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Journal of Non-Equilibrium Thermodynamics

Power and efficient power optimization of one-qubit Novikov quantum heat engines with an external dissipative heat leak

Julio Juan Fernández

Published May 29, 2024• 5 citations
Publisher

Abstract

Abstract We optimize one-qubit Novikov quantum heat engines with a dissipative heat leak using the formalisms of open-system Quantum Mechanics and the Finite-Time Thermodynamics. We show that the leak changes the power-efficiency and the efficient-power-efficiency curves, reduces the maximum efficiency of the machine and does not change its power. We also discuss the effects of the leak on the power that is rejected from the machine to the environment. Finally, we study the high-temperature limit to check that the engine reduces in this limit to a classic Novikov heat engine.

DOI
10.1515/jnet-2023-0118

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Abstract We optimize one-qubit Novikov quantum heat engines with a dissipative heat leak using the formalisms of open-system Quantum Mechanics and the Finite-Time Thermodynamics. We show that the leak changes the power-efficiency and the efficient-power-efficiency curves, reduces the maximum efficiency of the machine and does not change its power. We also discuss the effects of the leak on the power that is rejected from the machine to the environment. Finally, we study the high-temperature limit to check that the engine reduces in this limit to a classic Novikov heat engine.
Abstract We study the ecological regime of quantum heat engines where the heat transfer between the environment and the engine is mediated with two qubits that act as energy filters and allow the conversion of heat into work. Using quantum thermodynamics, the theory of open quantum system and the fundamentals of finite-time thermodynamics we obtain the output power, the ecological function and the entropy production of the engine. Then, we optimize the functioning to the ecological function to find the range of efficiencies for which the system works optimally under the ecological criterium. We find that (i) the maximum value of the ecological function depends on the thermal copulings and the energies of the qubits that define the engine. (ii) We can define an ecological working region where the engine works producing a power that is similar to the maximum power but where it rejects much less heat to the environment. (iii) That the range of efficiencies defining the ecological region depends on the parameters defining the engine.(iv) An optimal working region where both the power and the ecological function are big is defined for each machine.
We present a detailed study of a three-level quantum heat engine operating at maximum efficient power function, a trade-off objective function defined by the product of the efficiency and power output of the engine.The efficient power function represents a trade-off between the power output and efficiency of a heat engine.Engines working in the maximum efficient power regime operate at finite power, with finite efficiency lying in between the regimes of maximum power and maximum efficiency (Carnot efficiency).First, for near-equilibrium conditions, we find a general expression for the efficiency and establish the universal nature of efficiency at maximum power and maximum efficient power.Then in the high-temperature limit, optimizing with respect to one parameter while constraining the other one, we obtain the lower and upper bounds on the efficiency for both strong as well as weak matter-field coupling conditions.Except for the weak matter-field coupling condition, the obtained bounds on the efficiency exactly match with the bounds already known for some models of classical heat engines.Further for weak matter-field coupling, we derive some new bounds on the efficiency of the engine which lie beyond the range covered by bounds obtained for strong matter-field coupling.We conclude by comparing the performance of our three-level quantum heat engine in maximum power and maximum efficient power regimes and show that the engine operating at maximum efficient power produces at least 88.89% of the maximum power output while considerably reducing the power loss due to entropy production.Finally, to complete our analysis, we review the experimental setup of a recently realized effective three-level quantum engine.
Abstract Quantum heat engines (QHEs) are commonly believed to achieve their optimal efficiency only when operated quasi-statically. When running at finite power, however, they suffer effective friction due to the generation of coherences and transitions between energy eigenstates. It was noted that it is possible to increase the power of a QHE using external control schemes or suitable dephasing noise. Here, we investigate the thermodynamic cost associated with dephasing noise schemes using both numerical and analytical methods. Our findings unveil that the observed gain in power is generally not free of thermodynamic costs, as it involves energy costs of the control fields or heat flows between thermal and dephasing baths. These contributions must be duly accounted for when determining the engine’s overall efficiency. We identify suitable regimes in which, at a fixed effective dephasing rate, the heat leaked into the explicitly modelled dephasing bath can be made arbitrarily small, so that the efficiency at finite power approaches that of a quasi-statically operated Otto engine even when the dephasing environment is fully accounted for.
The concept of thermal machines has evolved from the canonical steam engine to the recently proposed nanoscopic quantum systems as working fluids. The latter obey quantum open system dynamics and frequently operate in nonequilibrium conditions. However, the role of this dynamics in the overall performance of quantum heat engines remains an open problem. Here we analyze and optimize the efficiency and power output of two-stage quantum heat engines fueled by nonequilibrium steady states. In a charging first stage, the quantum working fluid consisting of a qutrit or two coupled qubits is connected to two reservoirs at different temperatures, which establish a heat current that stores ergotropy in the system; the second stage comprises a coherent driving force that extracts work from the machine in finite a amount of time; finally, the external drive is switched off and the machine enters a new cycle.
We investigate the finite-power performance of quantum heat engines working in the linear response regime where the temperature gradient is small. The engine cycles with working substances of ideal harmonic systems consist of two heat transfer and two adiabatic processes, such as the Carnot cycle, Otto cycle, and Brayton cycle. By analyzing the optimal protocol under maximum power we derive the explicitly analytic expression for the irreversible entropy production, which becomes the low dissipation form in the long duration limit. Assuming the engine to be endoreversible, we derive the universal expression for the efficiency at maximum power, which agrees well with that obtained from the phenomenological heat transfer laws holding in the classical thermodynamics. Through appropriate identification of the thermodynamic fluxes and forces that a linear relation connects, we find that the quantum engines under consideration are tightly coupled, and the universality of efficiency at maximum power is confirmed at the linear order in the temperature gradient.