state of the universe point-by-point on the fundamental space, without any need to appeal to irreducible holism. Second, it is dynamically local: expressed in 3N-dimensional space, the Schrödinger dynamics involve no action at a distance.Ney makes the case for separability at length. Her case for dynamical locality is brief: she regards it as a straightforward consequence of the fact that the Schrödinger equation is a differential equation, so that the rate of change of the wave function at a point x depends only on the wave function arbitrarily close to x. But I think there is more worth investigating here: after all, the nonrelativistic Schrödinger equation may be a differential equation, but it is a parabolic differential equation, with no maximum speed of propagation: the rate of change of the wave function at x may depend only on a neighborhood of x, but the value of the wavefunction at x an arbitrarily short time later depends on the wave function everywhere in space. (And this is not—or not straightforwardly—just an artifact of ignoring relativity.)But in any case, why think that a separable, local theory is preferable to the alternative? Ney claims that separability and locality are more intuitive and lead to a more comprehensible ontology—and she makes an unabashed defense of intuitiveness and explicability as theoretical virtues. She is quite explicit that her reasons are pragmatic: intuitive theories benefit students and teachers; they are better suited to help us develop new theories; they speak better to the reasons why many students (Ney included) want to study physics in the first place. The implied metaphilosophy here is fascinating and it would be good to see it developed further in subsequent work: Ney seems to reject the mainstream modern approach to ontology (in which these pragmatic virtues are not obviously relevant to the truth of wave function realism) in favor of something neo-Carnapian where (so far as I can see) the goal of a quantum ontology is to help us get a deeper understanding of quantum mechanics, and that’s all there is to it. This also fits naturally with the pluralism she urges, in which approaches other than hers can also be valuable.Chapter 4—on relativistic generalizations of wavefunction realism—attempts both a conceptual and a technical task. The conceptual task is to argue that wavefunction realism per se is not wedded to any particular theory or choice of Hilbert-space basis within the theory: rather, wave function realism is any strategy that reifies a high-dimensional space in order to produce a separable local quantum ontology. If so, there is no block in principle to a relativistic generalization of the approach: we just need to find some appropriate high-dimensional space to describe the quantum state in relativistic quantum theory.The general philosophical point is well taken and convincingly defended (though it’s important to note that while arbitrary choices of Hilbert-space basis will give a separable theory, there is no reason to assume they will give a dynamically local theory: even something as simple as shifting from the position to the momentum basis in nonrelativistic quantum mechanics transforms the Schrödinger equation into something explicitly nonlocal). Unfortunately, I don’t think Ney succeeds in giving a clear statement of the high-dimensional space she has in mind for quantum field theory. This is one place where her laudable goal of making the book intelligible to nonspecialists becomes problematic: she makes many suggestive and interesting comments on quantum field theory, but there is no explicit, precise, mathematical statement of her view that can be contrasted with the explicit, precise, mathematical representation of the state in nonrelativistic quantum mechanics as a complex function on 3N-dimensional space.In the last part of the book—concerned with the emergence of ordinary three-dimensional ontology—Ney begins (chapter 5) by rebutting influential arguments by Tim Maudlin, Valia Allori, Sheldon Goldstein, and others that it is empirically incoherent for a physical theory not to make precise, nonemergent, nonderivative statements about matter in three-dimensional space (for a theory not to have a primitive ontology, to use the standard term for it). Ney argues—persuasively, to me—that it is perfectly compatible with the way science usually works for a theory to make statements about the observable only in an indirect, derivative way, so that while it might be a desideratum for a theory to have a primitive ontology, it is not compulsory for it to do so in order to be empirically adequate. She goes on, though, to note that a satisfactory quantum metaphysics had better recover the existence of ordinary three-dimensional objects, on Moorean grounds: we are really confident that those objects exist!Chapter 6 is largely critical: an extended exegesis of the functionalist strategy for recovering higher-order ontology developed by David Albert, myself, and others. She raises two main criticisms of the functionalist strategy: it fails to distinguish between the wave function simulating three-dimensional objects and constituting those objects; it is restricted to recovering classical three-dimensional ontology, whereas we want to recover quantum-mechanical phenomena in three dimensions too. (The former objection is a development of criticisms by Bradley Monton, Tim Maudlin, and others; the latter is novel so far as I know.) For reasons of space, I won’t attempt to reply on behalf of the functionalist, but Ney certainly puts the challenge with admirable clarity.The final chapter of the book presents Ney’s positive account of emergent ontology, based not on functionalism but on considerations of symmetry (though she concedes that the separation is not completely sharp). Simplifying Ney’s subtle position: the permutation symmetries of quantum mechanics give a clear dynamical reason to regard certain decompositions of 3N-dimensional space (intuitively: those that decompose it into the N-fold product of Euclidean space) as preferred; that then licenses the metaphysical hypothesis that a localized wave function in 3N-dimensional space has, as its parts, particles in three-dimensional space. If the wave function is not localized (as will be the case generically, at least for the Everett interpretation), then we can think of those particles as being partially localized in various different regions of space.I have to say that I am not convinced this works, at least without a dynamical-collapse mechanism: in the Everett interpretation, it will yield an ontology where all the particles are completely delocalized. We only see a somewhat localized description of matter in three dimensions when we restrict to an Everett branch, and that restriction is normally motivated on functionalist grounds. But this may simply reflect subtleties of Ney’s intriguing proposal that I am not fully grasping at present.In summary, I congratulate Ney for a rich, subtle, and provocative account of wave function realism. Her edited collection of papers (coedited with Albert), The Wave Function, set the agenda for much of the metaphysics of quantum mechanics in the 2010s; The World in the Wave Function has a good chance of doing the same for the 2020s.
Abstract Philosophers have claimed that: (a) Born–Oppenheimer approximation methods for solving molecular Schrödinger equations violate the Heisenberg uncertainty relations; therefore, (b) ‘quantum chemistry’ is not fully quantum; and (c) therefore chemistry does not reduce to physics. This paper analyses the reasoning behind Born–Oppenheimer methods and shows that they are internally consistent and fully quantum mechanical, contrary to (a)–(c). Our analysis addresses important issues of mathematical rigour, physical idealization, reduction, and classicality in the quantum theory of molecules, and we propose an agenda for the philosophy of quantum chemistry more grounded in scientific practice.
It is sometimes said that a reason to prefer Everettian quantum mechanics is that it allows one to avoid the kind of spooky action at a distance that is a consequence of quantum entanglement according to other approaches. There is a straightforward argument to show EQM has this virtue, however some advocates argue that this requires we see branching as a local causal process. I explain this reasoning and then show why, given the way Everettians standardly conceive of worlds and branching as emergent phenomena, branching need not be viewed as a causal process for EQM to be relativistically local. Forthcoming in Local Quantum Mechanics, OUP 2026.