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Exact general solution of the Schrödinger equation by modified Cole-Hopf transformation

Alan Clark Longfellow

Published Dec 9, 2024• 0 citations
Publisher

Abstract

The Schrödinger equation is a linear partial differential equation that describes the temporal evolution of the state of a quantum mechanical system. One of the pillars of quantum mechanics, the Schrödinger equation has been used to describe a wide variety of phenomena such as wave-particle duality, atomic orbitals, quantum oscillations, and even some fluid mechanics problems. Despite its established importance in the development of quantum mechanics, a solution of the Schrödinger equation for an arbitrary distribution of quantum mechanical potential or for an arbitrary number of space dimensions remains unknown. This work seeks to rectify this theoretical roadblock by providing an analytical solution through a recasting of the well-known Cole-Hopf transformation which is used to linearize a broad class of PDEs of which the Schrödinger equation becomes a member after an earlier change of variables. These two successive transformations render the general wave function proportional to the solution of a forced heat equation, allowing an explicit analytical solution applicable to any system in any number of space dimensions. Two practical applications to deriving the explicit wave functions of multielectronic atoms and to the forced Burgers equation of fluid mechanics are discussed, enabling greater mathematical insight into quantum entanglement and nonlinear fluid systems.

DOI
10.31219/osf.io/4gvzt

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วธการทางคณตศาสตรสำหรบสมการชเรอดงเงอร และวธประมาณคาแบบดบเบลยเคบ

เพชรอาภา บุญเสริม

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The Schrödinger equation is a linear partial differential equation that describes the temporal evolution of the state of a quantum mechanical system. One of the pillars of quantum mechanics, the Schrödinger equation has been used to describe a wide variety of phenomena such as wave-particle duality, atomic orbitals, quantum oscillations, and even some fluid mechanics problems. Despite its established importance in the development of quantum mechanics, a solution of the Schrödinger equation for an arbitrary distribution of quantum mechanical potential or for an arbitrary number of space dimensions remains unknown. This work seeks to rectify this theoretical roadblock by providing an analytical solution through a recasting of the well-known Cole-Hopf transformation which is used to linearize a broad class of PDEs of which the Schrödinger equation becomes a member after an earlier change of variables. These two successive transformations render the general wave function proportional to the solution of a forced heat equation, allowing an explicit analytical solution applicable to any system in any number of space dimensions. Two practical applications to deriving the explicit wave functions of multielectronic atoms and to the forced Burgers equation of fluid mechanics are discussed, enabling greater mathematical insight into quantum entanglement and nonlinear fluid systems.
In light of a recently discovered general solution to the Schrödinger equation in an arbitrary integer-dimensional real domain with arbitrary initial conditions, boundary conditions, and quantum mechanical potential via a modified Cole-Hopf transform, a solution of the Madelung equations of equal generality is derived in this work. After a sufficient degree of mathematical context is established by a brief recapitulation of the solution of the Schrödinger equation, the derivation of the Madelung equations from first principles proves that a general Madelung flow field is implied by a general Schrödinger wave function through illustration of the mathematical essence of the quantities in the Madelung equations. The solution follows by a decomposition of the newly found general wave function into its polar form and its substitution into the definitions of the Madelung flow velocity and density, and a transfer from wave function initial and boundary conditions to density and velocity boundary conditions. The transfer between the complex scalar-valued wave function and the real vector-valued velocity field is achieved by a conditional inversion of the gradient operator. Plots of the velocity and vorticity take mere milliseconds to generate on consumer hardware via an enclosed GNU Octave script and show highly turbulent patterns consistent with the laws of quantum mechanics, showing that this analytical Madelung solution possesses unprecedented ability to deterministically replicate quantum turbulence without any numerical methods at all, effectively democratizing the study of quantum turbulence with its internal structure and mathematical origin. This Madelung solution paves the way to equally general solutions of unsolved problems in classical fluid mechanics including the Euler and Navier-Stokes equations, whose methods and analyses including existence and smoothness are expounded in works currently in production by the author.
We construct a Madelung fluid model with specific time variable parameters as dissipative quantum fluid and linearize it in terms of Schrodinger equation with time dependent parameters. It allows us to find exact solutions of the nonlinear Madelung system in terms of solutions of the Schrodinger equation and the corresponding classical linear ODE with variable frequency and damping. For the complex velocity field the Madelung system takes the form of a nonlinear complex Schrodinger-Burgers equation, for which we obtain exact solutions using complex Cole-Hopf transformation. In particular, we discuss and give exact results for nonlinear Madelung systems related with Caldirola-Kanai type dissipative harmonic oscillator.
The Schrödinger equation is a fundamental equation in physics for describing quantum mechanical behavior. It is a partial differential equation that shows how a wave function of a physical system evolves over time. In addition, it is associated with the kinetic energy and the potential energy, both of which contribute towards the total energy. This paper explains mathematical aspect of the Schrödinger equation. The concept of the WKB approximation has also been reviewed, which is an important method in finding the approximate solutions for the wave function. In addition, the paper also shows how to derive the transmission and reflection probabilities in relation to a one-dimensional quantum problem, called a “tunneling problem”, which occurs when a classical particle passes through a region where total energy is less than its potential energy. The WKB approximation can be used as a basis for formally writing down the exact solutions. Furthermore, it gives a high accuracy for the propagation of waves with high frequency or short wavelength.
We present a novel new way-called Schrödingerization-to simulate general (quantum and nonquantum) systems of linear ordinary and partial differential equations (PDEs) via quantum simulation. We introduce a new transform, referred to as the warped phase transformation, where any linear-including nonautonamous-system of ordinary or partial differential equation can be recast into a system of Schrödinger's equations, in real time, in a straightforward way. This approach is not only applicable to PDEs for classical problems but is also useful for quantum problems, including the preparation of quantum ground states and Gibbs thermal states, the simulation of quantum states in random media in the semiclassical limit, simulation of Schrödinger's equation in a bounded domain with artificial boundary conditions, and other non-Hermitian physics. This formulation is versatile enough to be applicable in a simple way to both digital quantum simulation as well as to analog quantum simulation, and using either qubits or continuous-variable quantum systems (qumodes).
We solve the Schrodinger equation analytically for systems whose potentials have a certain time-dependence (which is monotonously decreasing) and general coordinate-dependences.Only a few time-dependent systems have been reported to be analytically solved whose potentials are constant, linear, and quadratic functions of coordinate with arbitrary time-dependences.From a different perspective, we focus on the time-dependent systems whose potentials are monotonously decreasing functions of time with arbitrary coordinate dependences.Time-dependent potential of any coordinate-dependence can be handled analytically by transforming it to a time-independent potential of known solutions if its time-dependence is monotonously decreasing.We do this by a unitary transformation of the wavefunction and variable transformations to change the Schrodinger equation to be time-independent in new variables.These variables are then determined by solving a set of simple differential equations.This way we are able to find and to obtain analytical solutions for time-dependent potentials which we mention above.
An important feature of the wave equation is that its solutions q(r, t) are uniquely specified once the initial values q(r, 0) and (del)q(r, 0)/@t are specified. As was mentioned before, if we view the wave equation as describing a continuum limit of a network of coupled oscillators, then this result is very reasonable since one must specify the initial position and velocity of an oscillator to uniquely determine its motion. It is possible to write down other “equations of motion” that exhibit wave phenomena but which only require the initial values of the dynamical variable — not its time derivative — to specify a solution. This is physically appropriate in a number of situations, the most significant of which is in quantum mechanics where the wave equation is called the Schrodinger equation. This equation describes the time development of the observable attributes of a particle via the wave function (or probability amplitude) . In quantum mechanics, the complete specification of the initial conditions of the particle’s motion is embodied in the initial value of . The price paid for this change in the allowed initial data while asking for a linear wave equation is the introduction of complex numbers into the equation for the wave. Indeed, the values taken by are complex numbers. In what follows we shall explore some of the elementary features of the wave phenomena associated with the Schrodinger equation.